Citation: LIU Han-lin, LI Xiu-ping, ZHAO Rong-xiang. Preparation of DESs/SG catalyst and its performance in the oxidative desulfurization[J]. Journal of Fuel Chemistry and Technology, ;2020, 48(3): 369-377. shu

Preparation of DESs/SG catalyst and its performance in the oxidative desulfurization

1.
College of Chemistry, Chemical Engineering and Environmental Engineering, Liaoning Shihua University, Fushun 113001, China
2.
College of Chemistry & Material Science Engineering, Liaoning Shihua University, Fushun 113001, China

Corresponding author: ZHAO Rong-xiang, zylhzrx@126.com
Received Date: 21 October 2019
Revised Date: 21 January 2020

Fund Project: The project was supported by the Mentoring Program Projects from Liaoning Natural Science Foundation (2019-ZD-0064)The project was supported by the Mentoring Program Projects from Liaoning Natural Science Foundation 2019-ZD-0064

Figures(13)

DESs/SG catalyst was prepared by supporting the proline-based deep eutectic solvent (DES) on the silica-gel (SG) matrix using a sol-gel method; the catalyst structure was characterized by FT-IR, XRD, SEM/EDS and N₂ adsorption-desorption. The results showed that the DESs were successfully incorporated into the silica-gel matrix, leading to a decrease in the surface area and pore volume, but an increase in the pore diameter. With hydrogen peroxide as oxidant, the catalytic performance of DESs/SG in the oxidative desulfurization of a model oil containing dibenzothiophene (DBT) was investigated; the effects of deep eutectic solvent loading, reaction temperature, n(H₂O₂)/n(S) ratio, catalyst amount, sulfur compound type and catalyst recycle times on the desulfurization efficiency were considered. The results indicated that under optimum desulfurization conditions, the desulfurization degrees for DBT, 4, 6-dimethyl-dibenzothiophene (4, 6-DMDBT) and benzothiophene (BT) over the DESs/SG catalyst were 97%, 96.5% and 46.4%, respectively; after recycling for 9 times, the DESs/SG catalyst still displayed a desulfurization degree of above 89.4%.
- silica gel,
- oxidation desulfurization,
- deep eutectic solvents,
- sol-gel,
- dibenzothiophene
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