Synthesis and catalytic properties of hierarchical TS-1 in the presence of cationic organosilane surfactant

Shu Shuang Li An Feng Zhang Min Liu Xin Wen Guo

引用本文: Shu Shuang Li,  An Feng Zhang,  Min Liu,  Xin Wen Guo. Synthesis and catalytic properties of hierarchical TS-1 in the presence of cationic organosilane surfactant[J]. Chinese Chemical Letters, 2011, 22(3): 303-305. doi: 10.1016/j.cclet.2010.06.036 shu
Citation:  Shu Shuang Li,  An Feng Zhang,  Min Liu,  Xin Wen Guo. Synthesis and catalytic properties of hierarchical TS-1 in the presence of cationic organosilane surfactant[J]. Chinese Chemical Letters, 2011, 22(3): 303-305. doi: 10.1016/j.cclet.2010.06.036 shu

Synthesis and catalytic properties of hierarchical TS-1 in the presence of cationic organosilane surfactant

  • 基金项目:

    This project was sponsored by program for new century excellent talents in university (No. NCET-04-0268) and "111"project.

摘要: Hierarchical TS-1 has been synthesized in the presence of cationic organosilane surfactant. The material is characterized with XRD, TEM, N2 adsorption isotherm. The results show that the hierarchical TS-1 aggregates consist of small primary units with sizes of 20-30 nm. The BET surface area increases from 420 to 513 m2/g compared to conventional TS-1 zeolite. The sample is shown to be more active in epoxidation of cyclohexene than conventional TS-1.

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  • 收稿日期:  2010-04-13
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