Citation: ZHANG Wenfei, LIANG Jinhua, LIU Yanqiu, SUN Shoufei, REN Xiaoqian, JIANG Min. Knoevenagel condensation reaction over acid-base bifunctional MgO/HMCM-22 catalysts[J]. Chinese Journal of Catalysis, ;2013, 34(3): 559-566. doi: 10.1016/S1872-2067(11)60493-2 shu

Knoevenagel condensation reaction over acid-base bifunctional MgO/HMCM-22 catalysts

1.
a College of Chemistry and Chemical Engineering, Nanjing University of Technology, Nanjing 210009, Jiangsu, China;

Corresponding author: REN Xiaoqian,
Received Date: 30 September 2012
Available Online: 26 November 2012
Fund Project: 国家重点基础研究发展计划(973计划, 2009CB724701) (973计划, 2009CB724701) 国家高技术研究发展计划(863计划, 2011AA02A203) (863计划, 2011AA02A203) 江苏省博士后科研资助计划(1001016C). (1001016C)

MgO/HMCM-22 catalysts were prepared by impregnation and characterized by X-ray diffraction, N₂ physical adsorption-desorption, scanning electron microscopy, Fourier-transform infrared spectroscopy, temperature-programmed desorption of NH₃, and temperature-programmed desorption of CO₂. The results show that there were no significant structural changes in theMCM-22 zeolite after modification. Increasing the MgO loading increased the strength and content of the base, whereas the strength of the strong acid decreased significantly and the amount of weak acidic sites increased slightly. Knoevenagel condensation reactions were carried out as the probe reactions over the catalysts. Both acidic sites and basic sites significantly promoted the reaction. The conversion of benzaldehyde reached 92.6% under the optimal conditions. The catalytic performance of MgO/HMCM-22 and MgO/NaMCM-22 was better than that of HMCM-22 and MgO. The MgO/HMCM-22 catalysts gave good catalytic performance for Knoevenagel condensation reactions and exhibited obvious acid-base synergetic effects.
- MCM-22 zeolite,
- Magnesium oxide,
- Impregnation,
- Acid-base bifunction,
- Knoevenagel condensation reaction
1. [1]
  [1] Zhang X F, Lai E S M, Martin-Aranda R, Yeung K L. Appl Catal A, 2004, 261: 109
2. [2]
  [2] Bigi F, Chesini L, Maggi R, Sartori G. J Org Chem, 1999, 64: 1033
3. [3]
  [3] Parida K M, Rath D. J Mol Catal A, 2009, 310: 93
4. [4]
  [4] Hein R W, Astle M J, Shelton R J. J Org Chem, 1961, 26: 4874
5. [5]
  [5] Lan D X, Lin D, Zhao H M, Ma L, Chun Y. Chin J Catal (蓝冬雪, 林丹, 赵会民, 马丽, 淳远. 催化学报), 2011, 32: 1214
6. [6]
  [6] Shao Y Q, Guan J Q, Wu S J, Liu H, Liu B, Kan Q B. Microporous Mesoporous Mater, 2010, 128: 120
7. [7]
  [7] Macario A, Giordano G, Onida B, Cocina D, Tagarelli A, Giuffrè A M. Appl Catal A, 2010, 378: 160
8. [8]
  [8] Vermoortele F, Ameloot R, Vimont A, Serre C, Vos D D. ChemCommun, 2011,47: 1521
9. [9]
  [9] Hruby S L, Shanks B H. J Catal, 2009, 263: 181
10. [10]
  [10] Climent M J, Corma A, Iborra S, Velty A. J Mol Catal A,2002, 182-183: 327
11. [11]
  [11] Peng Y, Wang J Y, Long J, Liu G H. Catal Commun, 2011, 15: 10
12. [12]
  [12] Postole G, Chowdhury B, Karmakar B, Pinki K, Banerji J, Auroux A. J Catal, 2010, 269: 110
13. [13]
  [13] Keita I, Nao M, Takayuki T, Masato M. Catal Lett, 2011, 141: 877
14. [14]
  [14] Wang T, Wu G J, Guan N J, Li L D. Microporous Mesoporous Mater, 2012, 148: 184
15. [15]
  [15] Yu Zh W, Wang Q, Chen L, Deng F. Chin J Catal (喻志武, 王强, 陈雷, 邓风. 催化学报), 2012, 33: 129
16. [16]
  [16] Chu N B, Wang J Q, Zhang Y, Yang J H, Lu J M, Yin D H. Chem Mater, 2010, 22: 2757
17. [17]
  [17] Laforge S, Martin D, Guisnet M. Microporous Mesoporous Mater, 2004, 67: 235
18. [18]
  [18] Wu Y J, Ren X Q, Lu Y D, Wang J. Microporous Mesoporous Mater, 2008, 112: 138
19. [19]
