Citation: Fei Ma, Zhenwu Ding, Wei Chu, Shixiong Hao, Tao Qi. Preparation of LaXCoO₃ (X = Mg, Ca, Sr, Ce) catalysts and their performance for steam reforming of ethanol to hydrogen[J]. Chinese Journal of Catalysis, ;2014, 35(10): 1768-1778. doi: 10.1016/S1872-2067(14)60182-0 shu

Preparation of LaXCoO₃ (X = Mg, Ca, Sr, Ce) catalysts and their performance for steam reforming of ethanol to hydrogen

Fei Ma ^a,b ,
Zhenwu Ding ^a,c ,
Wei Chu ^a,c,, ,
Shixiong Hao ^a,d ,
Tao Qi ^b

1.
a Department of Chemical Engineering, Sichuan University, Chengdu 610065, Sichuan, China;

Corresponding author: Wei Chu,
Received Date: 25 April 2014
Available Online: 28 June 2014
Fund Project:

Perovskite nanocomposite catalysts LaXCoO₃ (X = Mg, Ca, Sr, or Ce; n(La):n(X) = 3:2) have been prepared by a citric acid-complexing method and used for steam reforming of ethanol (SRE), leading to hydrogen generation. The samples were characterized by X-ray diffraction, infrared spectroscopy, scanning electron microscopy, X-ray photoelectron spectroscopy, N₂ adsorption-desorption, and H₂ temperature-programmed reduction. The effects of elemental substitution in the LaCoO₃ perovskite were studied, and the catalytic performance and primary stability of the hydrogen production from SRE were investigated. In the highly substituted samples, only the Ce-doped sample was isolated as the pure perovskite phase. The presence of a Co₃O₄ phase in the Ca-doped or Sr-doped samples was beneficial for the reduction of the active Co component, while Sr-doped or Ce-doped samples showed good activity and stability. The sample incorporating Sr demonstrated better catalytic performance than those of other samples.
- Citric acid-complexing method,
- Perovskite,
- Cobalt,
- Composite catalyst,
- Ethanol steam reforming,
- Hydrogen
1. [1]
  [1] Tong D G, Chu W, Wu P, Gu G F, Zhang L. J Mater Chem A, 2013, 1: 358
2. [2]
  [2] Liu Q H, Liao L W, Liu Z L, Dong X F. J Energy Chem, 2013, 22: 665
3. [3]
  [3] Fishtik I, Alexander A, Datta R, Geana D. Int J Hydrogen Energy, 2000, 25: 31
4. [4]
  [4] Vizcaíno A J, Carrero A, Calles J A. Catal Today, 2009, 146: 63
5. [5]
  [5] Sun J, Wu F, Qiu X P, Wang F, Hao S J, Liu Y. Chin J Catal (孙杰, 吴锋, 邱新平, 王芳, 郝少军, 刘媛. 催化学报), 2004, 25: 551
6. [6]
  [6] Zhang L F, Liu J, Li W, Guo C L, Zhang J L. J Nat Gas Chem, 2009, 18: 55
7. [7]
  [7] Ma F, Chu W, Huang L H, Yu X P, Wu Y Y. Chin J Catal (马飞, 储伟, 黄利宏, 余晓鹏, 吴永永. 催化学报), 2011, 32: 970
8. [8]
  [8] Pereira E B, Homs N, Martí S, Fierro J L G, de la Piscina P R. J Catal, 2008, 257: 206
9. [9]
  [9] Birot A, Epron F, Descorme C, Duprez D. Appl Catal B, 2008, 79: 17
10. [10]
  [10] Cai W J, Wang F G, Zhan E S, Van Veen A C, Mirodatos C, Shen W J. J Catal, 2008, 257: 96
11. [11]
  [11] He L, Wu Q, Li T M. Nat Gas Chem Ind (何飗, 吴倩, 李佟茗. 天然气化工(Cl化学与化工)), 2010, 35(5): 5
12. [12]
  [12] Vizcaíno A J, Carrero A, Calles J A. Int J Hydrogen Energy, 2007, 32: 1450
