Citation: Jiaying Cai, Hong Ma, Junjie Zhang, Zhongtian Du, Yizheng Huang, Jin Gao, Jie Xu. Catalytic oxidation of glycerol to tartronic acid over Au/HY catalyst under mild conditions[J]. Chinese Journal of Catalysis, ;2014, 35(10): 1653-1660. doi: 10.1016/S1872-2067(14)60132-7 shu

Catalytic oxidation of glycerol to tartronic acid over Au/HY catalyst under mild conditions

Jiaying Cai ^a,b ,
Hong Ma ^a ,
Junjie Zhang ^a,b ,
Zhongtian Du ^a ,
Yizheng Huang ^a ,
Jin Gao ^a ,
Jie Xu ^a,,

1.
a Dalian National Laboratory for Clean Energy, State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaoning, China;

Corresponding author: Jie Xu,
Received Date: 30 March 2014
Available Online: 28 April 2014
Fund Project:

Gold nanoclusters or nanoparticles on various supports (CeO₂, activated carbon, HY, REY, and NaY) were investigated for glycerol oxidation in the aqueous phase under mild conditions. Compared with other catalysts, Au/HY showed remarkable catalytic performance in forming dicarboxylic acid (tartronic acid) over the monocarboxylic acid (glyceric acid) or the C-C cleavage product (oxalic acid). Au/HY achieved 98% conversion of glycerol and 80% yield of tartronic acid at 60 ℃ under 0.3 MPa O₂. Further characterization showed that the small size of Au clusters is the key factor for the high oxidation performance. In situ Fourier transform infrared spectroscopy revealed that glycerol was first transformed to glyceric acid, and then glyceric acid was directly oxidized to tartronic acid.
- Catalytic oxidation,
- Glycerol,
- Gold,
- Tartronic acid
1. [1]
  [1] Ragauskas A J, Williams C K, Davison B H, Britovsek G, Cairney J, Eckert C A, Frederick W J Jr, Hallett J P, Leak D J, Liotta C L, Mielenz J R, Murphy R, Templer R, Tschaplinski T. Science, 2006, 311: 484
2. [2]
  [2] Bozell J J. Clean Soil Air Water, 2008, 36: 633
3. [3]
  [3] Bozell J J, Petersen G R. Green Chem, 2010, 12: 539
4. [4]
  [4] Kohse-Hinghaus K, Osswald P, Cool T A, Kasper T, Hansen N, Qi F, Westbrook C K, Westmoreland P R. Angew Chem Int Ed, 2010, 49: 3572
5. [5]
  [5] Huber G W, Iborra S, Corma A. Chem Rev, 2006, 106: 4044
6. [6]
  [6] Clark I T. Ind Eng Chem, 1958, 50: 1125
7. [7]
  [7] Rennard D C, Kruger J S, Michael B C, Schmidt L D. Ind Eng Chem Res, 2010, 49: 8424
8. [8]
  [8] Zhang M Y, Liang D, Nie R F, Lü X Y, Chen P, Hou Z Y. Chin J Catal (张梦媛, 梁丹, 聂仁峰, 吕秀阳, 陈平, 侯昭胤. 催化学报), 2012, 33: 1340
9. [9]
  [9] Zhao J, Yu W Q, Li D C, Ma H, Gao J, Xu J. Chin J Catal (赵静, 于维强, 李德财, 马红, 高进, 徐杰. 催化学报), 2010, 31: 200
10. [10]
  [10] Berchmans H J, Hirata S. Bioresour Technol, 2008, 99: 1716
11. [11]
  [11] Liang D, Cui S Y, Gao J, Wang J H, Chen P, Hou Z Y. Chin J Catal (梁丹, 崔世玉, 高静, 王军华, 陈平, 侯昭胤. 催化学报), 2011, 32, 1831
12. [12]
  [12] Pagliaro M, Rossi M. The Future of Glycerol. Cambridge: Royal Society of Chemistry, 2008
13. [13]
  [13] Biesiada A, Nawirska A, Kucharska A, Sokol-Letowska A. Ecol Chem Eng A, 2011, 18: 9
14. [14]
  [14] Kimura H, Imanaka T, Yokota Y. JP Patent 06279352A. 1994
15. [15]
  [15] Caselli G, Monatovanini M, Gandolfi C A, Allegretti M, Fiorentino S, Pellegrini L, Melillo G, Bertini R, Sabbatini W, Anacardio R, Calvenna G, Sciortino G, Teti A. J Bone Miner Res, 1997, 12: 972
16. [16]