  [19] Shang Y C, Yang P P, Jia M J, Zhang W X, Wu T H. Catal Commun, 2008, 9: 907
20. [20]
  [20] Shu Y Y, Ma D, Xu L Y, Xu Y D, Bao X H. Catal Lett, 2000, 70: 67
21. [21]
  [21] Jain D, Khatri C, Rani A. Fuel Process Technol, 2010, 91: 1015
22. [22]
  [22] Corma A, Corell C, Fornés V, Kolodziejski W, Pérez-Pariente J. Zeolite, 1995, 15: 576
23. [23]
  [23] Kumara G S, Saravanamurugan S, Hartmann M, Palanichamy M, Murugesan V. J Mol Catal A, 2007, 272: 38
24. [24]
  [24] Liu Z Y, Zhu Z B, Wang R Y, Zhu X D. Chin J Catal (刘子玉, 朱子彬, 王仁远, 朱学栋. 催化学报), 2008, 29: 928
25. [25]
  [25] Pappas G S, Liatsi P, Kartsonakis I A, Danilidis I, Kordas G. J Non-Cryst Solids, 2008, 354: 755
26. [26]
  [26] Sakthivel A, Komura K, Huang S J, Wu P H, Liu S B, Sasaki Y, Sugi Y. Ind Eng Chem Res, 2010, 49: 65
27. [27]
  [27] Xu Q L, Li T C, Yan Y J. J Fuel Chem Technol, 2008, 36: 181
28. [28]
  [28] Xue B, Li Y X, Deng L J. Catal Commun, 2009, 10: 1609
29. [29]
  [29] Rodriguez I, Sastre G, Corma A, Iborra S. J Catal, 1999, 183: 14
30. [30]
  [30] Corma A, Fornés V, Martín-Aranda R M, García H, Primo J. Appl Catal, 1990, 59: 237
31. [31]
  [31] Gupta R, Gupta M, Paul S, Gupta R. Bull Korean Chem Soc, 2009, 30: 2419
1. [1]
  Xiaosong PU , Hangkai WU , Taohong LI , Huijuan LI , Shouqing LIU , Yuanbo HUANG , Xuemei LI . Adsorption performance and removal mechanism of Cd(Ⅱ) in water by magnesium modified carbon foam. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1537-1548. doi: 10.11862/CJIC.20240030
2. [2]
  Yufang GAO , Nan HOU , Yaning LIANG , Ning LI , Yanting ZHANG , Zelong LI , Xiaofeng LI . Nano-thin layer MCM-22 zeolite: Synthesis and catalytic properties of trimethylbenzene isomerization reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1079-1087. doi: 10.11862/CJIC.20240036
3. [3]
  Zhenghua ZHAO , Qin ZHANG , Yufeng LIU , Zifa SHI , Jinzhong GU . Syntheses, crystal structures, catalytic and anti-wear properties of nickel(Ⅱ) and zinc(Ⅱ) coordination polymers based on 5-(2-carboxyphenyl)nicotinic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 621-628. doi: 10.11862/CJIC.20230342
4. [4]
  Weizhong LING , Xiangyun CHEN , Wenjing LIU , Yingkai HUANG , Yu LI . Syntheses, crystal structures, and catalytic properties of three zinc(Ⅱ), cobalt(Ⅱ) and nickel(Ⅱ) coordination polymers constructed from 5-(4-carboxyphenoxy)nicotinic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1803-1810. doi: 10.11862/CJIC.20240068
5. [5]
  Jimin HOU , Mengyang LI , Chunhua GONG , Shaozhuang ZHANG , Caihong ZHAN , Hao XU , Jingli XIE . Synthesis, structures, and properties of metal-organic frameworks based on bipyridyl ligands and isophthalic acid. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 549-560. doi: 10.11862/CJIC.20240348
6. [6]
  Pei Li , Yuenan Zheng , Zhankai Liu , An-Hui Lu . Boron-Containing MFI Zeolite: Microstructure Control and Its Performance of Propane Oxidative Dehydrogenation. Acta Physico-Chimica Sinica, 2025, 41(4): 2406012-0. doi: 10.3866/PKU.WHXB202406012
7. [7]
  Hong Lu , Yidie Zhai , Xingxing Cheng , Yujia Gao , Qing Wei , Hao Wei . Advancements and Expansions in the Proline-Catalyzed Asymmetric Aldol Reaction. University Chemistry, 2024, 39(5): 154-162. doi: 10.3866/PKU.DXHX202310074
8. [8]
  Yong Shu , Xing Chen , Sai Duan , Rongzhen Liao . How to Determine the Equilibrium Bond Distance of Homonuclear Diatomic Molecules: A Case Study of H₂. University Chemistry, 2024, 39(7): 386-393. doi: 10.3866/PKU.DXHX202310102
9. [9]
