Citation: Xi Zhou, Xin Ge, Rongzhi Tang, Tong Chen, Gongying Wang. Preparation and catalytic property of modified multi-walled carbon nanotube-supported TiO₂ for the transesterification of dimethyl carbonate with phenol[J]. Chinese Journal of Catalysis, ;2014, 35(4): 481-489. doi: 10.1016/S1872-2067(14)60010-3 shu

Preparation and catalytic property of modified multi-walled carbon nanotube-supported TiO₂ for the transesterification of dimethyl carbonate with phenol

Xi Zhou ^a,b ,
Xin Ge ^a ,
Rongzhi Tang ^a ,
Tong Chen ^a,, ,
Gongying Wang ^a,,

1.
a Chengdu Institute of Organic Chemistry, Chinese Academy of Sciences, Chengdu 610041, Sichuan, China;

Corresponding author: Tong Chen, Gongying Wang,
Received Date: 7 November 2013
Available Online: 24 December 2013
Fund Project: 国家高技术研究发展计划(863计划, SS2013AA031703) (863计划, SS2013AA031703)四川省青年科技创新研究团队(2013TD0010). (2013TD0010)

Modified multi-walled carbon nanotube-supported TiO₂ samples were prepared and used as an efficient heterogeneous catalyst for the transesterification of dimethyl carbonate with phenol. The catalysts were characterized by X-ray photoelectron spectroscopy, transmission electron microscopy, N₂ adsorption-desorption, and X-ray powder diffraction. The results showed that the catalyst, which was prepared using a low concentration (0.4%) of ammonium hydroxide as the precipitant instead of ionized water, had better catalytic activity, separability, and reusability properties. The effects of the TiO₂ loading, amount of catalyst and reaction time on the performance of the transesterification reaction were also studied. Under the optimum reaction conditions, the conversion of phenol reached 42.5% with over 99.9% selectivity for methyl phenyl carbonate and diphenyl carbonate. The catalyst could be reused for the transesterification in four runs with only slight loss of its catalytic activity.
- Multi-walled carbon nanotube,
- Titanium dioxide,
- Diphenyl carbonate,
- Transesterification,
- Precipitant
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沈阳化工大学材料科学与工程学院沈阳 110142

Preparation and catalytic property of modified multi-walled carbon nanotube-supported TiO2 for the transesterification of dimethyl carbonate with phenol

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通讯作者: 陈斌, bchen63@163.com

Preparation and catalytic property of modified multi-walled carbon nanotube-supported TiO₂ for the transesterification of dimethyl carbonate with phenol