  [16] Villa A, Chan-Thaw C E, Prati L. Appl Catal B, 2010, 96: 541
17. [17]
  [17] Zope B N, Davis S E, Davis R J. Top Catal, 2012, 55: 24
18. [18]
  [18] Yakusheva T S. Bull Exp Biol Med, 1958, 45: 52
19. [19]
  [19] Gandolfi C A, Cotini L, Mantovanini M, Caselli G, Clavenna G, Omini C. WO Patent 9 410 127. 1994
20. [20]
  [20] Dimitratos N, Lopez-Sanchez J A, Lennon D, Porta F, Prati L, Villa A. Catal Lett, 2006, 108: 147
21. [21]
  [21] Dimitratos N, Messi C, Porta F, Prati L, Villa A. J Mol Catal A, 2006, 256: 21
22. [22]
  [22] Dimitratos N, Porta F, Prati L. Appl Catal A, 2005, 291: 210
23. [23]
  [23] Ma H, Nie X, Cai J Y, Chen C, Gao J, Miao H, Xu J. Sci China Chem, 2010, 53: 1497
24. [24]
  [24] Cai J Y, Ma H, Zhang J J, Song Q, Du Z T, Huang Y Z, Xu J. Chem Eur J, 2013, 19: 14215
25. [25]
  [25] Simões M, Baranton S, Coutanceau C. Appl Catal B, 2010, 93: 354
26. [26]
  [26] Kimura H, Yokota Y, Sawamoto Y. Catal Lett, 2005, 99: 133
1. [1]
  Yongmei Liu , Lisen Sun , Zhen Huang , Tao Tu . Curriculum-Based Ideological and Political Design for the Experiment of Methanol Oxidation to Formaldehyde Catalyzed by Electrolytic Silver. University Chemistry, 2024, 39(2): 67-71. doi: 10.3866/PKU.DXHX202308020
2. [2]
  Yajin Li , Huimin Liu , Lan Ma , Jiaxiong Liu , Dehua He . Photothermal Synthesis of Glycerol Carbonate via Glycerol Carbonylation with CO₂ over Au/Co₃O₄-ZnO Catalyst. Acta Physico-Chimica Sinica, 2024, 40(9): 2308005-0. doi: 10.3866/PKU.WHXB202308005
3. [3]
  Ruifeng CHEN , Chao XU , Jianting JIANG , Tianshe YANG . Gold nanorod/zinc oxide/mesoporous silica nanoplatform: A triple-modal platform for synergistic anticancer therapy. Chinese Journal of Inorganic Chemistry, 2025, 41(11): 2272-2282. doi: 10.11862/CJIC.20250117
4. [4]
  Wei LI , Jianjie XU , Linlin WANG , Chuanbing HOU , Hongliang HAN , Qionghua JIN . Synthesis, structure, and photocatalytic properties of {PMo₁₂}-based rare-earth tetraisopropyl ethylenediphosphonate complexes. Chinese Journal of Inorganic Chemistry, 2026, 42(10): 2077-2091. doi: 10.11862/CJIC.20260220
5. [5]
  Yu Dai , Xueting Sun , Haoyu Wu , Naizhu Li , Guoe Cheng , Xiaojin Zhang , Fan Xia . Determination of the Michaelis Constant for Gold Nanozyme-Catalyzed Decomposition of Hydrogen Peroxide. University Chemistry, 2025, 40(5): 351-356. doi: 10.12461/PKU.DXHX202407052
6. [6]
  Dingwen CHEN , Siheng YANG , Haiyan FU , Hua CHEN , Xueli ZHENG , Weichao XUE , Jiaqi XU , Ruixiang LI . NiOOH-mediated synthesis of gold nanoaggregates for electrocatalytic performance for selective oxidation of glycerol to glycolate. Chinese Journal of Inorganic Chemistry, 2025, 41(11): 2317-2326. doi: 10.11862/CJIC.20250053
7. [7]
  Qingtao CHEN , Xiangdong SHI , Xianghai RAO , Liying JIANG , Chunxiao JIA , Fenghua CHEN . Catalytic and in situ surface-enhanced Raman scattering detection properties of graphene oxide/gold nanorod assembly. Chinese Journal of Inorganic Chemistry, 2026, 42(1): 120-128. doi: 10.11862/CJIC.20250091
8. [8]
  Zhanggui DUAN , Yi PEI , Shanshan ZHENG , Zhaoyang WANG , Yongguang WANG , Junjie WANG , Yang HU , Chunxin LÜ , Wei ZHONG . Preparation of UiO-66-NH₂ supported copper catalyst and its catalytic activity on alcohol oxidation. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 496-506. doi: 10.11862/CJIC.20230317
