An efficient synthesis of imidodicarbonic diamides from 1,3-thiazetidin-2-ones with NH<sub>2</sub>OH·HCl <i>via</i> ring-opening reaction

Citation: Wen-Yuan Tang, Jing-Jing Guo, Xing-Xing Gui, De-Man Han, Jian-Jun Li. An efficient synthesis of imidodicarbonic diamides from 1,3-thiazetidin-2-ones with NH₂OH·HCl via ring-opening reaction[J]. Chinese Chemical Letters, 2015, 26(1): 85-88. doi: 10.1016/j.cclet.2014.10.015 shu

An efficient synthesis of imidodicarbonic diamides from 1,3-thiazetidin-2-ones with NH₂OH·HCl via ring-opening reaction

通讯作者: Jian-Jun Li,

基金项目:
We are grateful to the Natural Science Foundation of Zhejiang Province (No. LY13B020015) (No. LY13B020015)

Technology Plan Project of Taizhou (No. 131KY03) for financial support. (No. 131KY03)

摘要: A ring-opening process of 4-imino-1,3-thiazetidin-2-ones with NH₂OH·HCl was described for the first time. Two different scaffolds of imidodicarbonic diamide were obtained selectively in good yields in the presence of organic base. The obtained imidodicarbonic diamides were demonstrated by X-ray diffraction analysis.

关键词:

English

An efficient synthesis of imidodicarbonic diamides from 1,3-thiazetidin-2-ones with NH₂OH·HCl via ring-opening reaction

1.
a College of Pharmaceutical and Chemical Engineering, Taizhou University, Zhejiang 317000, China;
2.
b Key Laboratory for Green Pharmaceutical Technologies and Related Equipment of Ministry of Education, College of Pharmaceutical Sciences, Zhejiang University of Technology, Hangzhou 310014, China

Corresponding author: Jian-Jun Li,

Received Date: 08 July 2014
Available Online: 01 November 2014
Fund Project:

Abstract: A ring-opening process of 4-imino-1,3-thiazetidin-2-ones with NH₂OH·HCl was described for the first time. Two different scaffolds of imidodicarbonic diamide were obtained selectively in good yields in the presence of organic base. The obtained imidodicarbonic diamides were demonstrated by X-ray diffraction analysis.

Key words:

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1.
沈阳化工大学材料科学与工程学院沈阳 110142

An efficient synthesis of imidodicarbonic diamides from 1,3-thiazetidin-2-ones with NH₂OH·HCl via ring-opening reaction

通讯作者: Jian-Jun Li,

English

An efficient synthesis of imidodicarbonic diamides from 1,3-thiazetidin-2-ones with NH₂OH·HCl via ring-opening reaction

Corresponding author: Jian-Jun Li,

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

An efficient synthesis of imidodicarbonic diamides from 1,3-thiazetidin-2-ones with NH2OH·HCl via ring-opening reaction

通讯作者: Jian-Jun Li,

English

An efficient synthesis of imidodicarbonic diamides from 1,3-thiazetidin-2-ones with NH2OH·HCl via ring-opening reaction

Corresponding author: Jian-Jun Li,

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

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CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

An efficient synthesis of imidodicarbonic diamides from 1,3-thiazetidin-2-ones with NH₂OH·HCl via ring-opening reaction

An efficient synthesis of imidodicarbonic diamides from 1,3-thiazetidin-2-ones with NH₂OH·HCl via ring-opening reaction

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