A ligand-free Heck reaction catalyzed by the in situ-generated palladium nanoparticles in PEG-400

Wei Han Ning Liu Chun Liu Zi Lin Jin

引用本文: Wei Han,  Ning Liu,  Chun Liu,  Zi Lin Jin. A ligand-free Heck reaction catalyzed by the in situ-generated palladium nanoparticles in PEG-400[J]. Chinese Chemical Letters, 2010, 21(12): 1411-1414. doi: 10.1016/j.cclet.2010.06.019 shu
Citation:  Wei Han,  Ning Liu,  Chun Liu,  Zi Lin Jin. A ligand-free Heck reaction catalyzed by the in situ-generated palladium nanoparticles in PEG-400[J]. Chinese Chemical Letters, 2010, 21(12): 1411-1414. doi: 10.1016/j.cclet.2010.06.019 shu

A ligand-free Heck reaction catalyzed by the in situ-generated palladium nanoparticles in PEG-400

  • 基金项目:

    The authors thank the financial support from State Key Laboratory of Fine Chemicals (No.KF0801),Science Research Foundation of DUT,Graduate Student Education Reform Fund of DUT,and the National Natural Science Foundation of China (No.20976024).

摘要: A ligand-free Heck reaction catalyzed by in situ-generated palladium nanoparticles in PEG-400 has been developed. This catalytic system is a simple and active protocol for the Heck reaction of aryl halides under mild conditions. Comparative experiments demonstrated that the Heck reaction catalyzed by the palladium nanoparticles in situ-generated under the Heck reaction conditions was carried out much quicker than that by the in ex situ-generated ones.

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  • 收稿日期:  2010-04-01
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