Citation: Xi Zhou, Xin Ge, Rongzhi Tang, Tong Chen, Gongying Wang. Preparation and catalytic property of modified multi-walled carbon nanotube-supported TiO₂ for the transesterification of dimethyl carbonate with phenol[J]. Chinese Journal of Catalysis, ;2014, 35(4): 481-489. doi: 10.1016/S1872-2067(14)60010-3 shu

Preparation and catalytic property of modified multi-walled carbon nanotube-supported TiO₂ for the transesterification of dimethyl carbonate with phenol

Xi Zhou ^a,b ,
Xin Ge ^a ,
Rongzhi Tang ^a ,
Tong Chen ^a,, ,
Gongying Wang ^a,,

1.
a Chengdu Institute of Organic Chemistry, Chinese Academy of Sciences, Chengdu 610041, Sichuan, China;

Corresponding author: Tong Chen, Gongying Wang,
Received Date: 7 November 2013
Available Online: 24 December 2013
Fund Project: 国家高技术研究发展计划(863计划, SS2013AA031703) (863计划, SS2013AA031703)四川省青年科技创新研究团队(2013TD0010). (2013TD0010)

Modified multi-walled carbon nanotube-supported TiO₂ samples were prepared and used as an efficient heterogeneous catalyst for the transesterification of dimethyl carbonate with phenol. The catalysts were characterized by X-ray photoelectron spectroscopy, transmission electron microscopy, N₂ adsorption-desorption, and X-ray powder diffraction. The results showed that the catalyst, which was prepared using a low concentration (0.4%) of ammonium hydroxide as the precipitant instead of ionized water, had better catalytic activity, separability, and reusability properties. The effects of the TiO₂ loading, amount of catalyst and reaction time on the performance of the transesterification reaction were also studied. Under the optimum reaction conditions, the conversion of phenol reached 42.5% with over 99.9% selectivity for methyl phenyl carbonate and diphenyl carbonate. The catalyst could be reused for the transesterification in four runs with only slight loss of its catalytic activity.
- Multi-walled carbon nanotube,
- Titanium dioxide,
- Diphenyl carbonate,
- Transesterification,
- Precipitant
1. [1]
  [1] Shaikh A A G, Sivaram S. Chem Rev, 1996, 96: 951
2. [2]
  [2] Ronchin L, Vavasori A, Amadio E, Cavinato G, Toniolo L. J Mol Catal A, 2009, 298: 23
3. [3]
  [3] Yang X J, Han J Y, Du Z P, Yuan H, Jin F, Wu Y X. Catal Commun, 2010, 11: 643
4. [4]
  [4] Yalfani M S, Lolli G, Wolf A, Mleczko L, Müller T E, Leitner W. Green Chem, 2013, 15: 1146
5. [5]
  [5] Yuan X L, Zhang M, Chen X D, An N H, Liu G, Liu Y, Zhang W X, Yan W F, Jia M J. Appl Catal A, 2012, 439-440: 149
6. [6]
  [6] Cao P, Yang J, Yang X G, Yao J, Wang Y, Wang G Y. Chin J Catal (曹平, 杨建, 杨先贵, 姚洁, 王越, 王公应. 催化学报), 2009, 30: 65
7. [7]
  [7] Chen T, Han H J, Yao J, Wang G Y. Catal Commun, 2007, 8: 1361
8. [8]
  [8] Deshmukh K M, Qureshi Z S, Dhake K P, Bhanage B M. Catal Commun, 2010, 12: 207
9. [9]
  [9] Niu H Y, Yao J, Wang Y, Wang G Y. Catal Commun, 2007, 8: 355
10. [10]
  [10] Du Z P, Xiao Y H, Chen T, Wang G Y. Catal Commun, 2008, 9: 239.
11. [11]
  [11] Niu H Y, Guo H M, Yao J, Wang Y, Wang G Y. J Mol Catal A, 2006, 259: 292
12. [12]
  [12] Kim W B, Lee J S. J Catal, 1999, 185: 307
13. [13]
  [13] Tong D S, Chen T, Yao J, Wang Y, Wang G Y, Shi D C, Li Z, Chen Z M. Chin J Catal (童东绅, 陈彤, 姚洁, 王越, 王公应, 石大川, 李正, 陈志明. 催化学报), 2007, 28: 190
14. [14]
  [14] Tong D S, Yao J, Wang Y, Niu H Y, Wang G Y. J Mol Catal A, 2007, 268: 120
15. [15]
  [15] Cao M, Meng Y Z, Lu Y X. Catal Commun, 2005, 6: 802
16. [16]
  [16] Li Z H, Wang Y J, Ding X S, Zhao X Q. J Nat Gas Chem, 2009, 18: 104
17. [17]
  [17] Li Z H, Cheng B W, Su K M, Gu Y, Xi P, Guo M L. J Mol Catal A, 2008, 289: 100
18. [18]
  [18] Zhou W Q, Zhao X Q, Wang Y J, Zhang J Y. Appl Catal A, 2004, 260: 19
19. [19]
  [19] Wang S, Bai R X, Mei F M, Li G X. Catal Commun, 2009, 11: 202
20. [20]
  [20] Kim Y T, Park E D. Appl Catal A, 2009, 356: 211
21. [21]
  [21] Li B J, Tang R Z, Chen T, Wang G Y. Chin J Catal (李碧静, 唐荣芝, 陈彤, 王公应. 催化学报), 2012, 33: 601
22. [22]
  [22] Zhang X Y, Ma Q, Cheng B B, Wang J, Li J S, Nie F D. J Nat Gas Chem, 2012, 21: 774
23. [23]
  [23] Intarapong P, Iangthanarat S, Phanthong P, Luengnaruemitchai A, Jai-In S. J Energy Chem, 2013, 22: 690
24. [24]
  [24] Nigrovski B, Zavyalova U, Scholz P, Pollok K, Müller M, Ondruschka B. Carbon, 2008, 46: 1678
25. [25]
  [25] Kang J C, Deng W P, Zhang Q H, Wang Y. J Energy Chem, 2013, 22: 321
26. [26]
  [26] Karimi A, Nasernejad B, Rashidi A M. J Energy Chem, 2013, 22: 582
27. [27]
  [27] Ge X, Li B J, Hu J, Chen T, Wang G Y, Hu X T. Acta Chim Sin (葛鑫, 李碧静, 胡静, 陈彤, 王公应, 胡徐腾. 化学学报), 2011, 69: 2328
28. [28]
  [28] Ge X, Li B J, Hu J, Chen T, Wang G Y, Hu X T. Chem Eng (China) (葛鑫, 李碧静, 胡静, 陈彤, 王公应, 胡徐腾. 化学工程), 2011, 39: 61.
29. [29]
  [29] Kim W B, Lee J S. Catal lett, 1999, 59: 83
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沈阳化工大学材料科学与工程学院沈阳 110142

Preparation and catalytic property of modified multi-walled carbon nanotube-supported TiO2 for the transesterification of dimethyl carbonate with phenol

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通讯作者: 陈斌, bchen63@163.com

Preparation and catalytic property of modified multi-walled carbon nanotube-supported TiO₂ for the transesterification of dimethyl carbonate with phenol