Citation: DAI Hui, HU Shi-ye, MU Lu-lu, WANG Biao, NING Wen-sheng. Effects of glucose and Pd on the structure and performance of cobalt-based catalyst for F-T synthesis[J]. Journal of Fuel Chemistry and Technology, ;2020, 48(4): 490-494. shu

Effects of glucose and Pd on the structure and performance of cobalt-based catalyst for F-T synthesis

College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014, China

Corresponding author: NING Wen-sheng, wenshning@sohu.com
Received Date: 9 January 2020
Revised Date: 8 March 2020

Fund Project: the Zhejiang Provincial Natural Science Foundation of China LY14B030003The project was supported by the Zhejiang Provincial Natural Science Foundation of China (LY14B030003) and the National Ministry of Science and Technology of China (2014BAD02B05)the National Ministry of Science and Technology of China 2014BAD02B05

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Co-based catalyst was prepared by impregnation method with SiO₂ as the support. The effects of glucose and Pd on the structure and property of the catalysts were characterized by N₂ low-temperature adsorption, XRD, SEM and H₂-TPR. The reactive performance of the catalysts in F-T synthesis was evaluated in a fixed-bed reactor. The shape of Co₃O₄ crystal particle was changed by the added glucose and Pd. The addition of glucose increased the dispersion of Co₃O₄ species, and the addition of Pd promoted the reduction of the catalyst although its dose was only 0.0125%. The combination of glucose and Pd increased the dispersion and reduction of Co₃O₄ species on the catalysts simultaneously. As the result, both of the CO conversion and the selectivity of C₅₊ hydrocarbons increased in F-T synthesis reaction.
- Co/SiO₂,
- glucose,
- Pd,
- F-T synthesis
1. [1]
  DRY E M. The Fischer-Tropsch process:1950-2000[J]. Catal Today, 2002,71:227-241. doi: 10.1016/S0920-5861(01)00453-9
2. [2]
  KHODAKOV A Y, CHU W, FONGARLAND P. Advances in the development of novel cobalt Fischer-Tropsch catalysts for synthesis of long-chain hydrocarbons and clean Fuels[J]. Chem Rev, 2007,107(5):1692-1744. doi: 10.1021/cr050972v
3. [3]
  JIAO F, LI J, PAN X, XIAO J, LI H, MA H, WEI M, PAN Y, ZHOU Z, LI M, MIAO S, LI J, ZHU Y, XIAO D, HE T, YANG J, QI F, FU Q, BAO X. Selective conversion of syngas to light olefins[J]. Science, 2016,351:1065-1068. doi: 10.1126/science.aaf1835
4. [4]
  ZHONG L S, YU F, AN Y L, ZHAO Y H, SUN Y H, LI Z J, LIN T J, LIN Y J, QI X Z, DAI Y Y, GU L, HU J S, JIN S F, SHEN Q, WANG H. Cobalt carbide nanoprisms for direct production of lower olefins from syngas[J]. Nature, 2016,538:84-86. doi: 10.1038/nature19786
5. [5]
  CHENG K, KANG J C, KING D L, SUBRAMANIAN V, ZHOU C, ZHANG Q H, WANG Y. Advances in catalysis for syngas conversion to hydrocarbons[J]. Adv Catal, 2017,60:125-208.
6. [6]
  GAO Hai-yan, CHEN Jian-gang, XIANG Hong-wei, YANG Ji-li, LI Yong-wang, SUN Yu-han. Performance of Co/SiO₂ catalyst for the synthesis of heavy hydrocarbons in F-T reaction[J]. Chin J Catal, 2001,22(2):133-137. doi: 10.3321/j.issn:0253-9837.2001.02.009
7. [7]
  WOO M H, CHO J M, JUN K W. Thermally stabilized cobalt-based Fischer-Tropsch catalysts by phosphorous modification of Al₂O₃:Effect of calcination temperatures on catalyst stability[J]. ChemCatChem, 2015,7(9):1460-1469. doi: 10.1002/cctc.201402994
8. [8]
  QIU Cheng-wu, WU Bao-shang, CHANG Qiang, LI Yong-wang. Effect of Ru addition on the performance of Co/SiO₂ Fischer-Tropsch synthesis catalyst[J]. J Fuel Chem Technol, 2015,43(10):1230-1238. doi: 10.3969/j.issn.0253-2409.2015.10.011
9. [9]
  DEN OTTER J H, NIJVELD S R, DE JONG K P. Synergistic promotion of Co/SiO₂ Fischer-Tropsch catalysts by niobia and platinum[J]. ACS Catal, 2016,6(3):1616-1623. doi: 10.1021/acscatal.5b02418
