Citation: XING Chen. Preparation of H₄SiW₁₂O₄₀/Bi₂WO₆ nano-photocatalyst by supercritical hydrothermal synthesis and its photocatalysis denitrification performance[J]. Journal of Fuel Chemistry and Technology, ;2020, 48(3): 378-384. shu

Preparation of H₄SiW₁₂O₄₀/Bi₂WO₆ nano-photocatalyst by supercritical hydrothermal synthesis and its photocatalysis denitrification performance

XING Chen ^,

Daqing Oilfield Engineering Co., LTD. Daqing 163002, China

Corresponding author: XING Chen, xingchen_dod@petrochina.com.cn
Received Date: 22 November 2019
Revised Date: 24 December 2019

Figures(9)

An immobilized nano-photocatalyst H₄SiW₁₂O₄₀/Bi₂WO₆ was quickly prepared by the supercritical hydrothermal synthesis method. The properties, morphology and structure of the prepared catalysts were investigated and characterized by X-ray diffraction(XRD), scanning electron microscopy(SEM), and transmission electron microscope (TEM) and BET, respectively. The photocatalytic denitrification properties were evaluated by using the model oil with 15 mg/g pyridine. The results show that the photocatalyst is the self-assembly three-dimensional spherical structure by two-dimensional nano-flakes, and the relationship between Bi₂WO₆ and H₄SiW₁₂O₄₀ is not a simple solid loading, but is a new crystal under the condition of supercritical water. It is because the existence of this kind of crystal that the H₄SiW₁₂O₄₀ is firmly fixed on the Bi₂WO₆ photocatalyst and the photocatalytic activity and service life of H₄SiW₁₂O₄₀/Bi₂WO₆ photocatalyst are improved. In view of the contradiction between the preparation period of photocatalyst and the crystal development, the supercritical hydrothermal technology and the photocatalyst template-oriented synthesis technology are organically combined to obtain the H₄SiW₁₂O₄₀/Bi₂WO₆ photocatalyst with good crystal heterostructure and greatly shorten the preparation period of the photocatalyst, greatly reduce the preparation cost of the catalyst and overcome the main contradiction of the industrialized application of the photocatalyst. The nitrogen removal efficiency of the prepared H₄SiW₁₂O₄₀/Bi₂WO₆ photocatalyst for light oil is as high as 97%.
- supercritical hydrothermal synthesis,
- H₄SiW₁₂O₄₀,
- Bi₂WO₆,
- photocatalysis,
- denitrification
1. [1]
  FUJISHIMA A, HONDA K. Electrochemical photolysis of water at a semiconductor electrode[J]. Nature, 1972,238(5358):37-38. doi: 10.1038/238037a0
2. [2]
  TANTIS I, BOUSIAKOU L, KARIKAS G A, LIANOS P. Photocatalytic and hotoelectrocatalytic degradation of the antibacterial agent ciprofloxacin[J]. Photochem Photobiol Sci, 2015,14(3):603-607. doi: 10.1039/C4PP00377B
3. [3]
  CARMONA R J, VELASCO L F, HIDALGO M C, NAVÍO J A, ANIA C O. Boosting the visible-light photoactivity of Bi₂WO₆ using acidic carbon additives[J]. Appl Catal A:Gen, 2015,505:467-477. doi: 10.1016/j.apcata.2015.05.011
4. [4]
  TROVO A G, NOGUEIRA R F, AGUERA A, FERNANDEZ-ALBA A R, MALATO S. Degradation of the antibiotic amoxicillin by photo-Fenton process-chemical and toxicological assessment[J]. Water Res, 2011,45(3):1394-1402.
5. [5]
  XUE J, MA S, ZHOU Y, ZHANG Z, HE M. Facile photochemical synthesis of Au/Pt/gC₃N₄ with plasmon-enhanced photocatalytic activity for antibiotic aegradation[J]. ACS Appl Mater Inter, 2015,7(18):9630-9637.
6. [6]
  LIU G, HAN K, YE H, ZHU C, GAO Y, LIU Y, ZHOU Y. Graphene oxide/triethanolamine modified titanate nanowires as photocatalytic membrane for water treatment[J]. Chem Eng J, 2017,320:74-80.
7. [7]
  WANG X, NI Q, ZENG D, LIAO G, XIE C. Charge separation in branched TiO₂ nanorod array homojunction aroused by quantum effect for enhanced photocatalytic decomposition of gaseous benzene[J]. Appl Surf Sci, 2016,389:165-172. doi: 10.1016/j.apsusc.2016.07.090
8. [8]
  HOA P T, MANAGAKI S, NAKADA N, TAKADA H, SHIMIZU A, ANH D H, VIET P H, SUZUKI S. Antibiotic contamination and occurrence of antibiotic-resistant bacteria in aquatic environments of northern Vietnam[J]. Sci Total Environ, 2011,409(15):2894-2901.
9. [9]
  WANG J, TANG L, ZENG G, DENG Y, LIU Y, WANG L. Atomic scale g-C₃N₄/Bi₂WO₆ 2D/2D heterojunction with enhanced photocatalytic degradation of ibuprofen under visible light irradiation[J]. Appl Catal B:Environ, 2017,209:285-294. doi: 10.1016/j.apcatb.2017.03.019
10. [10]
