Citation: Zhou Qingxiang, Liu Yang, Ke Ming. Research Progress of Catalysts for Isobutane Direct Dehydrogenation to Isobutene[J]. Chemistry, ;2017, 80(9): 835-844. shu

Research Progress of Catalysts for Isobutane Direct Dehydrogenation to Isobutene

1.
Division of Scientific and Technological Information, PetroChina Haerbin Petrochemical Co., Ltd., Haerbin 150056
2.
College of Science, China University of Petroleum, Beijing 102249

Corresponding author: Ke Ming, mwyl123@sina.com
Received Date: 16 January 2017
Accepted Date: 18 April 2017

Figures(7)

The differences between isobutane direct dehydrogenation and oxydehydrogenation were summarized from the perspective of thermodynamics and reaction mechanism. The catalysts for the direct dehydrogenation of isobutane to isobutene, including PtSn-、CrO_x-、GaO_x-base and metal sulfide catalyst, are reviewed in terms of the nature of active center, deactivation-regeneration, the promoters and carriers. The advantages and disadvantages of the catalysts and the current research direction were analyzed. Other types of dehydrogenation catalysts were summarized, including Mo/MgAl₂O₄, carbon-based material, Co-, Ni₂P-, VO_x-based catalysts, etc. The problems of current dehydrogenation technology and the future research direction were analyzed.
- Isobutane,
- C4 hydrocarbons,
- Dehydrogenation,
- Isobutene,
- Catalyst
1. [1]
2. [2]
3. [3]
4. [4]
5. [5]
6. [6]
  Q J Zhu, M Takiguchi, T Setoyama et al. Catal. Lett., 2011, 141(5):670~677.
7. [7]
  J F Ding, Z F Qin, S W Chen et al. J. Fuel Chem. Technol., 2010, 38(4):458~461.
8. [8]
  L Horiuti, M Polanyi. Transac. Faraday Soc., 1934, 30:1164~1172.
9. [9]
  R D Cortright, P E Levin, J A Dumesic. Ind. Eng. Chem. Res., 1998, 37(5):1717~1723.
10. [10]
  S M K Airaksinen, M E Harlin, A O I Krause. Ind. Eng. Chem. Res., 2002, 41(23):5619~5626.
11. [11]
  J J Sattler, J Ruiz-Martinez, E Santillan-Jimenez et al. Chem. Rev., 2014, 114(20):10613~10653.
12. [12]
13. [13]
14. [14]
  Y Zhang, Y Zhou, L Wan et al. Fuel Proc. Technol., 2011, 92(8):1632~1638.
15. [15]
16. [16]
  N S Nesterenko, O A Ponomoreva, V V Yuschenko et al. Appl. Catal. A, 2003, 254(2):261~272.
17. [17]
  Z Nawaz. Rev. Chem. Eng., 2015, 31(5):413~436.
18. [18]
  B V Vora. Top. Catal., 2012, 55(19~20):1297~1308.
19. [19]
  Y Nagai, T Hirabayashi, K Dohmae et al. J. Catal., 2006, 242(1):103~109.
20. [20]
  L W Lin, T Zhang, J L Zang et al. Appl. Catal., 1990, 67(1):11~23.
21. [21]
  R D Cortright, J A Dumesic. J. Catal., 1995, 157(2):576~583.
22. [22]
  B M Nagaraja, C H Shin, K D Jung. Appl. Catal. A, 2013, 467:211~223.
23. [23]
  C L Yu, H Y Xu, Q J Ge et al. J. Mol. Catal. A, 2007, 266(1~2):80~87.
24. [24]
