Citation: Changlin Yu, Wanqin Zhou, Jimmy C. Yu, Hong Liu, Longfu Wei. Design and fabrication of heterojunction photocatalysts for energy conversion and pollutant degradation[J]. Chinese Journal of Catalysis, ;2014, 35(10): 1609-1618. doi: 10.1016/S1872-2067(14)60170-4 shu

Design and fabrication of heterojunction photocatalysts for energy conversion and pollutant degradation

Changlin Yu ^a,, ,
Wanqin Zhou ^a ,
Jimmy C. Yu ^b ,
Hong Liu ^c,, ,
Longfu Wei ^a

1.
a School of Metallurgy and Chemical Engineering, Jiangxi University of Science and Technology, Ganzhou 341000, Jiangxi, China;

Corresponding author: Changlin Yu, Hong Liu,
Received Date: 24 May 2014
Available Online: 5 June 2014
Fund Project:

Photocatalysis has attracted much attention for its promise in converting solar energy to chemical energy and in degrading various pollutants. Many recent investigations have demonstrated photocatalysts with well-defined junctions between two semiconductors with matched electronic band structures. Such structures effectively facilitate charge transfer and suppress recombination of photogenerated electrons and holes, leading to extremely high activity and stability. In this review, we focus on the influence of the heterojunction on the performance of semiconductor photocatalysts, including TiO₂-based, ZnO-based, and Ag-based semiconductor photocatalysts. We also investigate fabrication methods for heterojunctions and attempt to understand the mechanisms behind photocatalysis. Finally, we propose challenges to design and clarify the mechanism for enhancing the effect of the heterojunction on photocatalyst performance.
- Photocatalyst,
- Heterojunction,
- Semiconductor,
- Photocatalytic performance,
- Organic pollutant degradation,
- Hydrogen production
1. [1]
  [1] Fujishima A, Honda K. Nature, 1972, 238: 37
2. [2]
  [2] Cui W Q, Liu Y F, Liu L, Hu J S, Liang Y H. Appl Catal A, 2012, 417-418: 111
3. [3]
  [3] Jing D W, Jing L, Liu H, Yao S, Guo L J. Ind Eng Chem Res, 2013, 52: 1992
4. [4]
  [4] Ahmed A Y, Kandiel T A, Oekermann T, Bahnemann D. J Phys Chem Lett, 2011, 2: 2461
5. [5]
  [5] Zhang J Y, Wang Y H, Zhang J, Lin Z, Huang F, Yu J G. ACS Appl Mater Interfaces, 2013, 5: 1031
6. [6]
  [6] Cui W Q, Ma S S, Liu L, Liang Y H. Chem Eng J, 2012, 204-206: 1
7. [7]
  [7] Wang Y, Yu J G, Xiao W, Li Q. J Mater Chem A, 2014, 2: 3847
8. [8]
  [8] Yu C L, Yang K, Xie Y, Fan Q Z, Yu J C, Shu Q, Wang C Y. Nanoscale, 2013, 5: 2142
9. [9]
  [9] Yu C L, Cao F F, Li X, Li G, Xie Y, Yu J C, Shu Q, Fan Q Z, Chen J C. Chem Eng J, 2013, 219: 86
10. [10]
  [10] Zhou W Q, Yu C L, Fan Q Z, Wei L F, Chen J C, Yu J C. Chin J Catal (周晚琴, 余长林, 樊启哲, 魏龙福, 陈建钗, Yu J C. 催化学报), 2013, 34: 1250