  MENG X, ZHANG Z. Plasmonic Z-scheme Ag₂O-Bi₂MoO₆ p-n heterojunction photocatalysts with greatly enhanced visible-light responsive activities[J]. Mater Lett, 2017,189:267-270. doi: 10.1016/j.matlet.2016.11.114
11. [11]
  MENG X, ZHANG Z. Bi₂MoO₆ co-modified by reduced graphene oxide and palladium(Pd²⁺ and Pd⁰) with enhanced photocatalytic decomposition of phenol[J]. Appl Catal B:Environ, 2017,209:383-393. doi: 10.1016/j.apcatb.2017.01.033
12. [12]
  ZHOU X, GAN L, ZHANG Q, XIONG X, LI H, ZHONG Z. High performance near-infrared photodetectors based on ultrathin SnS nanobelts grown via physical vapor deposition[J]. J Mater Chem C, 2016:2111-2116.
13. [13]
  MENG X, LI Z, ZENG H, CHEN J, ZHANG Z. MoS₂ quantum dots-interspersed Bi₂WO₆ heterostructures for visible light-induced detoxification and disinfection[J]. Appl Catal B:Environ, 2017,210:160-172.
14. [14]
  CHEN D, NIU F, QIN L, WANG S, ZHANG N, HUANG Y. Defective BiFeO₃ with surface oxygen vacancies:Facile synthesis and mechanism insight into photocatalytic performance[J]. Sol Energy Mater Sol Cells, 2017,171:24-32. doi: 10.1016/j.solmat.2017.06.021
15. [15]
  WANG S, HAI X, DING X, CHANG K, XIANG Y, MENG X, YANG Z, CHEN H, YE J. Light-switchable oxygen vacancies in ultrafine Bi₅O₇Br nanotubes for boosting solar-driven nitrogen fixation in pure water[J]. Adv Mater, 2017,29(31)1101774.
16. [16]
  MENG X, ZHANG Z. Ag/AgCl loaded Bi₂WO₆ composite:A plasmonic Z-scheme visible light-responsive photocatalyst[J]. Int J Photoenergy, 2016:1-11.
17. [17]
  LIU X, LU Q, LIU J. Electrospinning preparation of one-dimensional ZnO/Bi₂WO₆, heterostructured sub-microbelts with excellent photocatalytic performance[J]. J Alloy Compd, 2016,662:598-606. doi: 10.1016/j.jallcom.2015.12.050
18. [18]
  SONG C, WANG X, ZHANG J, CHEN X, LI C. Enhanced performance of direct zscheme CuS-WO₃ system towards photocatalytic decomposition of organic pollutants under visible light[J]. Appl Surf Sci, 2017,425:788-795. doi: 10.1016/j.apsusc.2017.07.082
19. [19]
  HUANG Y, KANG S, YANG Y, QIN H, NI Z, YANG S. Facile synthesis of Bi/Bi₂WO₆ nanocomposite with enhanced photocatalytic activity under visible light[J]. Appl Catal B:Environ, 2016,196:89-99. doi: 10.1016/j.apcatb.2016.05.022
20. [20]
  MENG X, ZHANG Z. Synthesis and characterization of plasmonic and magnetically separable Ag/AgCl-Bi₂WO₆-Fe₃O₄-SiO₂ core-shell composites for visible light-induced water detoxification[J]. J Colloid Interf Sci, 2017,485:296-307.
21. [21]
  LIU Yang, JI Hong-wei, ZHOU De-feng, ZHU Xiao-fei, LI Zhao-hui. Controllable synthesis and photocatalytic activity of TiO₂/LaFeO₃ micro-nanofibers[J]. Chem J Chin Univ, 2014,35(1):19-25.
22. [22]
  LITKE A, HENSEN E J M, HOFMANN J P. Role of dissociatively adsorbed water on the formation of shallow trapped electrons in TiO₂ photocatalysts[J]. J Chem Phys, 2017,121:10153-10162.
23. [23]
  JARAMILLO-PÁEZ C, NAVÍO J A, HIDALGO M C, BOUZIANI A, AZZOUZI M E. Mixed α-Fe₂O₃/Bi₂WO₆ oxides for photoassisted hetero-fenton degradation of methyl orange and phenol[J]. J Photochem Photobiol A, 2017,332:521-533. doi: 10.1016/j.jphotochem.2016.09.031
24. [24]
  MENG X, ZHANG Z. Pd-doped Bi₂MoO₆ plasmonic photocatalysts with enhanced visible light photocatalytic performance[J]. Appl Surf Sci, 2017,392:169-180. doi: 10.1016/j.apsusc.2016.08.113
25. [25]
  SH/T 0162-1992, Method for the determination of basic nitrogen in petroleum products[S]. Sinopec Group, 1992.
26. [26]
  CHEN Ying, XING Chen, JI Shen-lun, LIANG Hong-bao. One-step preparation of H₃PW₁₂O₄₀/Bi₂WO₆ nano-photocatalysts by microwave liquid process and its photocatalysis denitrification properties[J]. Chem J Chin Univ, 2014,35(6):1277-1285.
27. [27]
  ZHOU L, WANG W Z, ZHANG L S. Ultrasonic-assisted synthesis of visible-light-indyced Bi₂MO₆(M=W, Mo)[J]. J Mol Catal A:Chem, 2007,268:195-200. doi: 10.1016/j.molcata.2006.12.026
28. [28]
  TANG J W, ZOU Z G, YE J H. Photophysical and photocatalytic properties of AgInW₂O₈[J]. Phys Inorg Chem, 2004,35(10).
29. [29]
  OZER R R, FERRY J L. Investigation of the photocatalytic activity of TiO₂-polyoxometalate systems[J]. Environ Sci Technol, 2001,35(15):3242-3246. doi: 10.1021/es0106568
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通讯作者: 陈斌, bchen63@163.com

Preparation of H₄SiW₁₂O₄₀/Bi₂WO₆ nano-photocatalyst by supercritical hydrothermal synthesis and its photocatalysis denitrification performance