  M H Lee, B M Nagaraja,K Y Lee et al. Catal. Today, 2014, 232(4):53~62.
25. [25]
  A Virnovskaia, S Morandi, E Rytter et al. J. Phys. Chem. C, 2007, 111(40):14732~14742.
26. [26]
  B K Vu, M B Song, I Y Ahn et al. Catal. Today, 2011, 164(1):214~220.
27. [27]
  G J Siri, G R Bertolini, M L Caselle et al. Mater. Lett., 2005, 59(18):2319~2324.
28. [28]
  B M Nagaraja, H Jung, D R Yang et al. Catal. Today, 2014, 232:40~52.
29. [29]
  L Y Bai, Y M Zhou, T W Zhang et al. Catal. Lett., 2009, 129(3):449~456.
30. [30]
  J Silvestre-Albero, J C Serrano-Ruiz, A Sepvlveda-Escribano et al. Appl. Catal. A, 2005, 292(1):244~251.
31. [31]
  G Siddiqi, P Sun, V Gavita et al. J. Catal., 2010, 274(2):200~206.
32. [32]
  P Sun, S Georges, M Chi et al. J. Catal., 2010, 274(2):192~199.
33. [33]
  A D Ballarini, P Zgolicz, I M J Vilella et al. Appl. Catal. A, 2010, 381(1~2):83~91.
34. [34]
  S A Bocanegra, A A Castro, O A Scelza et al. Appl. Catal. A, 2007, 333(1):49~56.
35. [35]
  H Seo, K Lee, G Hong et al. J. Nanosci. Nanotech., 2015, 15(10):8318~8323.
36. [36]
  M Setnicka, Z Tisler, D Kubicka et al. Top. Catal., 2015, 58(14):866~876.
37. [37]
  R D Cortright, J M Hill, J A Dumesic. Catal. Today, 2000, 55(3):213~223.
38. [38]
  K G Azzam, G Jacobs, W D Shafer et al. Appl. Catal. A, 2010, 390(1~2):264~270.
39. [39]
  C Jaye, M Tilyard. Fuel Proc. Technol., 2007, 88(9):883~889.
40. [40]
  B K Vu, M B Song, I Y Ahn et al. Appl. Catal. A, 2011, 400(1~2):25~33.
41. [41]
  V Galvita, G Siddiqi, P Sun et al. J. Catal., 2010, 271(2):209~219.
42. [42]
  P L D Cola, R Glaser, J Weitkamp. Appl. Catal. A, 2006, 306(143):85~97.
43. [43]
  Y Zhang, Y Zhou, J Shi et al. J. Mol. Catal. A, 2014, 381(1):138~147.
44. [44]
  S J Zhou, Y M Zhou, Y W Zhang et al. J. Mol. Catal. Sci., 2014, 49(3):1170~1178.
45. [45]
  S Delsarte, F Mauge, P Grange. J. Catal., 2001, 202(1):1~13.
46. [46]
  S Bocanegra, A Ballarini, P Zgolicz et al. Catal. Today, 2009, 143(3):334~340.
47. [47]
  Z Nawaz, F Baksh, J Zhu et al. J. Ind. Eng. Chem., 2013, 19(2):540~546.
48. [48]
  J C Serrano-Ruiz, A Sepulveda-Escribano, F Rodriguez-Reinoso. J. Catal., 2007, 246(1):158~165.
49. [49]
  M Ohta, Y Ikeda, A Igarashi. Appl. Catal. A, 2004, 266(2):229~233.
50. [50]
  B Gu, S He, X Rong et al. Catal. Lett., 2016, 146(8):1415~1422.
51. [51]
  A H Dong, K Wang, S Z Zhu et al. Fuel Proc. Technol., 2017, 158:218~225.
52. [52]
  R Grabowski, B Grzybowska, J Slczynski et al. Appl. Catal. A, 1996, 144(1~2):335~341.
53. [53]
  M Hoang, J F Mathews, K C Pratt. J. Catal., 1997, 171(1):320~324.
54. [54]
  A Hakuli, A Kytokivi, A O I Krause et al. J. Catal., 1996, 161(1):393~400.
55. [55]
  E Rombi, M G Cutrufello, V Solinas et al. Appl. Catal. A, 2003, 251(2):255~266.
56. [56]
