Citation: Mengxiao Zhang, Cuican Li, Weiming Hua, Yinghong Yue, Zi Gao. Preparation and catalytic performance of perfluorosulfonic acid-functionalized carbon nanotubes[J]. Chinese Journal of Catalysis, ;2014, 35(11): 1874-1882. doi: 10.1016/S1872-2067(14)60167-4 shu

Preparation and catalytic performance of perfluorosulfonic acid-functionalized carbon nanotubes

1.
Department of Chemistry and Shanghai Key Laboratory of Molecular Catalysis and Innovative Material, Fudan University, Shanghai 200433, China

Corresponding author: Yinghong Yue,
Received Date: 3 May 2014
Available Online: 10 June 2014
Fund Project: 国家自然科学基金(20773027,20773028和21273043) (20773027,20773028和21273043)上海市科学技术委员会(08DZ2270500). (08DZ2270500)

Perfluorosulfonic acid-functionalized carbon nanotubes were prepared by liquid deposition of the perfluorosulfonic acid-polytetrafluoroethylene copolymer and characterized by N₂ adsorption, scanning electron microscopy, transmission electron microscopy, Fourier transform infrared spectroscopy, and acid-base titration. The effects of reaction temperature and the type of solvent were investigated. The results showed that these solid acids are very stable in both polar and non-polar solvents and can maintain their acidity up to 300 ℃. Higher activity and better stability were observed over these materials in the alkylation of hydroquinone compared with poly(styrene sulfonic acid)-grafted carbon nanotubes.
- Carbon nanotube,
- Perfluorosulfonic acid,
- Acidity,
- Stability,
- Hydroquinone alkylation,
- tert-butanol,
1. [1]
  [1] Busca G. Chem Rev, 2007, 107: 5366
2. [2]
  [2] Okuhara T. Chem Rev, 2002, 102: 3641
3. [3]
  [3] Hara M, Yoshida T, Takagaki A, Takata T, Kondo J N, Hayashi S, Domen K. Angew Chem Int Ed, 2004, 43: 2955
4. [4]
  [4] Toda M, Takagaki A, Okamura M, Kondo J N, Hayashi S, Domen K, Hara M. Nature, 2005, 438: 178
5. [5]
  [5] Okamura M, Takagaki A, Toda M, Kondo J N, Domen K, Tatsumi T, Hara M, Hayashi S. Chem Mater, 2006, 18: 3039
6. [6]
  [6] Chang B B, Fu J, Tian Y L, Dong X P. J Phys Chem C, 2013, 117: 6252
7. [7]
  [7] Wang X Q, Liu R, Waje M M, Chen Z W, Yan Y S, Bozhilov K N, Feng P Y. Chem Mater, 2007, 19: 2395
8. [8]
  [8] Mo X H, López D E, Suwannakarn K, Liu Y J, Lotero E, Goodwin J G Jr. J Catal, 2008, 254: 332
9. [9]
  [9] Moghaddas M, Davoodnia A, Heravi M M, Tavakoli-Hoseini N. Chin J Catal (催化学报), 2012, 33: 706
10. [10]
  [10] Zhou L P, Dong B B, Tang S, Ma H, Chen C, Yang X M, Xu J. J Energy Chem, 2013, 22: 659
11. [11]
  [11] Zhou L N, Liu K, Hua W M, Yue Y H, Gao Z. Chin J Catal (周丽娜, 刘可, 华伟明, 乐英红, 高滋. 催化学报), 2009, 30: 196
12. [12]
  [12] Iijima S. Nature, 1991, 354: 56
13. [13]
  [13] Pantarotto D, Partidos C D,Graff R, Hoebeke J, Briand J P,Prato M, Bianco A. J Am Chem Soc, 2003, 125: 6160
14. [14]
  [14] Peng F, Zhang L, Wang H J, Lü P, Yu H. Carbon, 2005, 43: 2405
15. [15]
  [15] Shu Q, Zhang Q, Xu G H, Wang J F. Food Bioprod Process, 2009, 87: 164
16. [16]
  [16] Yu H, Jin Y G, Li Z L, Peng F, Wang H J. J Solid State Chem, 2008, 181: 432
17. [17]
  [17] Poonjarernsilp C, Sano N, Tamon H. Appl Catal B, 2014, 147: 726
18. [18]
  [18] Doroodmand M M, Sobhani S, Ashoori A. Can J Chem, 2012, 90: 701
19. [19]
  [19] Zhang X H, Tang Q Q, Yang D, Hua W M, Yue Y H, Wang B D, Zhang X H, Hu J H. Mater Chem Phys, 2011, 126: 310
20. [20]
  [20] Liu K, Li C C, Zhang X H, Hua W M, Yang D, Hu J H, Yue Y H, Gao Z. Catal Commun, 2010, 12: 217
21. [21]
  [21] Benak K R, Dominguez L, Economy J, Mangun C L. Carbon, 2002, 40: 2323
22. [22]
  [22] Cid R, Pecchi G. Appl Catal, 1985, 14: 15
23. [23]
  [23] Khder A S, El-Sharkamy E A, El-Hakam S A, Ahamed A I. Catal Commun, 2008, 9: 769
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沈阳化工大学材料科学与工程学院沈阳 110142