Citation: TONG Guo-tong, WU Rong-sheng. Liquefaction characteristics of Baorixile lignite with syngas and complex solvent[J]. Journal of Fuel Chemistry and Technology, ;2019, 47(6): 661-667. shu

Liquefaction characteristics of Baorixile lignite with syngas and complex solvent

TONG Guo-tong ^1,, ,
WU Rong-sheng ²

1.
Hangzhou Vocational and Technical College, Hangzhou 310018, China
2.
Hangzhou Limo Technology Co. Ltd., Hangzhou 310018, China

Corresponding author: TONG Guo-tong, tonggt@163.com
Received Date: 7 March 2019
Revised Date: 12 April 2019

Fund Project: Hangzhou Key Laboratory of Green Fine Chemical Engineering Research and Technical Conversion 2015ZD12The project was supported by Hangzhou Key Laboratory of Green Fine Chemical Engineering Research and Technical Conversion (2015ZD12)

Figures(6)

The effects of atmosphere, temperature and catalysts on the BRXL lignite liquefaction conversion and the yield of oil, gas, and water were studied with syngas and complex solvents (water+organic solvent), and the characteristics of BRXL lignite liquefaction were also discussed. The results show that the atmosphere of syngas and the temperature of 430-450℃ are beneficial to coal liquefaction reaction under complex solvents system with catalyst. The coal conversion is 81.15%, and the yield of oil, gas, and water reaches to 71.53%. Besides, the composite catalyst (including iron, base, and sulfur) can effectively improve the coal conversion and the yield of oil, gas, and water. The coal conversion and the yield of oil, gas, and water at 430℃ reach to 92.27% and 79.39%, respectively. Also, the composite catalyst can effectively promote the cracking of macromolecules in coal and the enhancement of water-gas shift reaction, resulting in a decrease of asphaltene and an increase of oil yield. Moreover, the polycyclic aromatic hydrocarbons and derivatives in liquefaction oil can be converted to monocyclic aromatic hydrocarbons and derivatives and alkenes olefins during catalytic liquefaction, resulting in a decrease of compound molecular weight and an improvement of oil quality.
- lignite,
- syngas,
- complex solvent,
- direct coal liquefaction,
- catalyst
1. [1]
  FISCHER F, SCHRADER H. The origin and chemical structure of coal[J]. Brennstoff Chem, 1921,2:37-45.
2. [2]
  ZHU M, WACHS I E. Iron-based catalysts for the high-temperature water-gas shift (HT-WGS) reaction:A review[J]. ACS Catal, 2016,6(2):722-732. doi: 10.1021/acscatal.5b02594
3. [3]
  BIANCO A D, PIERO G D, SERENELLINI S. Conversion of coal in CO/H₂O base system:Interaction between water-gas shift reaction catalysts and coal mineral matter[J]. Fuel, 1988,67(6):874-875. doi: 10.1016/0016-2361(88)90167-6
4. [4]
  TAKEMURA Y, OUCHI K. Catalytic liquefaction of various coals using a mixture of carbon monoxide and water[J]. Fuel, 1983,62(10):1133-1137. doi: 10.1016/0016-2361(83)90052-2
5. [5]
  HATA K A, WATANABE Y, WADAK , WADA K, MITSUDO T A. Iron sulfate/sulfur-catalyzed liquefaction of Wandoan coal using syngas-water as a hydrogen source[J]. Fuel Process Technol, 1998,56(3):291-304. doi: 10.1016/S0378-3820(98)00058-7
6. [6]
  LI Q L, CHEN Z, ZHOU Q, LI L, WU S Y. Shengli lignite liquefaction under syngas and complex solvent[J]. J Fuel Chem Technol, 2016,44:257-262. doi: 10.1016/S1872-5813(16)30014-7
