Citation: JI Ting-ting, YANG Xiao-xuan, WANG Ya-jing, WANG Yu-he. Steam reforming of phenol for producing hydrogen over nickel support on MgO prepared by different methods[J]. Journal of Fuel Chemistry and Technology, ;2016, 44(9): 1131-1137. shu

Steam reforming of phenol for producing hydrogen over nickel support on MgO prepared by different methods

College of Chemistry and Chemical Engineering, Harbin Normal University, Harbin 150025, China

Corresponding author: WANG Yu-he, wangyuhe@hrbnu.edu.cn
Received Date: 9 May 2016
Revised Date: 29 June 2016

Fund Project: Program for Scientific and Technological Innovation Team Construction in University of Heilongjiang Province 2011TD010Overseas Scholars Program of Department of Education, Heilongjiang Province 1155h019

Figures(6)

MgO-supported nickel catalysts were prepared by impregnation and hydrothermal coprecipitation methods; they were characterized by XRD, N₂ sorption, H₂-TPR, TEM and TG and used in the steam reforming of biomass oil model compound-phenol for hydrogen production. The results indicated that the NiO/MgO solid solution prepared by the impregnation method displays higher surface area (60.6 m²/g) and larger pore diameter (10.1 nm), in comparison with that prepared by hydrothermal coprecipitation. After reduction, the mesoporous Ni/MgO catalyst obtained from impregnation exhibits small and uniform Ni nanoparticles (5.0-6.0 nm) with high dispersion (19.44%). As high surface area is favorable for the dispersion of Ni nanoparticles and mesoporous structure can promote the mass transfer of reactants and products, the Ni/MgO catalyst exhibits high activity as well as excellent coke resistance ability and long-term stability in the steam reforming of phenol.
- mesoporous MgO,
- Ni/MgO catalyst,
- steam reforming,
- phenol,
- hydrogen
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