Citation: Huimin Liu, Yuming Li, Hao Wu, Weiwei Yang, Dehua He. Effects of Nd, Ce, and La modification on catalytic performance of Ni/SBA-15 catalyst in CO₂ reforming of CH₄[J]. Chinese Journal of Catalysis, ;2014, 35(9): 1520-1528. doi: 10.1016/S1872-2067(14)60095-4 shu

Effects of Nd, Ce, and La modification on catalytic performance of Ni/SBA-15 catalyst in CO₂ reforming of CH₄

1.
Innovative Catalysis Program, Key Laboratory of Organic Optoelectronics and Molecular Engineering of Ministry of Education, Department of Chemistry, Tsinghua University, Beijing 100084, China

Corresponding author: Dehua He,
Received Date: 14 February 2014
Available Online: 25 March 2014
Fund Project:

Rare-earth metal (Nd, Ce, and La) oxides modified Ni/SBA-15 catalysts were prepared by a β-cyclodextrin-modified impregnation method. The physicochemical properties of the catalysts were characterized using X-ray diffraction, N₂ adsorption-desorption, temperature-programmed reduction, and thermogravimetric analysis. The catalytic performance of the catalysts was evaluated in the CO₂ reforming of CH₄ to syngas. The characterization results showed that Nd, Ce, and La modification had little effect on the textural structures and crystalline phases of the obtained catalysts but influenced the reduction of NiO species. Addition of Nd favored interactions between Ni and SiO₂, possibly as a result of the formation of Ni-Nd-O species. The results for the CO₂ reforming of CH₄ revealed that the addition of suitable amounts of Nd (5-10 wt%) improved the catalytic activity and stability. A small amount of carbon was deposited over the used Nd-modified catalysts. The properties of Ni/SBA-15 catalysts modified with La and Ce were similar to those of the Nd-modified catalysts.
- Rare earth metal,
- Nd modification,
- Nickel,
- SBA-15 catalyst,
- Carbon dioxide reforming of methane,
- Carbon deposition
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Effects of Nd, Ce, and La modification on catalytic performance of Ni/SBA-15 catalyst in CO2 reforming of CH4

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通讯作者: 陈斌, bchen63@163.com

Effects of Nd, Ce, and La modification on catalytic performance of Ni/SBA-15 catalyst in CO₂ reforming of CH₄