11. [11]
  [11] Yu C L, Chen J C, Cao F F, Li X, Fan Q Z, Yu J C, Wei L F. Chin J Catal (余长林, 陈建钗, 操芳芳, 李鑫, 樊启哲, Yu J C, 魏龙福. 催化学报), 2013, 34: 385
12. [12]
  [12] Li K, Chai B, Peng T Y, Mao J, Zan L. ACS Catal, 2013, 3: 170
13. [13]
  [13] Grötzel M. J Photochem Photobiol C, 2003, 4: 145
14. [14]
  [14] Gong X Q, Selloni A, Dulub O, Jacobson P, Diebold U. J Am Chem Soc, 2008, 130: 370
15. [15]
  [15] Rodrigues S, Ranjit K T, Uma S, Martyanov I N, Klabunde K J. Adv Mater, 2005, 17: 2467
16. [16]
  [16] Liu G, Zhao Y N, Sun C H, Li F, Lu G Q, Cheng H M. Angew Chem Int Ed, 2008, 47: 4516
17. [17]
  [17] Chen X F, Wang X C, Hou Y D, Huang J H, Wu L, Fu X Z. J Catal, 2008, 255: 59
18. [18]
  [18] Yu C L, Li G, Kumar S, Kawasaki H, Jin R C. J Phys Chem Lett, 2013, 4: 2847
19. [19]
  [19] Asahi R, Morikawa T, Ohwaki T, Aoki K, Taga Y. Science, 2001, 293: 269
20. [20]
  [20] Yu C L, Cao F F, Li G, Wei R F, Yu J C, Jin R C, Fan Q Z, Wang C Y. Sep Purif Technol, 2013, 120: 110
21. [21]
  [21] Wang X C, Maeda K, Thomas A, Takanabe K, Xin G, Carlsson J M, Domen K, Antonietti M. Nat Mater, 2009, 8: 76
22. [22]
  [22] Zhou X M, Liu G, Yu J G, Fan W H. J Mater Chem, 2012, 22: 21337
23. [23]
  [23] Bi Y P, Hu H Y, Ouyang S X, Lu G X, Cao J Y, Ye J H. Chem Commun, 2012, 48: 3748
24. [24]
  [24] Heremans P, Cheyns D, Rand B P. Acc Chem Res, 2009, 42: 1740
25. [25]
  [25] Zhang J, Xu Q, Feng Z C, Li M J, Li C. Angew Chem Int Ed, 2008, 47: 1766
26. [26]
  [26] Yu C L, Li G, Kumar S, Yang K, Jin R C. Adv Mater, 2014, 26: 892
27. [27]
  [27] Su R, Tiruvalam R, Logsdail A J, He Q, Downing C A, Jensen M T, Dimitratos N, Kesavan L, Wells P P, Bechstein R, Jensen H H, Wendt S, Catlow C R A, Kiely C J, Hutchings G J, Besenbacher F. ACS Nano, 2014, 8: 3490
28. [28]
  [28] Yu C L, Wei L F, Li X, Chen J C, Fan Q Z, Yu J C. Mater Sci Eng B, 2013, 178: 344
29. [29]
  [29] Yu C L, Yang K, Zhou W Q, Fan Q Z, Wei L F, Yu J C. J Phys Chem Solids, 2013, 74: 1714
30. [30]
  [30] Yu C L, Fan C F, Meng X J, Yang K, Cao F F, Li X. React Kinet Catal Lett, 2011, 103: 141
31. [31]
  [31] Yu C L, Yu J C, Fan C F, Wen H R, Hu S J. Mater Sci Eng B, 2010, 166: 213
32. [32]
  [32] Xing M Y, Yang B Y, Yu H, Tian B Z, Bagwasi S, Zhang J L, Gong X Q. J Phys Chem Lett, 2013, 4: 3910
33. [33]
  [33] Yu J G, Xiong J F, Cheng B, Liu S W. Appl Catal B, 2005, 60: 211
34. [34]
  [34] Yu C L, Fan Q Z, Xie Y, Chen J C, Shu Q, Yu J C. J Hazard Mater, 2012, 237-238: 38
35. [35]
  [35] Barolo G, Livraghi S, Chiesa M, Paganini M C, Giamello E. J Phys Chem C, 2012, 116: 20887
36. [36]
  [36] Yu C L, Cai D J, Yang K, Yu J C, Zhou Y, Fan C F. J Phys Chem Solids, 2010, 71: 1337
37. [37]
  [37] Yu C L, Yu J C. Catal Lett, 2009, 129: 462
