Suzuki reaction of bromoallenes with arylboronic acids using an air-stable palladium complex Pd (PH2PCH2CH2)2 as a precatalyst

Xin Du Xiu Juan Feng Ying Liu Ren He Ming Bao

引用本文: Xin Du,  Xiu Juan Feng,  Ying Liu,  Ren He,  Ming Bao. Suzuki reaction of bromoallenes with arylboronic acids using an air-stable palladium complex Pd (PH2PCH2CH2)2 as a precatalyst[J]. Chinese Chemical Letters, 2010, 21(6): 641-645. doi: 10.1016/j.cclet.2010.01.042 shu
Citation:  Xin Du,  Xiu Juan Feng,  Ying Liu,  Ren He,  Ming Bao. Suzuki reaction of bromoallenes with arylboronic acids using an air-stable palladium complex Pd (PH2PCH2CH2)2 as a precatalyst[J]. Chinese Chemical Letters, 2010, 21(6): 641-645. doi: 10.1016/j.cclet.2010.01.042 shu

Suzuki reaction of bromoallenes with arylboronic acids using an air-stable palladium complex Pd (PH2PCH2CH2)2 as a precatalyst

  • 基金项目:

    We are grateful to the National Natural Science Foundation of China (No. 20603005) for financial support. This work was partly supported by the program for Changjiang Scholars and Innovative Research Teams in Universities (No. IRT0711).

摘要: Suzuki reaction of bromoallenes with arylboronic acids was successfully performed by using an air-stable hemilabile P-O coordinated cyclopalladated complex Pd(PH2PCH2CH2)2 as a precatalyst, and the corresponding coupling products were obtained in satisfactory to excellent yields. All products are unknown compounds which were characterized by 1H NMR, 13C NMR, IR, and HRMS.

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  • 收稿日期:  2009-11-13
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