Citation: Ma Xiuzhen, Hu Bin. Volumetric Properties of NaCl-KCl-H₂O System and Their Correlation with Pitzer Model[J]. Chemistry, ;2020, 83(5): 459-463. shu

Volumetric Properties of NaCl-KCl-H₂O System and Their Correlation with Pitzer Model

Ma Xiuzhen ,
Hu Bin ^,

Key Laboratory of Comprehensive and Highly Efficient Utilization of Salt Lake Resources, Qinghai Institute of Salt Lakes, Chinese Academy of Sciences; Key Laboratory of Salt Lake Resources Chemistry of Qinghai Province, Xining, 810008

Corresponding author: Hu Bin, hubin@isl.ac.cn
Received Date: 5 November 2019
Accepted Date: 25 December 2019

Figures(3)

The densities of NaCl-KCl aqueous mixture were determined at temperatures from 288.15 to 323.15 K and over a range of composition at ionic strength of 0.1~4 mol·kg^-1. A high precision vibrating-tube densitometer was used in the measurement. The excess volumes of the mixed electrolytes calculated from the experimental data permitted a parameterization of the Pitzer model for mixtures with the entire range of temperatures and compositions covered by this study. In addition, using the Pitzer model, we determined the volume of mixing at constant ionic strength and at 298.15 K.
- Density,
- Pitzer ion-interaction Model,
- Salt lake brine,
- Volume of mixing
1. [1]
  Wang S. J. Salt Lake Res., 2000, 8(4): 44~49.
2. [2]
  Pitzer K. J. Phys. Chem., 1973, 77(2), 268~277.
3. [3]
  Pitzer K. Activity coefficients in electrolyte solutions, second edition, CRC, Ann Arbor, 1991.
4. [4]
  Harvie C, Weare J. Geochim. Cosmochim. Acta, 1980, 44(7): 981~997.
5. [5]
  Krumgalz B. J. Mol. Liq., 2001, 91(1/3): 3~19.
6. [6]
  Lassin A, Andre L, Lach A, et al. Calphad, 2018, 61: 126~139.
7. [7]
  Ruby C, Kawa J. J. Am. Chem. Soc., 1926, 48(5): 1119~1128.
8. [8]
  Wirth H. J. Am. Chem. Soc., 1937, 59(12): 2549~2554.
9. [9]
  Campbell A, Kartzmark E. Can. J. Chem., 1956, 34(5): 672~678.
10. [10]
  Fabuss B, Korosi A, Othmer D. J. Chem. Eng. Data, 1969, 14(2): 192~197.
11. [11]
  Kumar A. J. Chem. Eng. Data, 1988, 33(2): 198~199.
12. [12]
  Zezin D, Driesner T, Sanchez-Valle C. J. Chem. Eng. Data, 2014, 59(3): 736~749.
13. [13]
  Ghafri S, Maitland G, Trusler P. J. Chem. Eng. Data, 2012, 57(4): 1288~1304.
14. [14]
  Dedick E, Hershey J, Sotolongo S, et al. J. Solution. Chem., 1990, 19(4): 353~374.
15. [15]
  Hu B, Hnědkovsky L, Li W, et al. J. Chem. Eng. Data, 2016, 61(4): 1388~1394.
16. [16]
  Krumgalz B, Pogorelskii R, Pitzer K. J. Solution Chem., 1995, 24(10): 1025~1038.
17. [17]
  Krumgalz B, Pogorelskii R, Sokolov A, et al. J. Phys. Chem. Ref. Data, 2000, 29(5): 1123~1140.
18. [18]
  Wagner W, Pruss A. J. Phys. Chem. Ref. Data, 2002, 31(2): 387~535.
19. [19]
  Desnoyer J, Arel M, Perron G, et al. J. Phys. Chem., 1969, 73(10): 3346~3351.
20. [20]
  Lovera J, Hernandez-Luiz F, Galleguillos H. J. Chem. Eng. Data, 2008, 53(12): 2902~2906.
1. [1]
  Fei Nie , Xueru Liu , Zhuang Hui , Yan Li , Bin Cui . Curriculum Ideological and Political Design of Comprehensive Experiment of Soda Ash Preparation from Salt Lake Water. University Chemistry, 2024, 39(2): 121-126. doi: 10.3866/PKU.DXHX202308054