  V Z Vladimir, R Fridman, M Severance. Appl. Catal. A, 2016, 523:39~53.
57. [57]
  B M Weckhuysen, R A Schoonheydt. Catal. Today, 1999, 51(2):223~232.
58. [58]
  D Sanfilippo, I Miracca. Catal. Today, 2006, 111(1~2):133~139.
59. [59]
  D R Fang, J B Zhao, W J Li et al. J. Energy Chem., 2015, 24(1):101~107.
60. [60]
  R L Puurunen, B M Weckhuysen, J. Catal., 2002, 210(2):418~430.
61. [61]
  B M Weckhuysen, L M D Ridder, P J Grobet et al. J. Phys. Chem., 1995, 99(1):320~326.
62. [62]
  P P Li, W Z Lang, K Xia et al. Appl. Catal. A, 2016, 522:172~179.
63. [63]
  S D Rossi, G Ferraris, S Fremitti et al. Appl. Catal. A, 1993, 106(1):125~141.
64. [64]
  S T Korhonen, S M K Airaksinen, M A Banares et al. Appl. Catal. A, 2007, 333(1):30~41.
65. [65]
  S Udomsak, R G Anthony. Ind. Eng. Chem. Res., 1996, 35(1):47~53.
66. [66]
  S Kilicarslan, M Dogan, T Dogu. Ind. Eng. Chem. Res., 2013, 52(10):3674~3682.
67. [67]
  T A Bugrova, N N Litvyakova, G V Mamontov. Kinet. Catal., 2015, 56(6):758~763.
68. [68]
  T Otroshchenko, J Radnik, M Schneider et al. Chem. Commun., 2016, 52(52):8164~8167.
69. [69]
70. [70]
  B Zheng, W Hua, Y Yue et al. J. Catal., 2005, 232(1):143~151.
71. [71]
  N S Nesterenko, O A Ponomoreva, V V Yuschenko et al. Appl. Catal. A, 2003, 254(2):261~272.
72. [72]
  G Wang, C Li, H Shan. Catal. Sci. Technol., 2016, 6(9):3128~3136.
73. [73]
  J Han, G Jiang, S Han et al. Catalysts, 2016, 6(1):13.
74. [74]
  G Wang, Z Meng, J Liu et al. ACS Catal., 2013, 3(12):2992~3001.
75. [75]
  Y N Sun, Y N Gao, Y Wu et al. Catal. Commun., 2015, 60:42~45.
76. [76]
  G Wang, C Li, H Shan. ACS Catal., 2014, 4(4):1139~1143.
77. [77]
  G Wang, C Gao, X Zhu et al. ChemCatChem, 2014, 6(8):2305~2314.
78. [78]
  Y N Sun, L Tao, T You et al. Chem. Eng. J., 2014, 244(10):145~151.
79. [79]
  G Wang, C Li, H Shan et al. Ind. Eng. Chem. Res., 2013, 52(27):13297~13304.
80. [80]
  Y Li, J Zhang, J Wang et al. Chin. J. Catal., 2015, 36(8):1214~1222.
81. [81]
  G Wang, X Zhu, J Zhang et al. RSC Adv., 2014, 4(100):57071~57082.
82. [82]
83. [83]
  Y L Xu, H X Sang, K Wang et al. Appl. Surf. Sci., 2014, 316:163~170.
84. [84]
  Y L Xu, X T Wang, L Rong. React. Kinet. Mech. Catal., 2014, 113(2):393~406.
85. [85]
  M A Chaar, D Patel, M C Kung et al. J. Catal., 1987, 105(2):483~498.
86. [86]
  Y P Tian, P Bai, S M Liu et al. Fuel Proc. Technol., 2016, 151:31~39.
87. [87]
  U Rodemerck, S Sokolov, M Stoyanova et al. J. Catal., 2016, 338:174~183.
88. [88]
  Z Zhang, Y Li, J Wang et al. Catal. Sci. Technol., 2016, 6:4863~4871.
1. [1]
  Lele Feng , Xueying Bai , Jifeng Pang , Hongchen Cao , Xiaoyan Liu , Wenhao Luo , Xiaofeng Yang , Pengfei Wu , Mingyuan Zheng . Single-atom Pd boosted Cu catalysts for ethanol dehydrogenation. Acta Physico-Chimica Sinica, 2025, 41(9): 100100-0. doi: 10.1016/j.actphy.2025.100100
