Syngas production in a novel perovskite membrane reactor with co-feed of CO<sub>2</sub>

引用本文: Yan Ying Wei, Liu Huang, Jun Tang, Ling Yi Zhou, Zhong Li, Hai Hui Wang. Syngas production in a novel perovskite membrane reactor with co-feed of CO₂[J]. Chinese Chemical Letters, 2011, 22(12): 1492-1496. doi: 10.1016/j.cclet.2011.05.040 shu

Citation: Yan Ying Wei, Liu Huang, Jun Tang, Ling Yi Zhou, Zhong Li, Hai Hui Wang. Syngas production in a novel perovskite membrane reactor with co-feed of CO₂[J]. Chinese Chemical Letters, 2011, 22(12): 1492-1496. doi: 10.1016/j.cclet.2011.05.040 shu

Syngas production in a novel perovskite membrane reactor with co-feed of CO₂

School of Chemistry & Chemical Engineering, South China University of Technology, Guangzhou 510640, China
基金项目:
The authors greatly acknowledge the financial support by Natural Science Foundation of China (Nos.U0834004 and 20936001), the Science-Technology Plan of Guangzhou City (No.2009J1-C511-1) and the Fundamental Research Funds for the Central Universities, SCUT (No.2009220038).

摘要: Partial oxidation of methane (POM) co-fed with CO₂ to syngas in a novel catalytic BaCo_0.6Fe_0.2Ta_0.2O_3-δ oxygen permeable membrane reactor was successfully reported. Adding CO₂ to the partial oxidation of methane reaction not only alters the ratio of CO/H₂, but also increases the oxygen permeation flux and CH₄ conversion. Around 96% CH₄ conversion with more than 93% CO₂ conversion and 100% CO selectivity is achieved, which shows an excellent reaction performance. A steady oxygen permeation flux of 15 mL/ (cm² min) is obtained during the 100-h operation, which shows good stability as well.

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English

Syngas production in a novel perovskite membrane reactor with co-feed of CO₂

School of Chemistry & Chemical Engineering, South China University of Technology, Guangzhou 510640, China
Received Date: 31 January 2004
Fund Project:
The authors greatly acknowledge the financial support by Natural Science Foundation of China (Nos.U0834004 and 20936001), the Science-Technology Plan of Guangzhou City (No.2009J1-C511-1) and the Fundamental Research Funds for the Central Universities, SCUT (No.2009220038).

Abstract: Partial oxidation of methane (POM) co-fed with CO₂ to syngas in a novel catalytic BaCo_0.6Fe_0.2Ta_0.2O_3-δ oxygen permeable membrane reactor was successfully reported. Adding CO₂ to the partial oxidation of methane reaction not only alters the ratio of CO/H₂, but also increases the oxygen permeation flux and CH₄ conversion. Around 96% CH₄ conversion with more than 93% CO₂ conversion and 100% CO selectivity is achieved, which shows an excellent reaction performance. A steady oxygen permeation flux of 15 mL/ (cm² min) is obtained during the 100-h operation, which shows good stability as well.

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沈阳化工大学材料科学与工程学院沈阳 110142

Syngas production in a novel perovskite membrane reactor with co-feed of CO₂

English

Syngas production in a novel perovskite membrane reactor with co-feed of CO₂

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Syngas production in a novel perovskite membrane reactor with co-feed of CO2

English

Syngas production in a novel perovskite membrane reactor with co-feed of CO2

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

Syngas production in a novel perovskite membrane reactor with co-feed of CO₂

Syngas production in a novel perovskite membrane reactor with co-feed of CO₂

CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs