Citation: Abdol R. Hajipour, Hirbod Karimi. Acetylation of alcohols and phenols under solvent-free conditions using copper zirconium phosphate[J]. Chinese Journal of Catalysis, ;2014, 35(12): 1982-1989. doi: 10.1016/S1872-2067(14)60185-6 shu

Acetylation of alcohols and phenols under solvent-free conditions using copper zirconium phosphate

Abdol R. Hajipour ^a,b,, ,
Hirbod Karimi ^a,c

1.
a. Pharmaceutical Research Laboratory, Department of Chemistry, Isfahan University of Technology, Isfahan 84156, Iran;

Corresponding author: Abdol R. Hajipour,
Received Date: 18 May 2014
Available Online: 1 July 2014
Fund Project: This work was supported by the Isfahan University of Technology(IUT) (IUT)

Copper zirconium phosphate nanoparticles have been used as an efficient catalyst for the acetylation of a wide range of alcohols and phenols with acetic anhydride in good to excellent yields under solvent-free conditions. The steric and electronic properties of the different substrates had a significant influence on the reaction conditions required to achieve the acetylation. The catalyst used in the current study was characterized by inductively-coupled plasma optical emission spectroscopy, energy dispersive spectroscopy, X-ray diffraction, N₂ adsorption-desorption, scanning electron microscopy, and transmission electron microscopy. These analyses revealed that the interlayer distance in the catalyst increased from 7.5 to 8.0 Å when Cu²⁺ was intercalated between the layers, whereas the crystallinity of the material was reduced. This nanocatalyst could also be recovered and reused at least six times without any discernible decrease in its catalytic activity. This new method for the acetylation of alcohols and phenols has several key advantages, including mild and environmentally friendly reaction conditions, as well as good to excellent yields and a facile work-up.
- Copper zirconium phosphate,
- Nanoparticles,
- Acylation,
- Heterogeneous catalysis,
- Solvent-free
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