Characterization and reactivity of γ-Al2O3 supported Pd-Ni bimetallic nanocatalysts for selective hydrogenation of cyclopentadiene

Citation: Yi-Si Feng, Jian Hao, Wei-Wei Liu, Yun-Jin Yao, Yue Cheng, Hua-Jian Xu. Characterization and reactivity of γ-Al₂O₃ supported Pd-Ni bimetallic nanocatalysts for selective hydrogenation of cyclopentadiene[J]. Chinese Chemical Letters, 2015, 26(6): 709-713. doi: 10.1016/j.cclet.2015.03.006 shu

Characterization and reactivity of γ-Al₂O₃ supported Pd-Ni bimetallic nanocatalysts for selective hydrogenation of cyclopentadiene

通讯作者: Hua-Jian Xu,

基金项目:
We are grateful to the financial assistance from the National Natural Science Foundation of China (Nos. 21272050, 21371044, 21472033) (Nos. 21272050, 21371044, 21472033)

the Program for New Century Excellent Talents in University of the Chinese Ministry of Education (No. NCET-11-0627). (No. NCET-11-0627)

摘要: Several γ-Al₂O₃ supported Pd-Ni bimetallic nanocatalysts (Pd-Ni (x:y)/Al₂O₃; where x and y represent the mass ratio of Pd and Ni, respectively) were prepared by the impregnation method and used for selective hydrogenation of cyclopentadiene to cyclopentene. The Pd-Ni/Al₂O₃ samples were confirmed to generate Pd-Ni bimetallic nanoparticles by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS) and transmission electron microscopy (TEM). The catalytic activity was assessed in view of the effects of different mass ratios of Pd and Ni, temperature, pressure, etc. Among all the samples, the Pd-Ni (1:1)/Al₂O₃ (PN-1:1) catalyst showed extremely high catalytic ability. The conversion of cyclopentadiene and selectivity for cyclopentene can be simultaneously more than 90%.

关键词:

English

Characterization and reactivity of γ-Al₂O₃ supported Pd-Ni bimetallic nanocatalysts for selective hydrogenation of cyclopentadiene

1.
a School of Chemistry and Chemical Engineering, School of Medical Engineering, Hefei University of Technology, Hefei 230009, China;
2.
b Anhui Key Laboratory of Controllable Chemical Reaction & Material Chemical Engineering, Hefei 230009, China;
3.
c Anhui Provincial Laboratory of Heterocyclic Chemistry, Maanshan 243110, China

Corresponding author: Hua-Jian Xu,

Received Date: 26 December 2014
Available Online: 09 March 2015
Fund Project:

Abstract: Several γ-Al₂O₃ supported Pd-Ni bimetallic nanocatalysts (Pd-Ni (x:y)/Al₂O₃; where x and y represent the mass ratio of Pd and Ni, respectively) were prepared by the impregnation method and used for selective hydrogenation of cyclopentadiene to cyclopentene. The Pd-Ni/Al₂O₃ samples were confirmed to generate Pd-Ni bimetallic nanoparticles by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS) and transmission electron microscopy (TEM). The catalytic activity was assessed in view of the effects of different mass ratios of Pd and Ni, temperature, pressure, etc. Among all the samples, the Pd-Ni (1:1)/Al₂O₃ (PN-1:1) catalyst showed extremely high catalytic ability. The conversion of cyclopentadiene and selectivity for cyclopentene can be simultaneously more than 90%.

Key words:

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1.
沈阳化工大学材料科学与工程学院沈阳 110142

Characterization and reactivity of γ-Al₂O₃ supported Pd-Ni bimetallic nanocatalysts for selective hydrogenation of cyclopentadiene

通讯作者: Hua-Jian Xu,

English

Characterization and reactivity of γ-Al₂O₃ supported Pd-Ni bimetallic nanocatalysts for selective hydrogenation of cyclopentadiene

Corresponding author: Hua-Jian Xu,

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