Citation: TAN Liang, MIAO Lei, WU Kui, WANG Wei-yan, YANG Yun-quan. Preparation of Ru/Co-Al-O supported catalysts and its hydrodeoxygenation properties[J]. Journal of Fuel Chemistry and Technology, ;2018, 46(2): 219-224. shu

Preparation of Ru/Co-Al-O supported catalysts and its hydrodeoxygenation properties

School of Chemical Engineering, Xiangtan University, Xiangtan 411105, China

Corresponding author: WANG Wei-yan, wangweiyan@xtu.edu.cn.
Received Date: 30 August 2017
Revised Date: 4 January 2018

Fund Project: Hunan Province Graduate Research and Innovation Funded Projects CX2017B334the National Natural Science Foundation of China 21776236The project was supported by the National Natural Science Foundation of China (21776236, 21676225) and Hunan Province Graduate Research and Innovation Funded Projects(CX2017B334)the National Natural Science Foundation of China 21676225

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Co-Al layered double hydroxides were prepared by co-precipitation method and converted into composite oxides via calcination.The composite oxide were then used to prepare a series of Ru/Co-Al-O supported catalysts.The structures and properties of the catalysts were characterized by XRD, BET and FT-IR.The hydrodeoxygenation (HDO) properties of these catalysts were tested by using 4-methylphenol as a typical oxygen-containing model compound of lignin biomass oil.This study concentrated on the effects of Co/Al molar ratio and the reduction temperature of the catalyst on the hydrodeoxygenation activity of Ru/Co-Al-O and the optimization of HDO temperature.The results showed that when the molar ratio of Co/Al was 3:1, the catalyst reduction temperature was 350℃ and the reaction temperature was 275℃, the HDO activity was the highest:both the conversion and deoxygenation degree in the HDO of p-methyl phenol reached up to 100%.
- hydrodeoxygenation,
- Co-Al layered double hydroxides,
- Ru,
- 4-methylphenol,
- composite oxides
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