Citation: ZHANG Xiaoliang, SONG Xin, QIU Lingfang, DING Minzheng, HU Na, ZHOU Rongfei, CHEN Xiangshu. Synthesis and pervaporation performance of highly reproducible zeolite T membranes from clear solutions[J]. Chinese Journal of Catalysis, ;2013, 34(3): 542-547. doi: 10.1016/S1872-2067(11)60478-6 shu

Synthesis and pervaporation performance of highly reproducible zeolite T membranes from clear solutions

1.
Jiangxi Inorganic Membrane Materials Engineering Research Centre, College of Chemistry and Chemical Engineering, Jiangxi Normal University, Nanchang 330022, Jiangxi, China

Corresponding author: CHEN Xiangshu,
Received Date: 5 September 2012
Available Online: 12 October 2012
Fund Project: 国家自然科学基金(20966003,21106059) (20966003,21106059)国家高技术研究发展计划(863计划,2012AA03A609) (863计划,2012AA03A609)江西省科技支撑计划重点项目和自然科学基金(2010BGA01200,2010GQH0068,20122BAB203018) (2010BGA01200,2010GQH0068,20122BAB203018)江西省教育厅科技项目(GJJ11377). (GJJ11377)

Zeolite T membranes with very good permeation performance were successfully synthesized on porous mullite supports by the secondary growth method with homemade microsized seeds from clear solutions. The influence of synthesis parameters such as the molar ratios of SiO₂/Al₂O₃ and H₂O/SiO₂, alkalinity, synthesis temperature, and crystallization time on membrane growth and permeation performance was investigated systematically. It is found that these parameters strongly affect the zeolite T growth and pervaporation performance of the membranes. Under the optimized synthesis conditions of 1SiO₂:0.015Al₂O₃:0.41(Na₂O+K₂O):30H₂O, the crystallization time was shortened to 6 h at 423 K and a continuous and dense T-type zeolite layer as thin as 5 μm formed on the surface of the support. It significantly improved the membrane density and permselective properties. A permeation flux and separation factor of 4.20 kg/(m²·h) and 7800, respectively, were obtained with the as-synthesized membrane for 10 wt% water-90 wt% i-propanol mixtures at 348 K. It also exhibited a very good pervaporation performance for water/ethanol mixtures separation. This high quality zeolite T membrane could be reproducibly prepared.
- Zeolite T membrane,
- Reproducibility,
- Clear solution,
- Secondary growth,
- Pervaporation
1. [1]
  [1] Drioli E, Fontananova E, Bonchio M, Carraro M, Gardan M, Scorrano G. Chin J Catal (催化学报), 2008, 29: 1152
2. [2]
  [2] Zhang X L, Wang W P, Xiong G X, Yang W Sh. Chin J Catal (张小亮, 王卫平, 熊国兴, 杨维慎. 催化学报), 2010, 31: 1049
3. [3]
  [3] Li X M, Wang Zh B, Zheng J, Shao Sh Q, Wang Y Ch, Yan Y Sh. Chin J Catal (李显明, 王正宝, 郑洁, 邵世群, 王胤超, 严玉山. 催化学报), 2011, 32: 217
4. [4]
  [4] Cui Y, Kita H, Okamoto K I. Chem Commun, 2003: 2154
5. [5]
  [5] Cui Y, Kita H, Okamoto K I. J Mater Chem, 2004, 14: 924
6. [6]
  [6] Cui Y, Kita H, Okamoto K I. J Membr Sci, 2004, 236: 17
7. [7]
  [7] Kondo M, Kita H. J Membr Sci, 2010, 361: 223
8. [8]
  [8] Mirfendereski M, Sadrzadeh M, Mohammadi T. Int J Greenhouse Gas Control, 2008, 2: 531
9. [9]
  [9] Mirfendereski S M, Mazaheri T, Sadrzadeh M, Mohammadi T. Sep Purif Technol, 2008, 61: 317
10. [10]
  [10] Zhou H, Li Y Sh, Zhu G Q, Liu J, Lin L W, Yang W Sh. Chin J Catal (周汉, 李砚硕, 朱广奇, 刘杰, 林励吾, 杨维慎. 催化学报), 2008, 29: 592
11. [11]
  [11] Zhou H, Li Y S, Zhu G Q, Liu J, Yang W S. Sep Purif Technol, 2009, 65: 164
12. [12]
  [12] Zhou R F, Chen X Sh, Liu D, Qi H, Lin X, Xu N P. J Chin Ceram Soc (周荣飞, 陈祥树, 刘丹, 漆虹, 林晓, 徐南平. 硅酸盐学报), 2007, 35: 1270
13. [13]
  [13] Zhou R F, Hu N, Yuan H, Zhu M H, Wang Zh Zh, Chen X Sh. J Chin Inorg Chem (周荣飞, 胡娜, 袁慧, 朱美华, 王振卓, 陈祥树. 无机化学学报), 2009, 25: 1439
14. [14]
  [14] Zhou R F, Zhang F, Hu N, Chen X S, Kita H. Chem Lett, 2011, 40: 1383
15. [15]
  [15] Zhang X L, Song X, Qiu L F, Zhou R F, Chen X Sh. Chin J Inorg Chem (张小亮, 宋鑫, 邱灵芳, 周荣飞, 陈祥树. 无机化学学报), 2012, 28: 1914
16. [16]
  [16] Breck D W, Acara N A. US Patent 2 950 952. 1960
17. [17]
  [17] Wang X Q, Chen Zh C, He Sh H, Mao Y G, Li Sh, Song T Y, Xu R R. Chem J Chin Univ (王杏乔, 陈忠财, 何淑华, 毛友刚, 李舒, 宋天佑, 徐如人. 高等学校化学学报), 1984, 5: 83
18. [18]
  [18] Occelli M L, Innes R A, Pollack S S, Sanders J V. Zeolites, 1987, 7: 265
19. [19]
  [19] Cichocki A. Zeolites, 1991, 11: 758
20. [20]
  [20] Ueda S, Nishimura M, Koizumi M. Stud Surf Sci Catal, 1985, 24: 105
21. [21]
  [21] Matin K T, Bastani D, Kazemian H. Chem Eng Technol, 2009, 32: 1042
22. [22]
  [22] Mirfendereski M, Mohammadi T. Powder Technol, 2011, 206: 345
23. [23]
  [23] Yu J H. Stud Surf Sci Catal, 2007, 168: 39
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沈阳化工大学材料科学与工程学院沈阳 110142