Synthesis and crystal structure of Ni, Cu complexes of 5-methyl-10,10,15,15,20,20-hexaethylcalix[4]pyrrole mono-Schiff bases

Citation: Juan-Juan Sun, Ying Han, Jing Sun, Chao-Guo Yan. Synthesis and crystal structure of Ni, Cu complexes of 5-methyl-10,10,15,15,20,20-hexaethylcalix[4]pyrrole mono-Schiff bases[J]. Chinese Chemical Letters, 2015, 26(6): 685-689. doi: 10.1016/j.cclet.2015.03.028 shu

Synthesis and crystal structure of Ni, Cu complexes of 5-methyl-10,10,15,15,20,20-hexaethylcalix[4]pyrrole mono-Schiff bases

通讯作者: Ying Han,
Chao-Guo Yan,

基金项目:
This work was financially supported by the National Natural Science Foundation of China (No. 21172190) (No. 21172190)

摘要: The functionalized calix[4]pyrrole meso-substituted Schiff bases were conveniently prepared by fourstep synthetic route. Furthermore, the nickel and copper complexes of calix[4]pyrrolemeso-substituted Schiff base with 1:2 stoichiometry were obtained. The crystal structures of the calix[4]pyrroles and their metal complexes were determined by X-ray diffraction.

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English

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