Citation: Zili Wu. Multi-wavelength Raman spectroscopy study of supported vanadia catalysts：Structure identification and quantification[J]. Chinese Journal of Catalysis, ;2014, 35(10): 1591-1608. doi: 10.1016/S1872-2067(14)60082-6 shu

Multi-wavelength Raman spectroscopy study of supported vanadia catalysts：Structure identification and quantification

Zili Wu ^,

1.
Center for Nanophase Materials Sciences and Chemical Science Division, Oak Ridge National Laboratory, Oak Ridge, TN 37831, USA

Corresponding author: Zili Wu,
Received Date: 28 April 2014
Available Online: 22 May 2014
Fund Project:

Revealing the structure of supported metal oxide catalysts is a prerequisite for establishing the structure-catalysis relationship. Among a variety of characterization techniques, multi-wavelength Raman spectroscopy, combining resonance Raman and non-resonance Raman with different excitation wavelengths, has recently emerged as a particularly powerful tool in not only identifying but also quantifying the structure of supported metal oxide clusters. In this review, we make use of two supported vanadia systems, VO_x/SiO₂ and VO_x/CeO₂, as examples to showcase how one can employ this technique to investigate the heterogeneous structure of active oxide clusters and to understand the complex interaction between the oxide clusters and the support. The qualitative and quantitative structural information gained from the multi-wavelength Raman spectroscopy can be utilized to provide fundamental insights for designing more efficient supported metal oxide catalysts.
- Multi-wavelength,
- Raman spectroscopy,
- Resonance Raman,
- Vanadia,
- Silica,
- Ceria
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