2. [2]
  Shu'e Song , Xiaokui Wang , Yongmei Liu , Wanchun Zhu , Hong Yuan , Fuping Tian , Yunshan Bai , Yunchao Li , Li Wang , Zhongyun Wu , Yuan Chun , Jianrong Zhang , Shuyong Zhang . Suggestions on Operating Specifications of Physical Chemistry Experiment: Measurement of Viscosity, Density and Optical Properties. University Chemistry, 2025, 40(5): 148-156. doi: 10.12461/PKU.DXHX202503026
3. [3]
  Yunfei Shen , Long Chen . Gradient imprinted Zn metal anodes assist dendrites-free at high current density/capacity. Chinese Journal of Structural Chemistry, 2024, 43(10): 100321-100321. doi: 10.1016/j.cjsc.2024.100321
4. [4]
  Zhilong Xie , Guohui Zhang , Ya Meng , Yefei Tong , Jian Deng , Honghui Li , Qingqing Ma , Shisong Han , Wenjun Ni . A natural nano-platform: Advances in drug delivery system with recombinant high-density lipoprotein. Chinese Chemical Letters, 2024, 35(11): 109584-. doi: 10.1016/j.cclet.2024.109584
5. [5]
  Qingyun Hu , Wei Wang , Junyuan Lu , He Zhu , Qi Liu , Yang Ren , Hong Wang , Jian Hui . High-throughput screening of high energy density LiMn_1-xFe_xPO₄ via active learning. Chinese Chemical Letters, 2025, 36(2): 110344-. doi: 10.1016/j.cclet.2024.110344
6. [6]
  Longsheng Zhan , Yuchao Wang , Mengjie Liu , Xin Zhao , Danni Deng , Xinran Zheng , Jiabi Jiang , Xiang Xiong , Yongpeng Lei . BiVO₄ as a precatalyst for CO₂ electroreduction to formate at large current density. Chinese Chemical Letters, 2025, 36(3): 109695-. doi: 10.1016/j.cclet.2024.109695
7. [7]
  Xu Huang , Kai-Yin Wu , Chao Su , Lei Yang , Bei-Bei Xiao . Metal-organic framework Cu-BTC for overall water splitting: A density functional theory study. Chinese Chemical Letters, 2025, 36(4): 109720-. doi: 10.1016/j.cclet.2024.109720
8. [8]
  Renshu Huang , Jinli Chen , Xingfa Chen , Tianqi Yu , Huyi Yu , Kaien Li , Bin Li , Shibin Yin . Synergized oxygen vacancies with Mn2O3@CeO2 heterojunction as high current density catalysts for Li–O2 batteries. Chinese Journal of Structural Chemistry, 2023, 42(11): 100171-100171. doi: 10.1016/j.cjsc.2023.100171
9. [9]
  Maitri Bhattacharjee , Rekha Boruah Smriti , R. N. Dutta Purkayastha , Waldemar Maniukiewicz , Shubhamoy Chowdhury , Debasish Maiti , Tamanna Akhtar . Synthesis, structural characterization, bio-activity, and density functional theory calculation on Cu(Ⅱ) complexes with hydrazone-based Schiff base ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1409-1422. doi: 10.11862/CJIC.20240007
10. [10]
  Zhengkun QIN , Zicong PAN , Hui TIAN , Wanyi ZHANG , Mingxing SONG . A series of iridium(Ⅲ) complexes with fluorophenyl isoquinoline ligand and low-efficiency roll-off properties: A density functional theory study. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1235-1244. doi: 10.11862/CJIC.20240429
11. [11]
  Hui Bian , Xinyi Yuan , Nan Zhang , Zhuo Xu , Juhong Lian , Ruibin Jiang , Junqing Yan , Deng Li , Shengzhong (Frank) Liu . Correlating vacancy-defect density with CO₂ activation for promoted CO₂ methanation over CsPbBr₃ photocatalyst. Chinese Chemical Letters, 2025, 36(7): 111034-. doi: 10.1016/j.cclet.2025.111034
