Citation: SONG Hua, GONG Jing, JANG Nan, LI Feng, DAI Min, ZHANG Jiao-jing, YU De-zhi. Effect of P/Ni ratio on the structure and hydrodesulfurization performance of nickel phosphide catalyst prepared by the solvothermal method[J]. Journal of Fuel Chemistry and Technology, ;2016, 44(5): 557-563. shu

Effect of P/Ni ratio on the structure and hydrodesulfurization performance of nickel phosphide catalyst prepared by the solvothermal method

SONG Hua ^1,2,*,, ,
GONG Jing ¹ ,
JANG Nan ¹ ,
LI Feng ^1,2 ,
DAI Min ^1,3 ,
ZHANG Jiao-jing ² ,
YU De-zhi ²

1.
College of Chemistry & Chemical Engineering, Northeast Petroleum University, Daqing 163318, China
2.
Provincial Key Laboratory of Oil & Gas Chemical Technology, Northeast Petroleum University, Daqing 163318, China
3.
CPE Xinjiang Petroleum Prospecting and Design Research Institute (Co., Ltd.), Karamay 834000, China

Corresponding author: SONG Hua, songhua2004@sina.com
Received Date: 10 December 2015
Revised Date: 5 February 2016

Fund Project: the Graduate Innovation Project of Northeast Petroleum University YJSCX2014-022NEPUthe Project of Education department of Heilongjiang Province 12541060the National Natural Science Foundation of China 21276048

Figures(4)

A series of MCM-41-supported Ni_xP catalysts was prepared by the solvothermal method using low-price triphenylphosphine as phosphorus material and tri-n-octylamine as coordinating liquid reaction system. They were characterized with X-ray diffraction, N₂ sorption, CO sorption, X-ray photoelectron spectroscopy and transmission electron microscopy techniques. The effects of initial P/Ni molar ratio on their structures and hydrodesulfurization performances were investigated in a lab-scale continuous flow fixed-bed reactor by feeding 1% of dibenzothiophene (DBT) in decahydronaphthalene. It was shown that Ni₁₂P₅ was primarily formed with a small amount of Ni₂P at the initial P/Ni molar ratio of 0.5. When the initial P/Ni molar ratio was higher than 0.5, pure Ni₂P phase was generated, and its crystal size decreased, and thus, its dispersion increased with the increase of initial P/Ni molar ratio. At 613 K, 3.0 MPa, H₂/oil ratio of 500 (volume ratio), and weight hourly space velocity of 2.0 h^-1, the DBT conversion nearly reached 100% on both the Ni-P (6)/MCM-41 and the Ni-P (10)/MCM-41 samples.
- solvothermal method,
- nickel phosphide,
- dibenzothiophene,
- hydrodesulfurization
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沈阳化工大学材料科学与工程学院沈阳 110142