Citation: Zhi Qiang WANG, Shi Wei LU, He Fu GUO, Ning Hai HU. CRYSTAL STRUCTURE OF FIVE-COORDINATE ZIRCONOCENE COMPLEX (MeCp)₂ZrC1(α-C₁₀H₇COO)[J]. Chinese Chemical Letters, ;1991, 2(7): 557-560. shu

CRYSTAL STRUCTURE OF FIVE-COORDINATE ZIRCONOCENE COMPLEX (MeCp)₂ZrC1(α-C₁₀H₇COO)

a Dalian Institute of Chemical Physics Dalian 116023;
b Changchun Institute of Applied Chemistry Changchun

Received Date: 1 April 1991

(MeCp)₂ZrCl(α-C₁₀H₇COO) has five-coordinate bent zirconocene in which the α-naphthoyloxy is a bidentate ligand(Zr-O 2.317(2), 2.260(2)ÅZr-Cl 2.521(1)ÅZr-C 2.480-2.550ÅZr-cent-CH₃C₅H₄ 2.217, 2.23OA;Cl-Zr-O1 134.8(1)⁰;Cl-Zr-O2 78.6(1)^O;O1-Zr-O2 56.3(1)^O).
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