Citation: Lianyue Wang, Bo Chen, Lanhui Ren, Henyun Zhang, Ying Lü, Shuang Gao. Vanadium catalyzed direct synthesis of imines from amines or alcohols and amines by an aerobic oxidative reaction under mild conditions[J]. Chinese Journal of Catalysis, ;2015, 36(1): 19-23. doi: 10.1016/S1872-2067(14)60196-0 shu

Vanadium catalyzed direct synthesis of imines from amines or alcohols and amines by an aerobic oxidative reaction under mild conditions

Lianyue Wang ^a ,
Bo Chen ^a,b ,
Lanhui Ren ^a,b ,
Henyun Zhang ^a ,
Ying Lü ^a ,
Shuang Gao ^a,,

1.
a Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaoning, China;

Corresponding author: Shuang Gao,
Received Date: 20 June 2014
Available Online: 16 July 2014
Fund Project: 国家重点基础研究发展计划(973计划, 2009CB623505). (973计划, 2009CB623505)

The direct synthesis of imines from amines or alcohols and amines by vanadium catalyzed aerobic oxidation was developed. Without an additive or promoter, various symmetrical and unsymmetrical imines were obtained in good to excellent yields under mild conditions with air as an environmentally benign oxidant. The catalyst is very easy to prepare and use, and this catalytic system is also effective for the synthesis of heteroatom-containing imines.
- Imine,
- Alcohol,
- Amine,
- Aerobic oxidation,
- Vanadium
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