12. [12]
  Hongxia Li , Xiyang Wang , Du Qiao , Jiahao Li , Weiping Zhu , Honglin Li . Mechanism of nanoparticle aggregation in gas-liquid microfluidic mixing. Chinese Chemical Letters, 2024, 35(4): 108747-. doi: 10.1016/j.cclet.2023.108747
13. [13]
  Keyang Li , Yanan Wang , Yatao Xu , Guohua Shi , Sixian Wei , Xue Zhang , Baomei Zhang , Qiang Jia , Huanhua Xu , Liangmin Yu , Jun Wu , Zhiyu He . Flash nanocomplexation (FNC): A new microvolume mixing method for nanomedicine formulation. Chinese Chemical Letters, 2024, 35(10): 109511-. doi: 10.1016/j.cclet.2024.109511
14. [14]
  Huyi Yu , Renshu Huang , Qian Liu , Xingfa Chen , Tianqi Yu , Haiquan Wang , Xincheng Liang , Shibin Yin . Te-doped Fe3O4 flower enabling low overpotential cycling of Li-CO2 batteries at high current density. Chinese Journal of Structural Chemistry, 2024, 43(3): 100253-100253. doi: 10.1016/j.cjsc.2024.100253
15. [15]
  Bin Zhao , Heping Luo , Jiaqing Liu , Sha Chen , Han Xu , Yu Liao , Xue Feng Lu , Yan Qing , Yiqiang Wu . S-doped carbonized wood fiber decorated with sulfide heterojunction-embedded S, N-doped carbon microleaf arrays for efficient high-current-density oxygen evolution. Chinese Chemical Letters, 2025, 36(5): 109919-. doi: 10.1016/j.cclet.2024.109919
16. [16]
  Shiyu Hou , Maolin Sun , Liming Cao , Chaoming Liang , Jiaxin Yang , Xinggui Zhou , Jinxing Ye , Ruihua Cheng . Computational fluid dynamics simulation and experimental study on mixing performance of a three-dimensional circular cyclone-type microreactor. Chinese Chemical Letters, 2024, 35(4): 108761-. doi: 10.1016/j.cclet.2023.108761
17. [17]
  Ruofan Qi , Jing Zhang , Wang Sun , Bai Yu , Zhenhua Wang , Kening Sun . Solid-acid-Lewis-base interaction accelerates lithium ion transport for uniform lithium deposition. Chinese Chemical Letters, 2025, 36(6): 110009-. doi: 10.1016/j.cclet.2024.110009
18. [18]
  Yuhao Zhou , Siyuan Wu , Xiaozhe Ren , Hongjin Li , Shu Li , Tianying Yan . Effects of salt fraction on the Na⁺ transport in salt-in-ionic liquid electrolytes. Chinese Chemical Letters, 2025, 36(6): 110048-. doi: 10.1016/j.cclet.2024.110048
19. [19]
  Qiangwei Wang , Huijiao Liu , Mengjie Wang , Haojie Zhang , Jianda Xie , Xuanwei Hu , Shiming Zhou , Weitai Wu . Observation of high ionic conductivity of polyelectrolyte microgels in salt-free solutions. Chinese Chemical Letters, 2024, 35(4): 108743-. doi: 10.1016/j.cclet.2023.108743
20. [20]
  Kailong Zhang , Chao Zhang , Luanhui Wu , Qidong Yang , Jiadong Zhang , Guang Hu , Liang Song , Gaoran Li , Wenlong Cai . Chloride molten salt derived attapulgite with ground-breaking electrochemical performance. Chinese Chemical Letters, 2024, 35(10): 109618-. doi: 10.1016/j.cclet.2024.109618

Get Citation

PDF

XML

Metrics

PDF Downloads(10)
Abstract views(609)
HTML views(46)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Volumetric Properties of NaCl-KCl-H2O System and Their Correlation with Pitzer Model

Metrics

通讯作者: 陈斌, bchen63@163.com

Volumetric Properties of NaCl-KCl-H₂O System and Their Correlation with Pitzer Model