Citation: WANG Lei, ZHAO Xin-hua, XIONG Zhen-hu, ZHANG Jin-miao, LI Chen, WU Chun-sheng. Combination of amino functionalized metal organic framework with nitrogenous compounds in model fuel[J]. Journal of Fuel Chemistry and Technology, ;2016, 44(9): 1089-1098. shu

Combination of amino functionalized metal organic framework with nitrogenous compounds in model fuel

1.
School of Environmental Science and Engineering, Tianjin University, Tianjin 300072, China
2.
School of Environmental and Municipal Engineering, Tianjin Chengjian University, Tianjin 300384, China

Corresponding author: WANG Lei, zhenhu.xiong@126.com; wangl1026@tcu.edu.cn
Received Date: 16 March 2016
Revised Date: 12 May 2016

Fund Project: the National Natural Science Foundation of China 50878138

Figures(7)

The metal-organic frameworks, MIL-53 (Al)-NH₂ and MIL-53 (Al), were synthesized and used as the adsorbents for the removal of nitrogen-containing compounds (quinoline and pyrrole) from model fuel. The adsorbents were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), FT-IR spectroscopy, and thermogravimetric analysis. Compared with the adsorption capacity of MIL-53 (Al), MIL-53(Al)-NH₂ possesses a higher adsorption capacity for quinoline and pyrrole in the model fuel due to the hydrogen bonding interaction between MIL-53(Al)-NH₂ and the nitrogen-containing compounds. The factors affecting the adsorption capacity are the adsorptive time and temperature. Furthermore, the pseudo-first-order and pseudo-second-order adsorption kinetics models were tested. It is found that the pseudo-second-order kinetics model is preferable to characterize the adsorption process. The adsorption isotherms and adsorption thermodynamics of quinoline and pyrrole on the MIL-53(Al)-NH₂ were also evaluated. The calculation of separation factor R_L and thermodynamic parameters (ΔG⁰, ΔH⁰和ΔS⁰) show that the adsorption of quinoline/pyrrole on the MIL-53(Al)-NH₂ is a spontaneous and exothermic process. The used MIL-53 (Al)-NH₂ could be regenerated by simple solvent washing with ethanol and reused in the adsorption process.
- MIL-53(Al)-NH₂,
- nitrogen-containing compounds,
- adsorptive denitrogenation,
- model fuel,
- hydrogen bonding interaction
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沈阳化工大学材料科学与工程学院沈阳 110142