9. [9]
  Hui-Ying Chen , Hao-Lin Zhu , Pei-Qin Liao , Xiao-Ming Chen . Integration of Ru(Ⅱ)-Bipyridyl and Zinc(Ⅱ)-Porphyrin Moieties in a Metal-Organic Framework for Efficient Overall CO₂ Photoreduction. Acta Physico-Chimica Sinica, 2024, 40(4): 2306046-0. doi: 10.3866/PKU.WHXB202306046
10. [10]
  Yinjie Xu , Suiqin Li , Lihao Liu , Jiahui He , Kai Li , Mengxin Wang , Shuying Zhao , Chun Li , Zhengbin Zhang , Xing Zhong , Jianguo Wang . Enhanced Electrocatalytic Oxidation of Sterols using the Synergistic Effect of NiFe-MOF and Aminoxyl Radicals. Acta Physico-Chimica Sinica, 2024, 40(3): 2305012-0. doi: 10.3866/PKU.WHXB202305012
11. [11]
  Mengyang LI , Hao XU , Zhonghao NIU , Chunhua GONG , Weihui ZHONG , Jingli XIE . Highly effective catalytic synthesis of β-amino alcohols by using viologen-polyoxometalate hybrid materials. Chinese Journal of Inorganic Chemistry, 2025, 41(7): 1294-1300. doi: 10.11862/CJIC.20250080
12. [12]
  Yucai Zhang , Jun Jiang . Electrochemical Carbon Dioxide Reduction to Ethylene. University Chemistry, 2026, 41(2): 190-196. doi: 10.12461/PKU.DXHX202503006
13. [13]
  Jiali Lei , Juan Wang , Wenhui Zhang , Guohong Wang , Zihui Liang , Jinmao Li . TiO₂/CdIn₂S₄ S-scheme heterojunction photocatalyst promotes photocatalytic hydrogen evolution coupled vanillyl alcohol oxidation. Acta Physico-Chimica Sinica, 2025, 41(12): 100174-0. doi: 10.1016/j.actphy.2025.100174
14. [14]
  Shuting KONG , Fengshi ZHANG , Zhiyi LU , Yanling LIU , Minglang YE , Zhengfang HU , Longsheng WANG , Bing HU , Haiying WANG . Research advance of the preparation of tributyl citrate catalyzed by supported heteropolyacid catalysts. Chinese Journal of Inorganic Chemistry, 2026, 42(3): 441-452. doi: 10.11862/CJIC.20250303
15. [15]
  Xiaofang Li , Zhigang Wang . 调节金助催化剂的d_z²占据轨道增强光催化合成H₂O₂. Acta Physico-Chimica Sinica, 2025, 41(7): 100080-0. doi: 10.1016/j.actphy.2025.100080
16. [16]
  Yuanyuan Ping , Wangqing Kong . 光催化碳氢键官能团化合成1-苯基-1,2-乙二醇. University Chemistry, 2025, 40(6): 238-247. doi: 10.12461/PKU.DXHX202408092
17. [17]
  Kezhen Qi , Bei Cheng , Kaiqiang Xu . Ultrafast interfacial charge transfer promoted by the LSPR of Au nanoparticles for photocatalytic H₂ evolution. Acta Physico-Chimica Sinica, 2026, 42(3): 100205-0. doi: 10.1016/j.actphy.2025.100205
18. [18]
  Yujin Deng , Yishuang Chen , Lijie Zhang , Huile Jin , Yun Yang , Quanlong Xu , Shun Wang . Plasmonic Au nanobipyramid assembly covalent organic framework for boosting photocatalytic hydrogen evolution through strong local electric field. Acta Physico-Chimica Sinica, 2026, 42(6): 100193-0. doi: 10.1016/j.actphy.2025.100193
19. [19]
  Qiang Zhang , Yuanbiao Huang , Rong Cao . Imidazolium-Based Materials for CO₂ Electroreduction. Acta Physico-Chimica Sinica, 2024, 40(4): 2306040-0. doi: 10.3866/PKU.WHXB202306040
20. [20]
  Zhiquan Zhang , Baker Rhimi , Zheyang Liu , Min Zhou , Guowei Deng , Wei Wei , Liang Mao , Huaming Li , Zhifeng Jiang . Insights into the Development of Copper-Based Photocatalysts for CO₂ Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2406029-0. doi: 10.3866/PKU.WHXB202406029

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(2594)
HTML views(217)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142