38. [38]
  [38] Yu J G, Wang Y, Xiao W. J Mater Chem A, 2013, 1: 10727
39. [39]
  [39] Kumar N, Maitra U, Hegde V I, Waghmare U V, Sundaresan A, Rao C N R. Inorg Chem, 2013, 52: 10512
40. [40]
  [40] Boppana V B R, Lobo R F. J Catal, 2011, 281: 156
41. [41]
  [41] Yu C L, Yu J C, Zhou W Q, Yang K. Catal Lett, 2010, 140: 172
42. [42]
  [42] Xing M Y, Qi D Y, Zhang J L, Chen F, Tian B Z, Bagwas S, Anpo M. J Catal, 2012, 294: 37
43. [43]
  [43] Xing M Y, Zhang J L, Chen F, Tian B Z. Chem Commun, 2011, 47: 4947
44. [44]
  [44] Xiang Q J, Yu J G, Jaroniec M. J Am Chem Soc, 2012, 134: 6575
45. [45]
  [45] Qiu B C, Xing M Y, Zhang J L. J Am Chem Soc, 2014, 136: 5852
46. [46]
  [46] Dai G P, Yu J G, Liu G. J Phys Chem C, 2011, 115: 7339
47. [47]
  [47] Yu C L, Wei L F, Chen J C, Xie Y, Zhou W Q, Fan Q Z. Ind Eng Chem Res, 2014, 53: 5759
48. [48]
  [48] Xu Q C, Wellia D V, Ng Y H, Amal R, Tan T T Y. J Phys Chem C, 2011, 115: 7419
49. [49]
  [49] Huang H J, Li D Z, Lin Q, Zhang W J, Shao Y, Chen Y B, Sun M, Fu X Z. Environ Sci Technol, 2009, 43: 4164
50. [50]
  [50] Zhang J Y, Zhu H L, Zheng S K, Pan F, Wang T M. ACS Appl Mater Interfaces, 2009, 1: 2111
51. [51]
  [51] Kim Y J, Gao B F, Han S Y, Jung M H, Chakraborty A K, Ko T, Lee C, Lee W I. J Phys Chem C, 2009, 113: 19179
52. [52]
  [52] Sun M, Chen G D, Zhang Y K, Wei Q, Ma Z M, Du B. Ind Eng Chem Res, 2012, 51: 2897
53. [53]
  [53] Yi Z G, Ye J H, Kikugawa N, Kako T, Ouyang S X, Stuart-Williams H, Yang H, Cao J Y, Luo W J, Li Z S, Liu Y, Wither R L. Nat Mater, 2010, 9: 559
54. [54]
  [54] Bi Y P, Ouyang S X, Umezawa N, Cao J Y, Ye J H. J Am Chem Soc, 2011, 133: 6490
55. [55]
  [55] Bi Y P, Ouyang S X, Cao J Y, Ye J H. Phys Chem Chem Phys, 2011, 13: 10071
56. [56]
  [56] Yang X F, Cui H Y, Li Y, Qin J L, Zhang R X, Tang H. ACS Catal, 2013, 3: 363
57. [57]
  [57] Tang J T, Liu Y H, Li H Z, Tan Z, Li D T. Chem Commun, 2013, 49: 5498
58. [58]
  [58] Yang J H, Wang D E, Han H X, Li C. Acc Chem Res, 2013, 46: 1900
59. [59]
  [59] Wang W S, Du H, Wang R X, Wen T, Xu A W. Nanoscale, 2013, 5: 3315
60. [60]
  [60] Zhu L, Wei B, Xu L L, Lü Z, Zhang H L, Gao H, Che J X. CrystEngComm, 2012, 14: 5705
61. [61]
  [61] Xu H, Xu Y G, Li H M, Xia J X, Xiong J, Yin S, Huang C J, Wan H L. Dalton Trans, 2012, 41: 3387
62. [62]
  [62] Zhou W J, Liu H, Wang J Y, Liu D, Du G J, Cui J J. ACS Appl Mater Interfaces, 2010, 2: 2385
63. [63]
  [63] Yao W F, Zhang B, Huang C P, Ma C, Song X L, Xu Q J. J Mater Chem, 2012, 22: 4050
64. [64]
  [64] Shen K, Gondal M A, Siddique R G, Shi S, Wang S Q, Sun J B, Xu Q Y. Chin J Catal (沈凯, Gondal M A, Siddigue R G, 施珊, 王斯琦, 孙江波, 徐庆宇. 催化学报), 2014, 35: 78
65. [65]
