引用本文:
Ardeshir Khazaei, Amin Rostami, Fatemeh Mantashlo. p-Toluenesulfonyl chloride as a new and effective catalyst for acetylation and formylation of hydroxyl compounds under mild conditions[J]. Chinese Chemical Letters,
2010, 21(12): 1430-1434.
doi:
10.1016/j.cclet.2010.05.025
Citation: Ardeshir Khazaei, Amin Rostami, Fatemeh Mantashlo. p-Toluenesulfonyl chloride as a new and effective catalyst for acetylation and formylation of hydroxyl compounds under mild conditions[J]. Chinese Chemical Letters, 2010, 21(12): 1430-1434. doi: 10.1016/j.cclet.2010.05.025
Citation: Ardeshir Khazaei, Amin Rostami, Fatemeh Mantashlo. p-Toluenesulfonyl chloride as a new and effective catalyst for acetylation and formylation of hydroxyl compounds under mild conditions[J]. Chinese Chemical Letters, 2010, 21(12): 1430-1434. doi: 10.1016/j.cclet.2010.05.025
p-Toluenesulfonyl chloride as a new and effective catalyst for acetylation and formylation of hydroxyl compounds under mild conditions
摘要:
The catalytic application of p-toluenesulfonyl chloride for efficient acetylation of various types of alcohols and phenols with acetic anhydride in solvent-free conditions is reported. Also structurally diverse alcohols were formylated using formic acid based on the use of catalytic amount of p-toluenesulfonyl chloride under solvent-free condition. The reactions were carried out in short reaction time and in good to excellent yields at room temperature.
English
p-Toluenesulfonyl chloride as a new and effective catalyst for acetylation and formylation of hydroxyl compounds under mild conditions
Abstract:
The catalytic application of p-toluenesulfonyl chloride for efficient acetylation of various types of alcohols and phenols with acetic anhydride in solvent-free conditions is reported. Also structurally diverse alcohols were formylated using formic acid based on the use of catalytic amount of p-toluenesulfonyl chloride under solvent-free condition. The reactions were carried out in short reaction time and in good to excellent yields at room temperature.
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Key words:
- p-Toluenesulfonyl chloride
- / Hydroxyl compounds
- / Acetylation
- / Formylation
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