Citation: Suitao Qi, Yingying Li, Jiaqi Yue, Hao Chen, Chunhai Yi, Bolun Yang. Hydrogen production from decalin dehydrogenation over Pt-Ni/C bimetallic catalysts[J]. Chinese Journal of Catalysis, ;2014, 35(11): 1833-1839. doi: 10.1016/S1872-2067(14)60178-9 shu

Hydrogen production from decalin dehydrogenation over Pt-Ni/C bimetallic catalysts

1.
School of Chemical Engineering and Technology, Xi'an Jiaotong University, Xi'an 710049, Shaanxi, China

Corresponding author: Suitao Qi,
Received Date: 6 April 2014
Available Online: 23 May 2014
Fund Project: 国家自然科学基金(21006076) (21006076) 高等学校博士学科点专项科研基金(20110201130002) (20110201130002) 中央高校基本科研业务费专项基金(xjj2011062). (xjj2011062)

Pt-Ni bimetallic catalysts and the corresponding monometallic Pt catalysts supported on active carbon were prepared by incipient wetness impregnation and characterized by X-ray diffraction, N₂ adsorption, and NH₃-temperature programmed desorption. Their activities for decalin dehydrogenation were investigated at a superheated liquid film state in a batch reactor. The effects of temperature, impregnation sequence, and Pt/Ni molar ratio on the dehydrogenation activity and the naphthalene yield were investigated. The results show that the Pt-Ni bimetallic catalyst significantly enhanced hydrogen evolution compared with either Ni or Pt monometallic catalyst. The highest dehydrogenation conversion and naphthalene yield were obtained when the Pt/Ni molar ratio was 1:1 and Pt was impregnated first. The experimental results were correlated with density functional theory calculations of hydrogen binding energy (HBE) on different catalytic surfaces. The correlation confirmed that bimetallic surfaces with stronger HBEs had higher dehydrogenation activities.
- Platinum,
- Nickel,
- Bimetallic,
- Decalin,
- Dehydrogenation,
- Density functional theory
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