13. [13]
  [13] Frusteri F, Freni S, Spadaro L, Chiodo V, Bonura G, Donato S, Cavallaro S. Catal Commun, 2004, 5: 611
14. [14]
  [14] Pang X J, Chen Y Z, Dai R Q, Cui P. Chin J Catal (庞潇健, 陈亚中, 代瑞旗, 崔鹏. 催化学报), 2012, 33: 281
15. [15]
  [15] Peng D Q, Liu N, Wang Y H. Chem Engineer (彭得群, 刘宁, 王玉和. 化学工程师), 2008, (1): 7
16. [16]
  [16] Petrovic S, Pakic V, Jovanovic D M, Baricevic A T. Appl Catal B, 2006, 66: 249
17. [17]
  [17] Balamurugan S, Xu M, Takayama-Muromachi E. J Solid State Chem, 2005, 178: 3431
18. [18]
  [18] Hejtmanek J, Jirak Z, Knizek K, Marysko M, Veverka M, Autret C. J Magn Magn Mater, 2008, 320: e92
19. [19]
  [19] Murthy P S R, Priolkar K R, Bhobe P A, Das A, Sarode P R, Nigam A K. J Magn Magn Mater, 2011, 323: 822
20. [20]
  [20] Magalhes R N S H, Toniolo F S, da Silva V T, Schmal M. Appl Catal A, 2010, 388: 216
21. [21]
  [21] Cui M S, Li M L, Zhang S L, Long Z Q, Cui D L, Huang X W. Chin J Nonferrous Metal (崔梅生, 李明来, 张顺利, 龙志奇, 崔大立, 黄小卫. 中国有色金属学报), 2004, 14: 1580
22. [22]
  [22] Leontiou A A, Ladavos A K, Armatas G S, Trikalitis P N, Pomonis P T. Appl Catal A, 2004, 263: 227
23. [23]
  [23] Sey B, Baghalha M, Kazemian H. Chem Eng J, 2009, 148: 306
24. [24]
  [24] Bedel L, Roger A C, Rehspringer J L, Zimmermann Y, Kiennemann A. J Catal, 2005, 235: 279
25. [25]
  [25] Ding R R, Li C, Wang L J, Hu R S. Appl Catal A, 2013, 464-465: 261
26. [26]
  [26] Han X, Yu Y B, He H, Zhao J J. J Energy Chem, 2013, 22: 861
27. [27]
  [27] Sun Y, Hla S S, Dffy G J, Cousins A J, French D, Morpeth L D, Edwards J H, Roberts D G. Int J Hydrogen Energy, 2011, 36: 79
28. [28]
  [28] Nakamoto K. Infrared and Raman Spectra of Inorganic and Coordination Compounds, Part B, Applications in Coordination, Organometallic, and Bioinorganic Chemistry. 6th Ed. New York: John Wiley & Sons, 2009. 110
29. [29]
  [29] Rao G V S, Rao C N R, Ferraro J R. Appl Spectrosc, 1970, 24: 436
30. [30]
  [30] Choi D H, Shim I B, Kim C S, Shaterian M. J Magn Magn Mater, 2008, 320: e575
31. [31]
  [31] Salavati-Niasari M, Khansari A, Davar F. Inorg Chim Acta, 2009, 362: 4937
32. [32]
  [32] Sharma Y, Sharma N, Subba Rao G V, Chowdari B V R. Solid State Ionics, 2008, 179: 587
33. [33]
  [33] Stelmachowski P, Maniak G, Kaczmarczyk J, Zasada F, Piskorz W, Kotarba A, Sojka Z. Appl Catal B, 2014, 146: 105
34. [34]
  [34] Hyman M P, Vohs J M. Surf Sci, 2011, 605: 383
1. [1]
  Yuchen Zhou , Huanmin Liu , Hongxing Li , Xinyu Song , Yonghua Tang , Peng Zhou . Designing thermodynamically stable noble metal single-atom photocatalysts for highly efficient non-oxidative conversion of ethanol into high-purity hydrogen and value-added acetaldehyde. Acta Physico-Chimica Sinica, 2025, 41(6): 100067-0. doi: 10.1016/j.actphy.2025.100067
2. [2]
  Yao Ma , Xin Zhao , Hongxu Chen , Wei Wei , Liang Shen . Progress and Perspective of Perovskite Thin Single Crystal Photodetectors. Acta Physico-Chimica Sinica, 2025, 41(4): 2309045-0. doi: 10.3866/PKU.WHXB202309045
