Citation: Fubao Zhang, Xiaopeng Yu, Fei Ma, Xiangui Yang, Jing Hu, Zhiyong Deng, Gongying Wang. Transesterification of dimethyl oxalate with phenol over a MoO₃/SiO₂ catalyst prepared by thermal spreading[J]. Chinese Journal of Catalysis, ;2014, 35(7): 1043-1053. doi: 10.1016/S1872-2067(14)60042-5 shu

Transesterification of dimethyl oxalate with phenol over a MoO₃/SiO₂ catalyst prepared by thermal spreading

Fubao Zhang ^a,c ,
Xiaopeng Yu ^b ,
Fei Ma ^a,d ,
Xiangui Yang ^a,d ,
Jing Hu ^a,d ,
Zhiyong Deng ^a,d,, ,
Gongying Wang ^a,d,,

1.
a. Chengdu Institute of Organic Chemistry, Chinese Academy of Sciences, Chengdu 610041, Sichuan, China;

Corresponding author: Zhiyong Deng, Gongying Wang,
Received Date: 7 December 2013
Available Online: 20 January 2014
Fund Project:

MoO₃/SiO₂ catalysts for the transesterification of dimethyl oxalate (DMO) with phenol were prepared by both the thermal spreading (TS) and incipient wetness impregnation methods. The results showed that the 10%MoO₃/SiO₂ catalyst prepared by TS (10%MoO₃/SiO₂-TS) exhibited higher catalytic performance compared with the 10%MoO₃/SiO₂ catalyst prepared by incipient wetness impregnation (10%MoO₃/SiO₂-C). The catalysts were characterized by X-ray diffraction, Raman spectroscopy, X-ray photoelectron spectroscopy, pyridine-IR spectroscopy, and NH₃ temperature-programmed desorption. These analyses indicated that weak Lewis acid sites were formed on the catalyst surfaces and that the Mo species were present as monomeric MoO₃ rather than as isolated molybdenum oxide or polymolybdate species on both catalysts, although the 10%MoO₃/SiO₂-TS exhibited better dispersion of MoO₃ and a higher surface Mo content than the 10%MoO₃/SiO₂-C. Under the optimal transesterification reaction conditions (1.2 g 10%MoO₃/SiO₂-TS, T=180℃, n(DMO)/n(phenol)=2, t=4 h), the conversion of phenol was 70.9%, and the yields of methyl phenyl oxalate and diphenyl oxalate were 63.1% and 7.7%, respectively.
- Thermal spreading method,
- MoO₃/SiO₂ catalyst,
- Methyl phenyl oxalate,
- Diphenyl oxalate,
- Transesterification
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沈阳化工大学材料科学与工程学院沈阳 110142

Transesterification of dimethyl oxalate with phenol over a MoO3/SiO2 catalyst prepared by thermal spreading

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Transesterification of dimethyl oxalate with phenol over a MoO₃/SiO₂ catalyst prepared by thermal spreading