7. [7]
  FENG Wan-lu, WU Shi-yong, YOU Quan, WU You-qing, ZHENG Hua-an, MIN Xiao-jian. Effect of moisture amount on liquefaction of Xilinhaote coal under syngas[J]. J East China Univ Technol:Nat Sci Ed, 2017,43(2):156-161.
8. [8]
  YOU Q, WU S Y, WU Y Q, HUANG S, GAO J S, SHANG J X, MIN X J, ZHENG H A. Product distributions and characterizations for integrated mild-liquefaction and carbonization of low rank coals[J]. Fuel Process Technol, 2017,156:54-161. doi: 10.1016/j.fuproc.2016.09.022
9. [9]
  BIANCO A D, GIRARDI E, STROPPA F. Liquefaction of Sulcis subbituminous coal in a CO/water/base system[J]. Fuel, 1990,69(2):240-244. doi: 10.1016/0016-2361(90)90180-X
10. [10]
  WANG Wei-dong, ZOU Chun-yu, ZHAO Jian-tao. Impact of high-temperature and re-heating on low-temperature pyrolysis products and coking of Yilan coal[J]. Coal Chem Ind, 2010,38(2):22-26. doi: 10.3969/j.issn.1005-9598.2010.02.005
11. [11]
  ZHU Pei-zhi, GAO Jin-sheng. Coal Chemistry[M]. Shanghai:Shanghai Scientific & Technical Publishers, 1984.
12. [12]
  CASSIDY P J, JACKSON W R, LARKINS F P, SAKUROVS R J, SUTTON J F. Hydrogenation of brown coal:8. The effect of added promoters and water on the liquefaction of Victorian brown coal using hydrogen, carbon monoxide and synthesis gas[J]. Fuel, 1986,65(3):374-379. doi: 10.1016/0016-2361(86)90298-X
13. [13]
  ZHAO Y Q, ZHANGM , CUI X T, DONG D L, WANG Q, ZHANG Y F. Converting lignite to caking coal via hydro-modification in a subcritical water-CO system[J]. Fuel, 2016,167:1-8. doi: 10.1016/j.fuel.2015.11.028
14. [14]
  PINTO F, GULYURTLU I, LOBO L S, CABRITA I. The role of catalyst impregnation and solvent type in improving liquefaction efficiencies[J]. Coal Sci Technol, 1995,24(6):1307-1310.
15. [15]
  JIN L J, HAN K M, WANG J Y, HU H Q. Direct liquefaction behaviors of Bulianta coal and its macerals[J]. Fuel Process Technol, 2014,128:232-237. doi: 10.1016/j.fuproc.2014.07.033
16. [16]
  KANEKO T, SUGITA S, TAMURA M, SHIMASAKI K, MAKINO E, SILALAHI L H. Highly active limonite catalysts for direct coal liquefaction[J]. Fuel, 2002,81(11):1541-1549.
17. [17]
  HUANG Chuan-rong, WU Shi-yong, NIE Li, QIN Xiao-gang, WU You-qing, GAO Jin-sheng. Effects of iron-based catalysts on liquefaction of Shengli lignite[J]. J East China Univ Technol:Nat Sci Ed, 2014,40(1):21-25. doi: 10.3969/j.issn.1006-3080.2014.01.004
18. [18]
  LI X, ZONG Z M, MA W W, CAO J P, MAYYAS M, WEI Z H, LI Y, YAN H L, WANG D, YANG R, WEI X Y. Multifunctional and highly active Ni/microfiber attapulgite for catalytic hydroconversion of model compounds and coal tars[J]. Fuel Process Technol, 2015,131:39-45.
19. [19]
  GENG Li-li, ZHOU Qi-xiong, MA Feng-yun, LENG Shuai. Study on the distributions of the products of Nantaizi coal during catalytic hydropyrolysis[J]. Coal Convers, 2012,35(1):1-3. doi: 10.3969/j.issn.1004-4248.2012.01.001
20. [20]
  WATANABE R, SAKAMOTO Y, YAMAMURO K, TAMURA S, KIKUCHI E, SEKINE Y. Role of alkali metal in a highly active Pd/alkali/Fe₂O₃ catalyst for water gas shift reaction[J]. Appl Catal A:Gen, 2013,457(4):1-11.
21. [21]