  Wenhui Li , Changshuo Zhu , Xinyu Cui , Chenfei Zhao , Lina Qiu , Yan Li , Chuandong Wu , Min Yang , Yuan Zhuang . Visual Determination of Acid-Base Titration Endpoints Using Smartphone APP-Based Analysis. University Chemistry, 2025, 40(7): 328-335. doi: 10.12461/PKU.DXHX202409062
10. [10]
  Yuhao SUN , Qingzhe DONG , Lei ZHAO , Xiaodan JIANG , Hailing GUO , Xianglong MENG , Yongmei GUO . Synthesis and antibacterial properties of silver-loaded sod-based zeolite. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 761-770. doi: 10.11862/CJIC.20230169
11. [11]
  Jiali CHEN , Guoxiang ZHAO , Yayu YAN , Wanting XIA , Qiaohong LI , Jian ZHANG . Machine learning exploring the adsorption of electronic gases on zeolite molecular sieves. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 155-164. doi: 10.11862/CJIC.20240408
12. [12]
  Yiping HUANG , Liqin TANG , Yufan JI , Cheng CHEN , Shuangtao LI , Jingjing HUANG , Xuechao GAO , Xuehong GU . Hollow fiber NaA zeolite membrane for deep dehydration of ethanol solvent by vapor permeation. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 225-234. doi: 10.11862/CJIC.20240224
13. [13]
  Xin Feng , Kexin Guo , Chunguang Jia , Bowen Liu , Suqin Ci , Junxiang Chen , Zhenhai Wen . Hydrogen Generation Coupling with High-Selectivity Electrocatalytic Glycerol Valorization into Formate in an Acid-Alkali Dual-Electrolyte Flow Electrolyzer. Acta Physico-Chimica Sinica, 2024, 40(5): 2303050-0. doi: 10.3866/PKU.WHXB202303050
14. [14]
  Nana Wang , Gaosheng Zhang , Huosheng Li , Tangfu Xiao . Discussion on the Teaching Reform of Environmental Functional Materials within the Context of “Double First-Class” Initiative: Emphasizing the Integration of Industry, Academia, Research, and Application. University Chemistry, 2024, 39(6): 137-144. doi: 10.3866/PKU.DXHX202312010
15. [15]
  Qiaoqiao BAI , Anqi ZHOU , Xiaowei LI , Tang LIU , Song LIU . Construction of pressure-temperature dual-functional flexible sensors and applications in biomedicine. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2259-2274. doi: 10.11862/CJIC.20240128
16. [16]
  Xueting Cao , Shuangshuang Cha , Ming Gong . Interfacial Electrical Double Layer in Electrocatalytic Reactions: Fundamentals, Characterizations and Applications. Acta Physico-Chimica Sinica, 2025, 41(5): 100041-0. doi: 10.1016/j.actphy.2024.100041
17. [17]
  Weicheng Feng , Jingcheng Yu , Yilan Yang , Yige Guo , Geng Zou , Xiaoju Liu , Zhou Chen , Kun Dong , Yuefeng Song , Guoxiong Wang , Xinhe Bao . Regulating the High Entropy Component of Double Perovskite for High-Temperature Oxygen Evolution Reaction. Acta Physico-Chimica Sinica, 2024, 40(6): 2306013-0. doi: 10.3866/PKU.WHXB202306013
18. [18]
  Shanghua Li , Malin Li , Xiwen Chi , Xin Yin , Zhaodi Luo , Jihong Yu . High-Stable Aqueous Zinc Metal Anodes Enabled by an Oriented ZnQ Zeolite Protective Layer with Facile Ion Migration Kinetics. Acta Physico-Chimica Sinica, 2025, 41(1): 100003-0. doi: 10.3866/PKU.WHXB202309003
19. [19]
  Qiangqiang SUN , Pengcheng ZHAO , Ruoyu WU , Baoyue CAO . Multistage microporous bifunctional catalyst constructed by P-doped nickel-based sulfide ultra-thin nanosheets for energy-efficient hydrogen production from water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1151-1161. doi: 10.11862/CJIC.20230454
20. [20]
  Qianli Ma , Tianbing Song , Tianle He , Xirong Zhang , Huanming Xiong . Sulfur-doped carbon dots: a novel bifunctional electrolyte additive for high-performance aqueous zinc-ion batteries. Acta Physico-Chimica Sinica, 2025, 41(9): 100106-0. doi: 10.1016/j.actphy.2025.100106

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(435)
HTML views(47)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142