3. [3]
  Yixuan Gao , Lingxing Zan , Wenlin Zhang , Qingbo Wei . Comprehensive Innovation Experiment: Preparation and Characterization of Carbon-based Perovskite Solar Cells. University Chemistry, 2024, 39(4): 178-183. doi: 10.3866/PKU.DXHX202311091
4. [4]
  Lin Song , Dourong Wang , Biao Zhang . Innovative Experimental Design and Research on Preparing Flexible Perovskite Fluorescent Gels Using 3D Printing. University Chemistry, 2024, 39(7): 337-344. doi: 10.3866/PKU.DXHX202310107
5. [5]
  Tongtong Zhao , Yan Wang , Shiyue Qin , Liang Xu , Zhenhua Li . New Experiment Development: Upgrading and Regeneration of Discarded PET Plastic through Electrocatalysis. University Chemistry, 2024, 39(3): 308-315. doi: 10.3866/PKU.DXHX202309003
6. [6]
  Qin Hu , Liuyun Chen , Xinling Xie , Zuzeng Qin , Hongbing Ji , Tongming Su . Construction of Electron Bridge and Activation of MoS₂ Inert Basal Planes by Ni Doping for Enhancing Photocatalytic Hydrogen Evolution. Acta Physico-Chimica Sinica, 2024, 40(11): 2406024-0. doi: 10.3866/PKU.WHXB202406024
7. [7]
  Cheng PENG , Jianwei WEI , Yating CHEN , Nan HU , Hui ZENG . First principles investigation about interference effects of electronic and optical properties of inorganic and lead-free perovskite Cs₃Bi₂X₉ (X=Cl, Br, I). Chinese Journal of Inorganic Chemistry, 2024, 40(3): 555-560. doi: 10.11862/CJIC.20230282
8. [8]
  Xue Liu , Lipeng Wang , Luling Li , Kai Wang , Wenju Liu , Biao Hu , Daofan Cao , Fenghao Jiang , Junguo Li , Ke Liu . Research on Cu-Based and Pt-Based Catalysts for Hydrogen Production through Methanol Steam Reforming. Acta Physico-Chimica Sinica, 2025, 41(5): 100049-0. doi: 10.1016/j.actphy.2025.100049
9. [9]
  Jizhou Liu , Chenbin Ai , Chenrui Hu , Bei Cheng , Jianjun Zhang . Accelerated Interfacial Electron Transfer in Perovskite Solar Cell by Ammonium Hexachlorostannate Modification and fs-TAS Investigation. Acta Physico-Chimica Sinica, 2024, 40(11): 2402006-0. doi: 10.3866/PKU.WHXB202402006
10. [10]
  Yingqi BAI , Hua ZHAO , Huipeng LI , Xinran REN , Jun LI . Perovskite LaCoO₃/g-C₃N₄ heterojunction: Construction and photocatalytic degradation properties. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 480-490. doi: 10.11862/CJIC.20240259
11. [11]
  Jiahe LIU , Gan TANG , Kai CHEN , Mingda ZHANG . Effect of low-temperature electrolyte additives on low-temperature performance of lithium cobaltate batteries. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 719-728. doi: 10.11862/CJIC.20250023
12. [12]
  Lele Feng , Xueying Bai , Jifeng Pang , Hongchen Cao , Xiaoyan Liu , Wenhao Luo , Xiaofeng Yang , Pengfei Wu , Mingyuan Zheng . Single-atom Pd boosted Cu catalysts for ethanol dehydrogenation. Acta Physico-Chimica Sinica, 2025, 41(9): 100100-0. doi: 10.1016/j.actphy.2025.100100
13. [13]
