Preparation and characterization of HypoGel-supported Pd nanocatalysts for Suzuki reaction under mild conditions

引用本文: Kin Hong Liew, Wan Zurina Samad, Norazzizi Nordin, Poh Lee Loh, Joon Ching Juan, Mohd Ambar Yarmo, Badrul Hisham Yahaya, Rahimi M. Yusop. Preparation and characterization of HypoGel-supported Pd nanocatalysts for Suzuki reaction under mild conditions[J]. 催化学报, 2015, 36(5): 771-777. doi: 10.1016/S1872-2067(14)60282-5 shu

Citation: Kin Hong Liew, Wan Zurina Samad, Norazzizi Nordin, Poh Lee Loh, Joon Ching Juan, Mohd Ambar Yarmo, Badrul Hisham Yahaya, Rahimi M. Yusop. Preparation and characterization of HypoGel-supported Pd nanocatalysts for Suzuki reaction under mild conditions[J]. Chinese Journal of Catalysis, 2015, 36(5): 771-777. doi: 10.1016/S1872-2067(14)60282-5 shu

Preparation and characterization of HypoGel-supported Pd nanocatalysts for Suzuki reaction under mild conditions

通讯作者: Rahimi M. Yusop

基金项目:
This work was supported by the Ministry of Higher Education Malaysia (FRGS/1/2012/ST01/UKM/02/1) (FRGS/1/2012/ST01/UKM/02/1)

Research Grant from UKM (IP-2014-070 and LAUREATE-2013-002). (IP-2014-070 and LAUREATE-2013-002)

摘要: A new heterogeneous catalyst composed of Pd nanoparticles immobilized within a HypoGel resin has been prepared in the absence of any ligands using an extensive cross-linking method. This newly developed nanocatalyst was characterized by N₂ adsorption-desorption, X-ray diffraction (XRD), transmission electron microscopy (TEM), scanning electron microscopy (SEM), energy dispersive X-ray (EDX), Fourier transform infrared spectroscopy and inductively coupled plasma-mass spectrometer (ICP-MS) techniques. TEM and XRD results revealed that the Pd nanoparticles were well dispersed with diameters in the range of 4-12 nm, and an average size of about 8 nm. The cross-linked Pd catalyst demonstrated excellent catalytic activity towards the synthesis of a series of biaryl compounds by the reaction of various aryl halides (e.g., bromides andiodides) with phenylboronic acid in the presence of tetrabutylammonium bromide. ICP-MS analysis indicated that there was only 0.25% weight loss of Pd (0.55 ± 0.02 ppm) from the supported catalyst after the first cycle reaction. Furthermore, the catalyst showed excellent reusability (up to five uses) with consistently high levels of catalytic activity following its recovery by filtration.

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English

Preparation and characterization of HypoGel-supported Pd nanocatalysts for Suzuki reaction under mild conditions

1.
a School of Chemical Sciences and Food Technology, Faculty of Science and Technology, Universiti Kebangsaan Malaysia, 43600 UKM, Bangi, Selangor Darul Ehsan, Malaysia;

Corresponding author: Rahimi M. Yusop

Received Date: 19 December 2014
Available Online: 20 May 2015
Fund Project:
This work was supported by the Ministry of Higher Education Malaysia (FRGS/1/2012/ST01/UKM/02/1)

Research Grant from UKM (IP-2014-070 and LAUREATE-2013-002).

Abstract: A new heterogeneous catalyst composed of Pd nanoparticles immobilized within a HypoGel resin has been prepared in the absence of any ligands using an extensive cross-linking method. This newly developed nanocatalyst was characterized by N₂ adsorption-desorption, X-ray diffraction (XRD), transmission electron microscopy (TEM), scanning electron microscopy (SEM), energy dispersive X-ray (EDX), Fourier transform infrared spectroscopy and inductively coupled plasma-mass spectrometer (ICP-MS) techniques. TEM and XRD results revealed that the Pd nanoparticles were well dispersed with diameters in the range of 4-12 nm, and an average size of about 8 nm. The cross-linked Pd catalyst demonstrated excellent catalytic activity towards the synthesis of a series of biaryl compounds by the reaction of various aryl halides (e.g., bromides andiodides) with phenylboronic acid in the presence of tetrabutylammonium bromide. ICP-MS analysis indicated that there was only 0.25% weight loss of Pd (0.55 ± 0.02 ppm) from the supported catalyst after the first cycle reaction. Furthermore, the catalyst showed excellent reusability (up to five uses) with consistently high levels of catalytic activity following its recovery by filtration.

Key words:

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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Preparation and characterization of HypoGel-supported Pd nanocatalysts for Suzuki reaction under mild conditions

通讯作者: Rahimi M. Yusop

English

Preparation and characterization of HypoGel-supported Pd nanocatalysts for Suzuki reaction under mild conditions

Corresponding author: Rahimi M. Yusop

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

Preparation and characterization of HypoGel-supported Pd nanocatalysts for Suzuki reaction under mild conditions

通讯作者: Rahimi M. Yusop

English

Preparation and characterization of HypoGel-supported Pd nanocatalysts for Suzuki reaction under mild conditions

Corresponding author: Rahimi M. Yusop

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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