引用本文:
Wang Yan Nie, Gang Li, Yang Li, Hong Yao Xu. Preparation and properties of a POSS-containing organic-inorganic hybrid crosslinked polymer[J]. Chinese Chemical Letters,
2009, 20(6): 738-742.
doi:
10.1016/j.cclet.2009.02.003
Citation: Wang Yan Nie, Gang Li, Yang Li, Hong Yao Xu. Preparation and properties of a POSS-containing organic-inorganic hybrid crosslinked polymer[J]. Chinese Chemical Letters, 2009, 20(6): 738-742. doi: 10.1016/j.cclet.2009.02.003
Citation: Wang Yan Nie, Gang Li, Yang Li, Hong Yao Xu. Preparation and properties of a POSS-containing organic-inorganic hybrid crosslinked polymer[J]. Chinese Chemical Letters, 2009, 20(6): 738-742. doi: 10.1016/j.cclet.2009.02.003
Preparation and properties of a POSS-containing organic-inorganic hybrid crosslinked polymer
摘要:
A novel POSS-containing organic-inorganic hybrid crosslinked polymer was prepared by hydrosilylation reaction of octahydridosilsesquioxane (T8H8) with 4,4'-bis(4-allyloxybenzoyloxy)phenyl (diene A). Its structure and property was characterized by FTIR, 29Si NMR, TGA and ellipsometer, respectively. The results show that the hybrid polymer possesses high thermal stability and low dielectric constant of 1.97 at optical frequencies.
English
Preparation and properties of a POSS-containing organic-inorganic hybrid crosslinked polymer
Abstract:
A novel POSS-containing organic-inorganic hybrid crosslinked polymer was prepared by hydrosilylation reaction of octahydridosilsesquioxane (T8H8) with 4,4'-bis(4-allyloxybenzoyloxy)phenyl (diene A). Its structure and property was characterized by FTIR, 29Si NMR, TGA and ellipsometer, respectively. The results show that the hybrid polymer possesses high thermal stability and low dielectric constant of 1.97 at optical frequencies.
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Key words:
- POSS
- / Hydrosilylation
- / Organic-inorganic hybrid polymer
- / Thermal stability
- / Dielectric property
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