Citation: Abdol R. Hajipour, Hirbod Karimi. Selective oxidation of alcohols over copper zirconium phosphate[J]. Chinese Journal of Catalysis, ;2014, 35(9): 1529-1533. doi: 10.1016/S1872-2067(14)60096-6 shu

Selective oxidation of alcohols over copper zirconium phosphate

Abdol R. Hajipour ^a,b,, ,
Hirbod Karimi ^a

1.
a Pharmaceutical Research Laboratory, Department of Chemistry, Isfahan University of Technology, Isfahan 84156, Iran;

Corresponding author: Abdol R. Hajipour,
Received Date: 21 February 2014
Available Online: 31 March 2014
Fund Project:

The catalytic activity of copper zirconium phosphate (ZPCu) in the selective oxidation of alcohols to their corresponding ketones or aldehydes, using H₂O₂ as an oxidizing agent, was studied. The oxidation reaction was performed without any organic solvent, phase-transfer catalyst, or additive. Steric factors associated with the substrates influenced the reaction. The catalyst was characterized using X-ray diffraction, inductively coupled plasma atomic emission spectroscopy, energy-dispersive X-ray spectroscopy, and scanning electron microscopy. It was shown that the interlayer distance increased from 0.74 to 0.80 nm and the crystallinity was reduced after Cu²⁺ intercalation into the layers. This catalyst can be recovered and reused three times without significant loss of activity and selectivity.
- Copper zirconium phosphate,
- Selective oxidation,
- Solid catalyst,
- Alcohol
1. [1]
  [1] Li F, Wei M, He J, Du Y, Sun P, Evans D G, Duan X. Chin J Catal (李峰, 卫敏, 何静, 杜以波, 孙鹏, Evans D G, 段雪. 催化学报), 1999, 20: 510
2. [2]
  [2] Sun L, Boo W J, Sue H J, Clearfield A. New J Chem, 2007, 31: 39
3. [3]
  [3] Clearfield A. Chem Rev, 1988, 88: 125
4. [4]
  [4] Shi Q S, Tan S Z, Ouyang Y S, Yang Q H, Chen A M, Li W R, Shu X L, Feng J, Fang J, Chen Y B. Adv Mater Res, 2011, 150-151: 852
5. [5]
  [5] Cai X, Dai G J, Tan S Z, Ouyang Y, Ouyang Y S, Shi Q S. Mate Lett, 2012, 67: 199
6. [6]
  [6] Clearfield A, Kalnins J M. J Inorg Nucl Chem, 1978, 40: 1933
7. [7]
  [7] Clearfield A, Kalnins J M. J Inorg Nucl Chem, 1976, 38: 849
8. [8]
  [8] Allulli S, Ferragina C, La Ginestra A, Massucci M A, Tomassini N, Tomlinson A A G. J Chem Soc, Dalton Trans, 1976: 2115
9. [9]
  [9] Khare S, Chokhare R. J Mol Catal A, 2012, 353-354: 138
10. [10]
  [10] Izumi Y, Mizutani Y. Bull Chem Soc Jpn, 1979, 52: 3065
11. [11]
  [11] Khare S, Chokhare R. J Mol Catal A, 2011, 344: 83
12. [12]
  [12] Iwamoto M, Nomura Y, Kagawa S. J Catal, 1981, 69: 234
13. [13]
  [13] Pylinina A I, Mikhalenko I I. Russ J Phys Chem, 2013, 87: 372
14. [14]
  [14] Pylinina A I, Mikhalenko I I. Russ J Phys Chem, 2011, 85: 2109
15. [15]
  [15] Shirini F, Abedini M, Pourvali A. Chin Chem Lett, 2011, 22: 33
16. [16]
  [16] Cheng X Y, Li K F, Wang Q J, Wang C Y, Ying T K. Chin Chem Lett, 2012, 23: 801
17. [17]
  [17] Pourali A R, Tabaean M, Nazifi S M R. Chin Chem Lett, 2012, 23: 21
18. [18]
  [18] Ahmad J U, Räisänen M T, Leskelä M, Repo T. Appl Catal A, 2012, 411-412: 180
19. [19]
  [19] Hu Z Z, Kerton F M. Appl Catal A, 2012, 413-414: 332
20. [20]
  [20] Furukawa S, Tamura A, Shishido T, Teramura K, Tanaka T. Appl Catal B, 2011, 110: 216
21. [21]
  [21] Lingaiah N, Reddy K M, Babu N S, Rao K N, Suryanarayana I, Prasad P S S. Catal Commun, 2006, 7: 245
22. [22]
  [22] Zhou X T, Ji H B. Chin J Catal (周贤太, 纪红兵. 催化学报), 2012, 33: 1906
23. [23]
  [23] Zhang H, Fu L L, Zhong H N. Chin J Catal (张华, 付罗岭, 钟红敏. 催化学报), 2013, 34: 1848
24. [24]
  [24] Zhang H, Liu Y, Zhang X G. Chin J Catal (张海, 刘荣, 张勋高. 催化学报), 2011, 32: 1693
25. [25]
  [25] Ali S R, Chandra P, Latwal M, Jain S K, Bansal V K, Singh S P. Chin J Catal (催化学报), 2011, 32: 1844
26. [26]
  [26] Rao P S N, Rao K T V, Sai Prasad P S, Lingaiah N. Chin J Catal (催化学报), 2011, 32: 1719
27. [27]
  [27] Yang Y H, Dai G J, Tan S Z, Liu Y L, Shi Q S, Ouyang Y S. J Rare Earths, 2011, 29: 308
28. [28]
  [28] Egerton T A, Stone F S. J Chem Soc, Faraday Trans 1, 1973, 69: 22
29. [29]
  [29] Sneddon J. Biochem Pharmacol, 1987, 36: 3723
30. [30]
  [30] Chen S B, Ma Y B, Chen L, Xian K. Geochem J, 2010, 44: 233
31. [31]
  [31] Babu S G, Priyadarsini P A, Karvembu R. Appl Catal A, 2011, 392: 218
32. [32]
  [32] Chen C Y, Liu B, Chen W Z. Synthesis, 2013, 45: 3387
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沈阳化工大学材料科学与工程学院沈阳 110142