Synthesis and characterization of a-{3-[(2,3-dihydroxy) propoxy]propyl}-v-butyl-polydimethylsiloxanes

Xiao Li Zhan Zhen Huan Luo Qing Hua Zhang Bi Chen Feng Qiu Chen

引用本文: Xiao Li Zhan,  Zhen Huan Luo,  Qing Hua Zhang,  Bi Chen,  Feng Qiu Chen. Synthesis and characterization of a-{3-[(2,3-dihydroxy) propoxy]propyl}-v-butyl-polydimethylsiloxanes[J]. Chinese Chemical Letters, 2009, 20(6): 729-732. doi: 10.1016/j.cclet.2008.12.047 shu
Citation:  Xiao Li Zhan,  Zhen Huan Luo,  Qing Hua Zhang,  Bi Chen,  Feng Qiu Chen. Synthesis and characterization of a-{3-[(2,3-dihydroxy) propoxy]propyl}-v-butyl-polydimethylsiloxanes[J]. Chinese Chemical Letters, 2009, 20(6): 729-732. doi: 10.1016/j.cclet.2008.12.047 shu

Synthesis and characterization of a-{3-[(2,3-dihydroxy) propoxy]propyl}-v-butyl-polydimethylsiloxanes

  • 基金项目:

    This work was financially supported by the National Natural Science Foundation of China (No.20576117 and No.20836007).

摘要: Hydrosilylation has been carried out between Si-H terminated polydimethylsiloxanes with narrow molecular weight distribution and protected 3-allyloxy-1,2-propanediol, and after subsequently alcoholyzed, α-{3-[(2,3-dihydroxy)propoxy]propyl}-ω-butyl-polydimethylsiloxanes with varying number of ((Si(CH3)2-O) unit were obtained. At each step, the produced compounds were carefully characterized. The results showed that each step was successfully carried out and target products were achieved.

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  • 收稿日期:  2008-09-27
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