Citation: Fei Ma, Zhenwu Ding, Wei Chu, Shixiong Hao, Tao Qi. Preparation of LaXCoO₃ (X = Mg, Ca, Sr, Ce) catalysts and their performance for steam reforming of ethanol to hydrogen[J]. Chinese Journal of Catalysis, ;2014, 35(10): 1768-1778. doi: 10.1016/S1872-2067(14)60182-0 shu

Preparation of LaXCoO₃ (X = Mg, Ca, Sr, Ce) catalysts and their performance for steam reforming of ethanol to hydrogen

Fei Ma ^a,b ,
Zhenwu Ding ^a,c ,
Wei Chu ^a,c,, ,
Shixiong Hao ^a,d ,
Tao Qi ^b

1.
a Department of Chemical Engineering, Sichuan University, Chengdu 610065, Sichuan, China;

Corresponding author: Wei Chu,
Received Date: 25 April 2014
Available Online: 28 June 2014
Fund Project:

Perovskite nanocomposite catalysts LaXCoO₃ (X = Mg, Ca, Sr, or Ce; n(La):n(X) = 3:2) have been prepared by a citric acid-complexing method and used for steam reforming of ethanol (SRE), leading to hydrogen generation. The samples were characterized by X-ray diffraction, infrared spectroscopy, scanning electron microscopy, X-ray photoelectron spectroscopy, N₂ adsorption-desorption, and H₂ temperature-programmed reduction. The effects of elemental substitution in the LaCoO₃ perovskite were studied, and the catalytic performance and primary stability of the hydrogen production from SRE were investigated. In the highly substituted samples, only the Ce-doped sample was isolated as the pure perovskite phase. The presence of a Co₃O₄ phase in the Ca-doped or Sr-doped samples was beneficial for the reduction of the active Co component, while Sr-doped or Ce-doped samples showed good activity and stability. The sample incorporating Sr demonstrated better catalytic performance than those of other samples.
- Citric acid-complexing method,
- Perovskite,
- Cobalt,
- Composite catalyst,
- Ethanol steam reforming,
- Hydrogen
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1.
沈阳化工大学材料科学与工程学院沈阳 110142

Preparation of LaXCoO3 (X = Mg, Ca, Sr, Ce) catalysts and their performance for steam reforming of ethanol to hydrogen

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通讯作者: 陈斌, bchen63@163.com

Preparation of LaXCoO₃ (X = Mg, Ca, Sr, Ce) catalysts and their performance for steam reforming of ethanol to hydrogen