  Xinyuan Shi , Chenyangjiang , Changyu Zhai , Xuemei Lu , Jia Li , Zhu Mao . Preparation and Photoelectric Performance Characterization of Perovskite CsPbBr₃ Thin Films. University Chemistry, 2024, 39(6): 383-389. doi: 10.3866/PKU.DXHX202312019
14. [14]
  Jian Li , Yu Zhang , Rongrong Yan , Kaiyuan Sun , Xiaoqing Liu , Zishang Liang , Yinan Jiao , Hui Bu , Xin Chen , Jinjin Zhao , Jianlin Shi . Highly Efficient, Targeted, and Traceable Perovskite Nanocrystals for Photoelectrocatalytic Oncotherapy. Acta Physico-Chimica Sinica, 2025, 41(5): 100042-0. doi: 10.1016/j.actphy.2024.100042
15. [15]
  Weicheng Feng , Jingcheng Yu , Yilan Yang , Yige Guo , Geng Zou , Xiaoju Liu , Zhou Chen , Kun Dong , Yuefeng Song , Guoxiong Wang , Xinhe Bao . Regulating the High Entropy Component of Double Perovskite for High-Temperature Oxygen Evolution Reaction. Acta Physico-Chimica Sinica, 2024, 40(6): 2306013-0. doi: 10.3866/PKU.WHXB202306013
16. [16]
  Rui Li , Huan Liu , Yinan Jiao , Shengjian Qin , Jie Meng , Jiayu Song , Rongrong Yan , Hang Su , Hengbin Chen , Zixuan Shang , Jinjin Zhao . Emerging Irreversible and Reversible Ion Migrations in Perovskites. Acta Physico-Chimica Sinica, 2024, 40(11): 2311011-0. doi: 10.3866/PKU.WHXB202311011
17. [17]
  Nengmin ZHU , Wenhao ZHU , Xiaoyao YIN , Songzhi ZHENG , Hao LI , Zeyuan WANG , Wenhao WEI , Xuanheng CHEN , Weihai SUN . Preparation of high-performance CsPbBr₃ perovskite solar cells by the aqueous solution solvent method. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1131-1140. doi: 10.11862/CJIC.20240419
18. [18]
  Yameen Ahmed , Xiangxiang Feng , Yuanji Gao , Yang Ding , Caoyu Long , Mustafa Haider , Hengyue Li , Zhuan Li , Shicheng Huang , Makhsud I. Saidaminov , Junliang Yang . Interface Modification by Ionic Liquid for Efficient and Stable FAPbI₃ Perovskite Solar Cells. Acta Physico-Chimica Sinica, 2024, 40(6): 2303057-0. doi: 10.3866/PKU.WHXB202303057
19. [19]
  Ke Li , Chuang Liu , Jingping Li , Guohong Wang , Kai Wang . Architecting Inorganic/Organic S-Scheme Heterojunction of Bi₄Ti₃O₁₂ Coupling with g-C₃N₄ for Photocatalytic H₂O₂ Production from Pure Water. Acta Physico-Chimica Sinica, 2024, 40(11): 2403009-0. doi: 10.3866/PKU.WHXB202403009
20. [20]
  Jinghua Wang , Yanxin Yu , Yanbiao Ren , Yesheng Wang . Integration of Science and Education: Investigation of Tributyl Citrate Synthesis under the Promotion of Hydrate Molten Salts for Research and Innovation Training. University Chemistry, 2024, 39(11): 232-240. doi: 10.3866/PKU.DXHX202402057

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(578)
HTML views(19)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Preparation of LaXCoO3 (X = Mg, Ca, Sr, Ce) catalysts and their performance for steam reforming of ethanol to hydrogen

Metrics

通讯作者: 陈斌, bchen63@163.com

Preparation of LaXCoO₃ (X = Mg, Ca, Sr, Ce) catalysts and their performance for steam reforming of ethanol to hydrogen