  [65] He W W, Kim H K, Wamer W G, Melka D, Callahan J H, Yin J J. J Am Chem Soc, 2014, 136: 750
66. [66]
  [66] Mclaren A, Valdes-Solis T, Li G Q, Tsang S C. J Am Chem Soc, 2009, 131: 12540
67. [67]
  [67] Li P, Wei Z, Wu T, Peng Q, Li Y D. J Am Chem Soc, 2011, 133: 5660
68. [68]
  [68] Chu D, Masuda Y, Ohji T, Kato K. Langmuir, 2010, 26: 2811
69. [69]
  [69] Yu C L, Yang K, Yu J C, Peng P, Cao F F, Li X, Zhou X C. Acta Phys-Chim Sin (物理化学学报), 2011, 27: 505
70. [70]
  [70] Lai Y L, Meng M, Yu Y F, Wang X T, Ding T. Appl Catal B, 2011, 105: 335
71. [71]
  [71] Yu C L, Yang K, Shu Q, Yu J C, Cao F F, Li X. Chin J Catal (余长林, 杨凯, 舒庆, Yu J C, 操芳芳, 李鑫. 催化学报), 2011, 32: 555
72. [72]
  [72] Yu L L, Yang K, Yu J C, Cao F F, Li X, Zhou X Z. J Inorg Mater (余长林, 杨凯, Yu J C, 操芳芳, 李鑫, 周晓春. 无机材料学报), 2011, 26: 1157
73. [73]
  [73] Yang K, Yu C L, Zhang L N, Yu J C. J Synth Cryst (杨凯, 余长林, 张丽娜, 余济美. 人工晶体学报), 2012, 41: 171
74. [74]
  [74] Yu C L, Yang K, Shu Q, Yu J C, Cao F F, Li X, Zhou X C. Sci China Chem, 2012, 55: 1802
75. [75]
  [75] Zheng L R, Zheng Y H, Chen C Q, Zhan Y Y, Lin X Y, Zheng Q, Wei K M, Zhu J F. Inorg Chem, 2009, 48: 1819
76. [76]
  [76] Zong X, Yan H J, Wu G P, Ma G J, Wen F Y, Wang L, Li C. J Am Chem Soc, 2008, 130: 7176
77. [77]
  [77] Yang J H, Wang D E, Han H X, Li C. Acc Chem Res, 2013, 46: 1900
78. [78]
  [78] Yu C L, Fan C F, Yu J C, Zhou W Q, Yang K. Mater Res Bull, 2011, 46: 140
79. [79]
  [79] Yu C L, Zhou W Q, Yu J C, Cao F F, Li X. Chin J Chem, 2012, 30: 721
80. [80]
  [80] Yu C L, Yang K, Yu J C, Cao F F, Li X, Zhou X Z. J Alloys Compd, 2011, 509: 4547
81. [81]
  [81] Lin X P, Xing J C, Wang W D, Shan Z C, Xu F F, Huang F Q. J Phys Chem C, 2007, 111: 18288
82. [82]
  [82] Xie T P, Liu C L, Xu L J, Yang J, Zhou W. J Phys Chem C, 2013, 117: 24601
83. [83]
  [83] Shenawi-Khalil S, Uvarov V, Fronton S, Popov I, Sasson Y. J Phys Chem C, 2012, 116: 11004
84. [84]
  [84] He Z Q, Shi Y Q, Gao C, Wen L N, Chen J M, Song S A. J Phys Chem C, 2014, 118: 389
85. [85]
  [85] Chang C, Zhu L Y, Wang S F, Chu X L, Yue L F. ACS Appl Mater Interfaces, 2014, 6: 5083
86. [86]
  [86] Reddy K H, Martha S, Parida K M. Inorg Chem, 2013, 52: 6390
87. [87]
  [87] Xu L L, Ni L, Shi W D, Guan J G. Chin J Catal (许蕾蕾,倪磊,施伟东,官建国.催化学报), 2012, 33: 1101
88. [88]
  [88] Yu J G, Jin J, Cheng B, Jaroniec M. J Mater Chem A, 2014, 2: 3407
89. [89]
  [89] Chai S N, Zhao G H, Zhang Y N, Wang Y J, Nong F Q, Li M F, Li D M. Environ Sci Technol, 2012, 46: 10182
90. [90]
  [90] Yang L X, Luo S L, Li Y, Xiao Y, Kang Q, Cai Q Y. Environ Sci Technol, 2010, 44: 7641
91. [91]
  [91] Zhang J, Yu J G, Zhang Y M, Li Q, Gong J R. Nano Lett, 2011, 11: 4774
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