Citation: Kai-jun Li, Xiao-ting Chen, Hao Sun, Xu-dong Tang. STRUCTURE AND PROPERTIES OF PHOSPHROUS-CONTAINING POLY(ARYL ETHER KETONE) WITH BISPHENOL-A MOIETY[J]. Chinese Journal of Polymer Science, ;2007, 25(6): 651-655. shu

STRUCTURE AND PROPERTIES OF PHOSPHROUS-CONTAINING POLY(ARYL ETHER KETONE) WITH BISPHENOL-A MOIETY

Received Date: 3 April 2007
Revised Date: 5 June 2007

A phosphrous-containing poly(aryl ether ketone) was synthesized derived from bisphenol-A and bis[4-(4-fluorobenzoyl)phenyl] phenyl phosphine oxide (FPPPO) by nucleophilic substitution reaction. The structure of the polymer was characterized by FT-IR, 1H-NMR and 31P-NMR. The thermal property of the PAEK was measured by DSC and TGA. The glass transition temperature (Tg) of the polymer was 205°C, and the 5% weight loss temperature under nitrogen was 475°C. Good solubility of the polymer in organic solvents, such as N-methylpyrrolidone, dimethylformamide, dimethylacetamide, dimethylsulfoxide and chloroalkanes was observed, flexible film was obtained from the polymer’s CH2Cl2 solution. The limiting oxygen index (LOI) of the PAEK was 40, which indicated that organic phosphorus moiety can offer good flame retardant property to the polymer.
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