Citation:
Guo Dong ZHENG, Qing Da AN, Yu Wen LIU, Ying Jun WANG, Xi Zhang CAO. ELECTROCARBOXYLATION OF ORGANIC COMPOUNDS WITH CARBON DIOXIDE CATALYZED BY METALLOPORPHYRINS(Ⅱ)--ELECTROSYNTHESIS OF SOME ORGANIC COMPOUNDS WITH CO2 CATALYZED BY CoTPP[J]. Chinese Chemical Letters,
;1992, 3(4): 265-266.
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The catalyzation of CoTPP for electrocarboxylation of alkyl halides, alkenes and ketones with CO2 are studied. The electrocarboxylation of these organic compounds with CO2 in the presenec of catalyst can occur at more positive potential than that of no catalyst. The products of electrocarboxylation were identified by UV, IR and GC-MS. The electrocarboxylation mechanisms of different organic compounds are discussed
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