10. [10]
  SONG H Q, ZHAO Q Z, ZHOU X, CAO Z Y, LUO M S. Selection of highly active and stable Co supported SiC catalyst for Fischer-Tropsch synthesis:Effect of the preparation method[J]. Fuel, 2018,229:144-150. doi: 10.1016/j.fuel.2018.05.025
11. [11]
  JACOBS G, PATTERSON P M, ZHANG Y Q, DAS T, LI J L, DAVIS B H. Fischer-Tropsch synthesis:Deactivation of noble metal-promoted Co/Al₂O₃ catalysts[J]. Appl Catal A:Gen, 2002,233(1):215-226.
12. [12]
  SOLED S L, IGLESIA E, FIATO R A, BAUMGARTNER J E, VROMAN H, MISEO S. Control of metal dispersion and structure by changes in the solid-state chemistry of supported cobalt Fischer-Tropsch catalysts[J]. Top Catal, 2003,26:101-109. doi: 10.1023/B:TOCA.0000012990.83630.f9
13. [13]
  ZHANG Y, HANAYAMA K, TSUBAKI N. The surface modification effects of silica support by organic solvents for Fischer-Tropsch synthesis catalysts[J]. Catal Commun, 2006,7:251-254. doi: 10.1016/j.catcom.2005.11.008
14. [14]
  CHEN Hong-xian, NING Wen-sheng, CHEN Chun-hua, ZHANG Tian. Influence of Fe₂O₃ crystal phase on the performance of Fe-based catalysts for CO₂ hydrogenation[J]. J Fuel Chem Technol, 2015,43(11):1387-1392. doi: 10.3969/j.issn.0253-2409.2015.11.015
15. [15]
  NING W, SHEN H, JIN Y, YANG X. Effects of weak surface modification on Co/SiO₂ catalyst for Fischer-Tropsch reaction[J]. PLoS One, 2015,10(5)e0124228. doi: 10.1371/journal.pone.0124228
16. [16]
  GARCÍA-TRENCO A, MARTÍNEZ A. A simple and efficient approach to confine Cu/ZnO methanol synthesis catalysts in the ordered mesoporous SBA-15 silica[J]. Catal Today, 2013,215:152-161. doi: 10.1016/j.cattod.2013.03.005
17. [17]
  ZHANG Rui, PAN Xi-qiang, PAN Rui-juan, WANG Hong-mei, XIE Xiao-li, DUAN Chao, QI Xiao-feng. Preparation and synthesis of heavy hydrocarbon by Co/Al₂O₃ catalyst[J]. Ind Catal, 2018,26(9):48-52.
18. [18]
  JIANG Z S, ZHAO Y H, HUANG C F, SONG Y H, LI D P, LIU Z T, LIU Z W. Metal-support interactions regulated via carbon coating-A case study of Co/SiO₂, for Fischer-Tropsch synthesis[J]. Fuel, 2018,226:213-220. doi: 10.1016/j.fuel.2018.03.195
19. [19]
  WANG Kai, DAI Hui, LI Bei, WANG Biao, NING Wen-sheng. Advances in the research of hcp-co based synthesis catalysts[J]. Petrochem Technol, 2019,48(9):968-975.
20. [20]
  KHODAKOV A Y, GRIBOVAL-CONSTANT A, BECHARA R, ZHOLOBENKO L V. Pore size effects in Fischer-Tropsch synthesis over cobalt-supported mesoporous silicas[J]. J Catal, 2002,206:230-241. doi: 10.1006/jcat.2001.3496
21. [21]
  TSUBAKI N, SUN S, FUJIMOTO K. Different functions of the noble metals added to cobalt catalysts for Fischer-Tropsch synthesis[J]. J Catal, 2001,199(2):236-246. doi: 10.1006/jcat.2001.3163
22. [22]
  QIU X Q, TSUBAKI N, SUN S, FUJIMOTO K. Influence of noble metals on the performance of Co/SiO₂, catalyst for 1-hexene hydroformylation[J]. Fuel, 2002,81:1625-1630. doi: 10.1016/S0016-2361(02)00088-1
23. [23]
  SUN S, FUJIMOTO K, YONEYAMA Y, TSUBAKI N. Fischer-Tropsch synthesis using Co/SiO₂ catalysts prepared from mixed precursors and addition effect of noble metals[J]. Fuel, 2002,81:1583-1591. doi: 10.1016/S0016-2361(02)00090-X
24. [24]
  LI Cheng, MA Xiang-dong, YING Wei-yong, FANG Ding-ye. F-T synthesis of Co-Ru/Al₂O₃ catalyst[J]. Petrochem Technol, 2008,37(1):34-38.
25. [25]
  JIN Y, XIAO G Q, HAN Y Y, SUN F L, ZHANG D H, ZHANG Y H, LI J L, HONG J P. Products selectivity and reaction stability of cobalt-based Fischer-Tropsch catalysts affected by glow discharge plasma treatment and silica structure[J]. Catal Today, 2019,337:139-146. doi: 10.1016/j.cattod.2019.04.023
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