引用本文:
Wei Han, Ning Liu, Chun Liu, Zi Lin Jin. A ligand-free Heck reaction catalyzed by the in situ-generated palladium nanoparticles in PEG-400[J]. Chinese Chemical Letters,
2010, 21(12): 1411-1414.
doi:
10.1016/j.cclet.2010.06.019
Citation: Wei Han, Ning Liu, Chun Liu, Zi Lin Jin. A ligand-free Heck reaction catalyzed by the in situ-generated palladium nanoparticles in PEG-400[J]. Chinese Chemical Letters, 2010, 21(12): 1411-1414. doi: 10.1016/j.cclet.2010.06.019
Citation: Wei Han, Ning Liu, Chun Liu, Zi Lin Jin. A ligand-free Heck reaction catalyzed by the in situ-generated palladium nanoparticles in PEG-400[J]. Chinese Chemical Letters, 2010, 21(12): 1411-1414. doi: 10.1016/j.cclet.2010.06.019
A ligand-free Heck reaction catalyzed by the in situ-generated palladium nanoparticles in PEG-400
摘要:
A ligand-free Heck reaction catalyzed by in situ-generated palladium nanoparticles in PEG-400 has been developed. This catalytic system is a simple and active protocol for the Heck reaction of aryl halides under mild conditions. Comparative experiments demonstrated that the Heck reaction catalyzed by the palladium nanoparticles in situ-generated under the Heck reaction conditions was carried out much quicker than that by the in ex situ-generated ones.
English
A ligand-free Heck reaction catalyzed by the in situ-generated palladium nanoparticles in PEG-400
Abstract:
A ligand-free Heck reaction catalyzed by in situ-generated palladium nanoparticles in PEG-400 has been developed. This catalytic system is a simple and active protocol for the Heck reaction of aryl halides under mild conditions. Comparative experiments demonstrated that the Heck reaction catalyzed by the palladium nanoparticles in situ-generated under the Heck reaction conditions was carried out much quicker than that by the in ex situ-generated ones.
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Key words:
- In situ nanocatalysis
- / Palladium nanoparticles
- / Heek reaction
- / Polyethylene glycol
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