Citation: Yanpeng Pei, Yunjie Ding, Juan Zang, Xiangen Song, Wenda Dong, Hejun Zhu, Tao Wang, Weimiao Chen. Fischer-Tropsch synthesis: Characterizing and reaction testing of Co₂C/SiO₂ and Co₂C/Al₂O₃ catalysts[J]. Chinese Journal of Catalysis, ;2015, 36(2): 252-259. doi: 10.1016/S1872-2067(14)60179-0 shu

Fischer-Tropsch synthesis: Characterizing and reaction testing of Co₂C/SiO₂ and Co₂C/Al₂O₃ catalysts

Yanpeng Pei ^a,c ,
Yunjie Ding ^a,b,, ,
Juan Zang ^a,c ,
Xiangen Song ^a,c ,
Wenda Dong ^a,c ,
Hejun Zhu ^a ,
Tao Wang ^a ,
Weimiao Chen ^a

1.
a Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaoning, China;

Corresponding author: Yunjie Ding,
Received Date: 24 October 2014
Available Online: 16 November 2014

SiO₂- and Al₂O₃-supported Co₂C catalysts were prepared by carburizing supported Co precursors with CO. The catalysts were characterized by N₂ physisorption, X-ray diffraction and H₂ temperature-programmed reduction techniques, and evaluated by the Fischer-Tropsch (F-T) reaction. The results showed that SiO₂- and Al₂O₃-supported Co₂C catalysts could be successfully obtained but sufficient carburization time was required. All of the as-prepared supported Co₂C catalysts exhibited activity and selectivity towards alcohols. It is considered that surface metallic Co species contributed to the activity, surface Co₂C species were responsible for the formation of alcohols, and bulk Co₂C species were inert during the F-T reaction.
- Supported cobalt carbide,
- Fischer-Tropsch synthesis,
- Alcohols,
- Surface sites
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沈阳化工大学材料科学与工程学院沈阳 110142

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Fischer-Tropsch synthesis: Characterizing and reaction testing of Co₂C/SiO₂ and Co₂C/Al₂O₃ catalysts