2. [2]
  Peng YUE , Liyao SHI , Jinglei CUI , Huirong ZHANG , Yanxia GUO . Effects of Ce and Mn promoters on the selective oxidation of ammonia over V₂O₅/TiO₂ catalyst. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 293-307. doi: 10.11862/CJIC.20240210
3. [3]
  Bing WEI , Jianfan ZHANG , Zhe CHEN . Research progress in fine tuning of bimetallic nanocatalysts for electrocatalytic carbon dioxide reduction. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 425-439. doi: 10.11862/CJIC.20240201
4. [4]
  Wentao Xu , Xuyan Mo , Yang Zhou , Zuxian Weng , Kunling Mo , Yanhua Wu , Xinlin Jiang , Dan Li , Tangqi Lan , Huan Wen , Fuqin Zheng , Youjun Fan , Wei Chen . Bimetal Leaching Induced Reconstruction of Water Oxidation Electrocatalyst for Enhanced Activity and Stability. Acta Physico-Chimica Sinica, 2024, 40(8): 2308003-0. doi: 10.3866/PKU.WHXB202308003
5. [5]
  Yongwei ZHANG , Chuang ZHU , Wenbin WU , Yongyong MA , Heng YANG . Efficient hydrogen evolution reaction activity induced by ZnSe@nitrogen doped porous carbon heterojunction. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 650-660. doi: 10.11862/CJIC.20240386
6. [6]
  Zhaoyu Wen , Na Han , Yanguang Li . Recent Progress towards the Production of H₂O₂ by Electrochemical Two-Electron Oxygen Reduction Reaction. Acta Physico-Chimica Sinica, 2024, 40(2): 2304001-0. doi: 10.3866/PKU.WHXB202304001
7. [7]
  Xuejie Wang , Guoqing Cui , Congkai Wang , Yang Yang , Guiyuan Jiang , Chunming Xu . Research Progress on Carbon-based Catalysts for Catalytic Dehydrogenation of Liquid Organic Hydrogen Carriers. Acta Physico-Chimica Sinica, 2025, 41(5): 100044-0. doi: 10.1016/j.actphy.2024.100044
8. [8]
  Wei Zhong , Dan Zheng , Yuanxin Ou , Aiyun Meng , Yaorong Su . Simultaneously Improving Inter-Plane Crystallization and Incorporating K Atoms in g-C₃N₄ Photocatalyst for Highly-Efficient H₂O₂ Photosynthesis. Acta Physico-Chimica Sinica, 2024, 40(11): 2406005-0. doi: 10.3866/PKU.WHXB202406005
9. [9]
  Lu Zhuoran , Li Shengkai , Lu Yuxuan , Wang Shuangyin , Zou Yuqin . Cleavage of C―C Bonds for Biomass Upgrading on Transition Metal Electrocatalysts. Acta Physico-Chimica Sinica, 2024, 40(4): 2306003-0. doi: 10.3866/PKU.WHXB202306003
10. [10]
  Xichen YAO , Shuxian WANG , Yun WANG , Cheng WANG , Chuang ZHANG . Oxygen reduction performance of self?supported Fe/N/C three-dimensional aerogel catalyst layers. Chinese Journal of Inorganic Chemistry, 2025, 41(7): 1387-1396. doi: 10.11862/CJIC.20240384
11. [11]
  Jun LI , Huipeng LI , Hua ZHAO , Qinlong LIU . Preparation and photocatalytic performance of AgNi bimetallic modified polyhedral bismuth vanadate. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 601-612. doi: 10.11862/CJIC.20230401