  YANG Li-jun, PAN Tie-ying, SHI Xin-mei, LIN Hua-lin, ZHANG De-xiang, GAO Jin-sheng. Characterization of coal liquefaction oil by ¹H NMR and GC-MS[J]. J Instrum Anal, 2007,26(4):488-491. doi: 10.3969/j.issn.1004-4957.2007.04.008
22. [22]
  MA W W, ZONG Z M, LI X, WEI X Y. Catalytic hydrocracking of extraction residue from Huolinguole lignite over Fe₃O₄/SiO₂/Mg₂Si magnetic solid superbase catalyst[C]. Academic Forum for Graduate Students of "Mechanical Engineering and Thermal Engineering" in Shanghai, 2014.
23. [23]
  WU Xiu-zhang, SHI Yu-lin, XU Chun-ming. Hydro-upgrading pilot test of direct coal liquefaction effluent[J]. Acta Pet Sin:Pet Process Sect, 2009,25(2):156-161. doi: 10.3969/j.issn.1001-8719.2009.02.004
24. [24]
  SHAN X G, SHU G P, LI K J, ZHANG X W, WANG H X, CAO X P, JIANG H B, WEN H X. Effect of hydrogenation of liquefied heavy oil on direct coal liquefaction[J]. Fuel, 2017,194:291-296. doi: 10.1016/j.fuel.2017.01.034
1. [1]
  Peng YUE , Liyao SHI , Jinglei CUI , Huirong ZHANG , Yanxia GUO . Effects of Ce and Mn promoters on the selective oxidation of ammonia over V₂O₅/TiO₂ catalyst. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 293-307. doi: 10.11862/CJIC.20240210
2. [2]
  Bing WEI , Jianfan ZHANG , Zhe CHEN . Research progress in fine tuning of bimetallic nanocatalysts for electrocatalytic carbon dioxide reduction. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 425-439. doi: 10.11862/CJIC.20240201
3. [3]
  Wentao Xu , Xuyan Mo , Yang Zhou , Zuxian Weng , Kunling Mo , Yanhua Wu , Xinlin Jiang , Dan Li , Tangqi Lan , Huan Wen , Fuqin Zheng , Youjun Fan , Wei Chen . Bimetal Leaching Induced Reconstruction of Water Oxidation Electrocatalyst for Enhanced Activity and Stability. Acta Physico-Chimica Sinica, 2024, 40(8): 2308003-0. doi: 10.3866/PKU.WHXB202308003
4. [4]
  Yongwei ZHANG , Chuang ZHU , Wenbin WU , Yongyong MA , Heng YANG . Efficient hydrogen evolution reaction activity induced by ZnSe@nitrogen doped porous carbon heterojunction. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 650-660. doi: 10.11862/CJIC.20240386
5. [5]
  Zhaoyu Wen , Na Han , Yanguang Li . Recent Progress towards the Production of H₂O₂ by Electrochemical Two-Electron Oxygen Reduction Reaction. Acta Physico-Chimica Sinica, 2024, 40(2): 2304001-0. doi: 10.3866/PKU.WHXB202304001
6. [6]
  Qingqing SHEN , Xiangbowen DU , Kaicheng QIAN , Zhikang JIN , Zheng FANG , Tong WEI , Renhong LI . Self-supporting Cu/α-FeOOH/foam nickel composite catalyst for efficient hydrogen production by coupling methanol oxidation and water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1953-1964. doi: 10.11862/CJIC.20240028
7. [7]
  Xichen YAO , Shuxian WANG , Yun WANG , Cheng WANG , Chuang ZHANG . Oxygen reduction performance of self?supported Fe/N/C three-dimensional aerogel catalyst layers. Chinese Journal of Inorganic Chemistry, 2025, 41(7): 1387-1396. doi: 10.11862/CJIC.20240384
8. [8]
  Ruolin CHENG , Haoran WANG , Jing REN , Yingying MA , Huagen LIANG . Efficient photocatalytic CO₂ cycloaddition over W₁₈O₄₉/NH₂-UiO-66 composite catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 523-532. doi: 10.11862/CJIC.20230349
9. [9]
