Citation: ZHOU Ze-ling, ZHANG Meng, ZHANG Jun-feng, SONG Fa-en, ZHANG Qing-de, TAN Yi-sheng, HAN Yi-zhuo. Methane reforming with carbon dioxide over the perovskite supported Ni catalysts[J]. Journal of Fuel Chemistry and Technology, ;2020, 48(7): 833-841. shu

Methane reforming with carbon dioxide over the perovskite supported Ni catalysts

1.
State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, China
2.
University of Chinese Academy of Sciences, Beijing 100049, China

Corresponding author: ZHANG Jun-feng, zhangjf@sxicc.ac.cn HAN Yi-zhuo, hanyz@sxicc.ac.cn
Received Date: 9 June 2020
Revised Date: 9 July 2020

Fund Project: The project was supported by the Special National Key Research and Development Project (2016YFF0102601)the Special National Key Research and Development Project 2016YFF0102601

Figures(7)

A series of MTiO₃ (M=Mg, Ca, Sr, Ba) supported Ni catalysts (with a Ni loading of 5%) for methane reforming with carbon dioxide (DRM) were prepared by the impregnation method. The Ni/MTiO₃ catalysts were characterized by XRD, N₂ sorption, H₂-TPR, CO₂-TPD, XPS and TG; the effect of alkaline earth metals (M) on the catalytic performance of Ni/MTiO₃ in the DRM was then investigated. The results indicate that the metal-support interaction, the surface Ni atomic concentration and the mobility of lattice oxygen species on the Ni/MTiO₃ catalysts are related to the alkaline earth metal M used in the MTiO₃ supports. The Ni/CaTiO₃ catalyst shows superior performance in DRM to other catalysts, which is ascribed to the strong metal-support interaction, large amount of reduced active Ni and relatively high mobility of lattice oxygen species. In contrast, the SrTiO₃ support has a relatively large particle size, leading to poor Ni dispersion on the Ni/SrTiO₃ catalyst as well as weak metal-support interaction, low lattice oxygen mobility, and less surface active Ni atoms; as a result, the Ni/SrTiO₃ catalyst exhibits relatively poor performance in DRM.
- perovskite,
- alkaline earth metal,
- methane,
- carbon dioxide,
- carbon deposition
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