Benzoylformamides as new photocaged bases for photo-latent anion polymerization

Ming-Hui He Mei-Lin Su Zhao-Hui Yu Guang-Xue Chen Zhao-Hua Zeng Jian-Wen Yang

Citation:  Ming-Hui He, Mei-Lin Su, Zhao-Hui Yu, Guang-Xue Chen, Zhao-Hua Zeng, Jian-Wen Yang. Benzoylformamides as new photocaged bases for photo-latent anion polymerization[J]. Chinese Chemical Letters, 2015, 26(1): 21-25. doi: 10.1016/j.cclet.2014.10.002 shu

Benzoylformamides as new photocaged bases for photo-latent anion polymerization

    通讯作者: Jian-Wen Yang,
  • 基金项目:

    This research was financially supported by National Natural Science Foundation of China (No. 21374135) (No. 21374135)

    Paper EngineeringinSouthChinaUniversityofTechnology(No.C713043z) (No.C713043z)

    the Fundamental Research Funds for the Central Universities (No. 2013ZB0025). (No. 2013ZB0025)

摘要: Benzoylformamide (BFA) derivatives are proposed as new photocaged bases with good solubility in epoxy resin. Initially their structures were confirmed by 1HNMR, 13C NMR, and elemental analysis. Next, we detail their thermal stability, solubility behavior, and photolysis products. Furthermore, the model photo-latent anion polymerization (AP) of epoxide system in the presence of BFA-dBA (N,N-dibenzyl-2-oxo-2-phenylacetamide) as a photocaged base has been investigated, and excellent photopolymerization profile is obtained.

English

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  • 发布日期:  2014-10-08
  • 收稿日期:  2014-08-10
  • 网络出版日期:  2014-09-25
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