Citation: Zhao Futong, Li Chenglong, Gao Wenyi, Lv Xuechuan, Jiao Yujuan, Gao Xiaohan. Hydroxylation of Phenol to Produce Dihydroxybenzene Catalyzed by Iron Modified HMS[J]. Chemistry, ;2018, 81(10): 924-928. shu

Hydroxylation of Phenol to Produce Dihydroxybenzene Catalyzed by Iron Modified HMS

School of Chemistry and Material Science, College of Chemistry, Chemical Engineering and Environmental Engineering, Liaoning Shihua University Fushun 113001

Corresponding author: Gao Xiaohan, gaoxhan@163.com
Received Date: 12 May 2018
Accepted Date: 29 June 2018

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Catechol and hydroquinone are very important fine chemical intermediate products. They have a wide range of applications in all industries. It is a mild and environment-friendly route to produce dihydroxybenzene through the reaction of phenol with hydrogen peroxide. The choice of the catalyst and the optimization of the reaction conditions are very important to the route. HMS modified by iron (Fe/HMS) is used as a catalyst. Effects of Fe contents in Fe/HMS, catalyst amount, temperature and reaction time on the catalytic performances were examined. Under the conditions of water solvent, n(Fe)/n(Si) of 0.04, ratio of phenol to H₂O₂ of 2:1, reaction temperature of 50℃, amount of catalyst of 0.1 g and reaction time of 4 hours, phenol conversion of 45.5% and the dihydroxybenzene selectivity of 94.9% are achieved. The results of the N₂ absorption-desorption isotherms illustrates that Fe/HMS material has a uniform mesoporous structure, and Fe is successfully incorporated into the framework of HMS. The catalyst has good stability, and its skeleton remains intact after recycling.
- Hydroxylation of phenol,
- Hydrogen peroxide,
- Fe/HMS,
- Green chemistry,
- Modified molecular sieve
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