引用本文:
Xia Wu, Jian Lei, Zhen Lei Song. Synthesis of cyclic β-silylenones via oxidative rearrangement of tertiary α-hydroxy allylsilanes with PCC[J]. Chinese Chemical Letters,
2011, 22(3): 306-309.
doi:
10.1016/j.cclet.2010.10.018
Citation: Xia Wu, Jian Lei, Zhen Lei Song. Synthesis of cyclic β-silylenones via oxidative rearrangement of tertiary α-hydroxy allylsilanes with PCC[J]. Chinese Chemical Letters, 2011, 22(3): 306-309. doi: 10.1016/j.cclet.2010.10.018
Citation: Xia Wu, Jian Lei, Zhen Lei Song. Synthesis of cyclic β-silylenones via oxidative rearrangement of tertiary α-hydroxy allylsilanes with PCC[J]. Chinese Chemical Letters, 2011, 22(3): 306-309. doi: 10.1016/j.cclet.2010.10.018
Synthesis of cyclic β-silylenones via oxidative rearrangement of tertiary α-hydroxy allylsilanes with PCC
摘要:
An oxidative rearrangement of cyclic tertiary α-hydroxy allylsilanes has been carried out in refluxing ClCH2CH2Cl with pyridinium chlorochromate (PCC). The reaction provides a convenient method to synthesize cyclic β-silylenones in modest to excellent yields.
English
Synthesis of cyclic β-silylenones via oxidative rearrangement of tertiary α-hydroxy allylsilanes with PCC
Abstract:
An oxidative rearrangement of cyclic tertiary α-hydroxy allylsilanes has been carried out in refluxing ClCH2CH2Cl with pyridinium chlorochromate (PCC). The reaction provides a convenient method to synthesize cyclic β-silylenones in modest to excellent yields.
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Key words:
- Pyridinium chlorochromate
- / Oxidative rearrangement
- / Cyclic β-silylenones
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