Citation: Miao Jiang, Yunjie Ding, Li Yan, Xiangen Song, Ronghe Lin. Rh catalysts supported on knitting aryl network polymers for the hydroformylation of higher olefins[J]. Chinese Journal of Catalysis, ;2014, 35(9): 1456-1464. doi: 10.1016/S1872-2067(14)60068-1 shu

Rh catalysts supported on knitting aryl network polymers for the hydroformylation of higher olefins

Miao Jiang ^a,c ,
Yunjie Ding ^a,b,, ,
Li Yan ^a ,
Xiangen Song ^a ,
Ronghe Lin ^a

1.
a Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaoning, China;

Corresponding author: Yunjie Ding,
Received Date: 23 January 2014
Available Online: 26 February 2014

Rh catalysts supported on knitting aryl network polymers (Rh/KAPs) were prepared for the hydroformylation of higher olefins. Rh catalysts supported on triphenylphosphine-benzene-base polymers (Rh/KAPs-1) showed higher activity for the higher olefins than Rh/SiO₂ catalysts. Fourier transform infrared spectroscopy, thermogravimetry, N₂ adsorption-desorption, X-ray diffraction, transmission electron microscopy, ¹³C NMR, and ³¹P NMR showed that the Rh/KAPs-1 catalysts have high thermal stability, high surface area, hierarchical porosity, highly dispersed Rh nanoparticles, and in situ formed homogeneous active species during the reaction.
- Triphenylphosphine,
- Knitting aryl network polymer,
- Rhodium,
- Heterogeneous catalyst,
- Hydroformylation of higher olefins
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沈阳化工大学材料科学与工程学院沈阳 110142