  Lutian Zhao , Yangge Guo , Liuxuan Luo , Xiaohui Yan , Shuiyun Shen , Junliang Zhang . Electrochemical Synthesis for Metallic Nanocrystal Electrocatalysts: Principle, Application and Challenge. Acta Physico-Chimica Sinica, 2024, 40(7): 2306029-0. doi: 10.3866/PKU.WHXB202306029
10. [10]
  Wei Sun , Yongjing Wang , Kun Xiang , Saishuai Bai , Haitao Wang , Jing Zou , Arramel , Jizhou Jiang . CoP Decorated on Ti₃C₂T_x MXene Nanocomposites as Robust Electrocatalyst for Hydrogen Evolution Reaction. Acta Physico-Chimica Sinica, 2024, 40(8): 2308015-0. doi: 10.3866/PKU.WHXB202308015
11. [11]
  Jun LI , Huipeng LI , Hua ZHAO , Qinlong LIU . Preparation and photocatalytic performance of AgNi bimetallic modified polyhedral bismuth vanadate. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 601-612. doi: 10.11862/CJIC.20230401
12. [12]
  Jiapei Zou , Junyang Zhang , Xuming Wu , Cong Wei , Simin Fang , Yuxi Wang . A Comprehensive Experiment Based on Electrocatalytic Nitrate Reduction into Ammonia: Synthesis, Characterization, Performance Exploration, and Applicable Design of Copper-based Catalysts. University Chemistry, 2024, 39(6): 373-382. doi: 10.3866/PKU.DXHX202312081
13. [13]
  Zelong LIANG , Shijia QIN , Pengfei GUO , Hang XU , Bin ZHAO . Synthesis and electrocatalytic CO₂ reduction performance of metal-organic framework catalysts loaded with silver particles. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 165-173. doi: 10.11862/CJIC.20240409
14. [14]
  Xiaofang Li , Zhigang Wang . 调节金助催化剂的d_z²占据轨道增强光催化合成H₂O₂. Acta Physico-Chimica Sinica, 2025, 41(7): 100080-0. doi: 10.1016/j.actphy.2025.100080
15. [15]
  Xi YANG , Chunxiang CHANG , Yingpeng XIE , Yang LI , Yuhui CHEN , Borao WANG , Ludong YI , Zhonghao HAN . Co-catalyst Ni₃N supported Al-doped SrTiO₃: Synthesis and application to hydrogen evolution from photocatalytic water splitting. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 440-452. doi: 10.11862/CJIC.20240371
16. [16]
  Lewang Yuan , Yaoyao Peng , Zong-Jie Guan , Yu Fang . Insights into the development of 2D covalent organic frameworks as photocatalysts in organic synthesis. Acta Physico-Chimica Sinica, 2025, 41(8): 100086-0. doi: 10.1016/j.actphy.2025.100086
17. [17]
  Yajin Li , Huimin Liu , Lan Ma , Jiaxiong Liu , Dehua He . Photothermal Synthesis of Glycerol Carbonate via Glycerol Carbonylation with CO₂ over Au/Co₃O₄-ZnO Catalyst. Acta Physico-Chimica Sinica, 2024, 40(9): 2308005-0. doi: 10.3866/PKU.WHXB202308005
18. [18]
  Wei Zhong , Dan Zheng , Yuanxin Ou , Aiyun Meng , Yaorong Su . Simultaneously Improving Inter-Plane Crystallization and Incorporating K Atoms in g-C₃N₄ Photocatalyst for Highly-Efficient H₂O₂ Photosynthesis. Acta Physico-Chimica Sinica, 2024, 40(11): 2406005-0. doi: 10.3866/PKU.WHXB202406005
19. [19]
  Fangxuan Liu , Ziyan Liu , Guowei Zhou , Tingting Gao , Wenyu Liu , Bin Sun . 中空结构光催化剂. Acta Physico-Chimica Sinica, 2025, 41(7): 100071-0. doi: 10.1016/j.actphy.2025.100071
20. [20]
  Wenlong LI , Xinyu JIA , Jie LING , Mengdan MA , Anning ZHOU . Photothermal catalytic CO₂ hydrogenation over a Mg-doped In₂O_3-x catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 919-929. doi: 10.11862/CJIC.20230421

Get Citation

PDF

XML

Metrics

PDF Downloads(7)
Abstract views(1467)
HTML views(124)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142