Citation: Quanyi Wang, Yingxu Wei, Shutao Xu, Mozhi Zhang, Shuanghe Meng, Dong Fan, Yue Qi, Jinzhe Li, Zhengxi Yu, Cuiyu Yuan, Yanli He, Shuliang Xu, Jingrun Chen, Jinbang Wang, baolian Su, Zhongmin Liu. Synthesis of mesoporous ZSM-5 using a new gemini surfactant as a mesoporous directing agent：A crystallization transformation process[J]. Chinese Journal of Catalysis, ;2014, 35(10): 1727-1739. doi: 10.1016/S1872-2067(14)60128-5 shu

Synthesis of mesoporous ZSM-5 using a new gemini surfactant as a mesoporous directing agent：A crystallization transformation process

Quanyi Wang ^a,b,e ,
Yingxu Wei ^a,, ,
Shutao Xu ^a ,
Mozhi Zhang ^a,e ,
Shuanghe Meng ^a ,
Dong Fan ^a,e ,
Yue Qi ^a ,
Jinzhe Li ^a ,
Zhengxi Yu ^a ,
Cuiyu Yuan ^a ,
Yanli He ^a ,
Shuliang Xu ^a ,
Jingrun Chen ^a,e ,
Jinbang Wang ^a ,
baolian Su ^b,c,, ,
Zhongmin Liu ^a,d,,

1.
a Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaoning, China;

Corresponding author: Yingxu Wei, baolian Su, Zhongmin Liu,
Received Date: 9 April 2014
Available Online: 28 May 2014
Fund Project:

A new gemini surfactant, [C₁₈H₃₇(CH₃)₂-N⁺-(CH₂)₃-N⁺-(CH₃)₂C₁₈H₃₇]Cl₂ (C_18-3-18), has been successfully used as the mesopore directing agent in the hydrothermal synthesis of mesoporous ZSM-5 (MZSM-5). The synthesis of MZSM-5 was realized with a low temperature crystallization process at 130 ℃. The amount of C_18-3-18 used in the synthesis affected the relative crystallinity and the textural properties of the obtained MZSM-5. Detailed investigation showed that the formation of MZSM-5 followed a crystallization transformation process. The use of C_18-3-18 resulted in the formation of mesoporous material during the early stage of the synthesis, which was converted into MZSM-5 crystals templated by tetrapropylammonium bromide to form the MFI phase. As the synthesis proceeded, the MZSM-5 crystals aggregated into particles by weak interactions. This work shows that C_18-3-18 can be used as a mesopore directing agent, which could provide a route for the synthesis of other mesoporous zeolites.
- Mesoporous ZSM-5,
- Dual-templating,
- Gemini surfactant,
- Inter-crystalline mesopore,
- Crystallization transformation
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