12. [12]
  Haoyu Sun , Dun Li , Yuanyuan Min , Yingying Wang , Yanyun Ma , Yiqun Zheng , Hongwen Huang . Hierarchical Palladium-Copper-Silver Porous Nanoflowers as Efficient Electrocatalysts for CO₂ Reduction to C₂₊ Products. Acta Physico-Chimica Sinica, 2024, 40(6): 2307007-0. doi: 10.3866/PKU.WHXB202307007
13. [13]
  Yi YANG , Shuang WANG , Wendan WANG , Limiao CHEN . Photocatalytic CO₂ reduction performance of Z-scheme Ag-Cu₂O/BiVO₄ photocatalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 895-906. doi: 10.11862/CJIC.20230434
14. [14]
  Xue Dong , Xiaofu Sun , Shuaiqiang Jia , Shitao Han , Dawei Zhou , Ting Yao , Min Wang , Minghui Fang , Haihong Wu , Buxing Han . Electrochemical CO₂ Reduction to C₂₊ Products with Ampere-Level Current on Carbon-Modified Copper Catalysts. Acta Physico-Chimica Sinica, 2025, 41(3): 2404012-0. doi: 10.3866/PKU.WHXB202404012
15. [15]
  Wei Sun , Yongjing Wang , Kun Xiang , Saishuai Bai , Haitao Wang , Jing Zou , Arramel , Jizhou Jiang . CoP Decorated on Ti₃C₂T_x MXene Nanocomposites as Robust Electrocatalyst for Hydrogen Evolution Reaction. Acta Physico-Chimica Sinica, 2024, 40(8): 2308015-0. doi: 10.3866/PKU.WHXB202308015
16. [16]
  Hailang JIA , Hongcheng LI , Pengcheng JI , Yang TENG , Mingyun GUAN . Preparation and performance of N-doped carbon nanotubes composite Co₃O₄ as oxygen reduction reaction electrocatalysts. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 693-700. doi: 10.11862/CJIC.20230402
17. [17]
  Jiahui YU , Jixian DONG , Yutong ZHAO , Fuping ZHAO , Bo GE , Xipeng PU , Dafeng ZHANG . The morphology control and full-spectrum photodegradation tetracycline performance of microwave-hydrothermal synthesized BiVO₄:Yb³⁺,Er³⁺ photocatalyst. Journal of Fuel Chemistry and Technology, 2025, 53(3): 348-359. doi: 10.1016/S1872-5813(24)60514-1
18. [18]
  Jingping Li , Suding Yan , Jiaxi Wu , Qiang Cheng , Kai Wang . Improving hydrogen peroxide photosynthesis over inorganic/organic S-scheme photocatalyst with LiFePO₄. Acta Physico-Chimica Sinica, 2025, 41(9): 100104-0. doi: 10.1016/j.actphy.2025.100104
19. [19]
  Yajin Li , Huimin Liu , Lan Ma , Jiaxiong Liu , Dehua He . Photothermal Synthesis of Glycerol Carbonate via Glycerol Carbonylation with CO₂ over Au/Co₃O₄-ZnO Catalyst. Acta Physico-Chimica Sinica, 2024, 40(9): 2308005-0. doi: 10.3866/PKU.WHXB202308005
20. [20]
  Fangxuan Liu , Ziyan Liu , Guowei Zhou , Tingting Gao , Wenyu Liu , Bin Sun . 中空结构光催化剂. Acta Physico-Chimica Sinica, 2025, 41(7): 100071-0. doi: 10.1016/j.actphy.2025.100071

Get Citation

PDF

XML

Metrics

PDF Downloads(15)
Abstract views(2318)
HTML views(416)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142