Citation: Hui Chen, Qingfu Wang, Tingting Liu, Yao Zhang, Duo Zhou, Yunfei Li. Progress in Hydrogenation/Dehydrogenation Reactions Catalyzed by Non-Noble Metal Complexes of Iron, Cobalt and Manganese[J]. Chemistry, ;2021, 84(3): 232-239. shu

Progress in Hydrogenation/Dehydrogenation Reactions Catalyzed by Non-Noble Metal Complexes of Iron, Cobalt and Manganese

Hui Chen ¹ ,
Qingfu Wang ² ,
Tingting Liu ^1,, ,
Yao Zhang ¹ ,
Duo Zhou ¹ ,
Yunfei Li ¹

1.
Institute of Chemistry, Henan Academy of Sciences, Zhengzhou, 450002
2.
Technology Center, China Tobacco Henan Industrial Co., Ltd., Zhengzhou, 450000

Corresponding author: Tingting Liu, liutingting@kingorgchem.com
Received Date: 9 July 2020
Accepted Date: 11 September 2020

Figures(2)

Catalytic hydrogenation and dehydrogenation reactions are the core of the modern chemical industry. From the exploration of milligram-level organic chemical reactions to the production of tons of chemicals, there are wide applications of catalytic hydrogenation and dehydrogenation reactions. For a long time, precious metal catalysts have been the key to the catalytic hydrogenation and dehydrogenation of nitrogen-containing and oxygen-containing compounds. From the perspective of environmental protection and sustainable development, in recent years, non-noble metal-catalyzed hydrogenation and dehydrogenation reactions have made important research progress. This review aims to introduce the significant progress made in the development of non-noble metal-catalyzed hydrogenation and dehydrogenation conversions.
- Iron,
- Cobalt,
- Manganese,
- Metal complexes,
- Catalysis
1. [1]
  Alig L, Fritz M, Schneider S. Chem. Rev., 2019, 119(4): 2681~2751.
2. [2]
  Gunanathan C, Milstein D. Science, 2013, 341(6143): 1229712.
3. [3]
  Kumar A, Bhatti T M, Goldman A S. Chem. Rev., 2017, 117(19): 12357~12384.
4. [4]
  Crabtree R H. Chem. Rev., 2017, 117(13): 9228~9246.
5. [5]
  Filonenko G A, van Putten R, Hensen E J M, et al. Chem. Soc. Rev., 2018, 47: 1459~1483.
6. [6]
  Sui-Seng C, Haque F N, Hadzovic A, et al. Inorg. Chem., 2009, 48(2): 735~743.
7. [7]
  Langer R, Leitus G, Ben-David Y, et al. Angew. Chem. Int. Ed., 2011, 50(9): 2120~2124.
8. [8]
  Langer R, Diskin-Posner Y, Leitus G, et al. Angew. Chem. Int. Ed., 2011, 50(42): 9948~9952
9. [9]
  Zirakzadeh A, Kirchner K, Roller A, et al. Organometallics, 2016, 35(21): 3781~3787.
10. [10]
  Smith S A M, Lagaditis P O, Lüpke A, et al. Chem. Eur. J., 2017, 23(30): 7212~7216.
11. [11]
  Zell T, Ben-David Y, Milstein D. Angew. Chem. Int. Ed., 2014, 53(18): 4685~4689.
12. [12]
  Gajewski P, Gonzalez-de-Castro A, Renom-Carrasco M, et al. ChemCatChem, 2016, 8(22): 3431~3435.
13. [13]
  Werkmeister S, Junge K, Wendt B, et al. Angew. Chem. Int. Ed., 2014, 53(33): 8722~8726.
14. [14]
  Chakraborty S, Dai H, Bhattacharya P, et al. J. Am. Chem. Soc., 2014, 136(22): 7869~7872.
15. [15]
  Lange S, Elangovan S, Cordes C, et al. Catal. Sci. Technol., 2016, 6: 4768~4772.
16. [16]
  Bornschein C, Werkmeister S, Wendt B, et al. Nat. Commun., 2014, 5: 4111.
17. [17]
  Chakraborty S, Leitus G, Milstein D. Chem. Commun., 2016, 52: 1812~1815.
18. [18]
  Chakraborty S, Milstein D. ACS Catal., 2017, 7(6): 3968~3972.
19. [19]
  Garg J A, Chakraborty S, Ben-David Y, et al. Chem. Commun., 2016, 52: 5285~5288.
20. [20]
  Schneck F, Assmann M, Balmer M, et al. Organometallics, 2016, 35(11): 1931~1943.
21. [21]
  Rezayee N M, Samblanet D C, Sanford M S. ACS Catal., 2016, 6(10): 6377~6383.
22. [22]
  Jayarathne U, Zhang Y, Hazari N, et al. Organometallics, 2017, 36(2): 409~416.
23. [23]
  Zhang G, Scott B L, Hanson S K. Angew. Chem. Int. Ed., 2012, 51(48): 12102~12106.
24. [24]
  Rösler S, Obenauf J, Kempe R. J. Am. Chem. Soc., 2015, 137(25): 7998~8001.
25. [25]
  Srimani D, Mukherjee A, Goldberg A F G, et al. Angew. Chem. Int. Ed., 2015, 54(42): 12357~12360.
26. [26]
  Yuwen J, Chakraborty S, Brennessel W W, et al. ACS Catal., 2017, 7(5): 3735~3740.
27. [27]
  Korstanje T J, van der Vlugt J I, Elsevier C J, et al. Science, 2015, 350(6258): 298~302.
28. [28]
  Mukherjee A, Srimani D, Chakraborty S, et al. J. Am. Chem. Soc., 2015, 137(28): 8888~8891.
29. [29]
  Adam R, Bheeter C B, Cabrero-Antonino J R, et al. ChemSusChem, 2017, 10(5): 842~846.
30. [30]
  Elangovan S, Topf C, Fischer S, et al. J. Am. Chem. Soc., 2016, 138(28): 8809~8814.
31. [31]
  Elangovan S, Garbe M, Jiao H, et al. Angew. Chem. Int. Ed., 2016, 55(49): 15364~15368.
32. [32]
  Widegren M B, Harkness G J, Slawin A M Z, et al. Angew. Chem. Int. Ed. 2017, 56(21): 5825~5828.
33. [33]
  Kallmeier F, Irrgang T, Dietel T, et al. Angew. Chem. Int. Ed., 2016, 55(39): 11806~11809.
34. [34]
  Garbe M, Junge K, Walker S, et al. Angew. Chem. Int. Ed., 2017, 56(37): 11237~11241.
35. [35]
  van Putten R, Uslamin E A, Garbe M, et al. Angew. Chem. Int. Ed., 2017, 56(26): 7531~7534.
36. [36]
  Espinosa-Jalapa N A, Nerush A, Shimon L J W, et al. Chem. Eur. J., 2017, 23(25): 5934~5938.
37. [37]
  Fu S, Shao Z, Wang Y, et al. J. Am. Chem. Soc., 2017, 139(34): 11941~11948.
38. [38]
  Chakraborty S, Brennessel W W, Jones W D. J. Am. Chem. Soc., 2014, 136(24): 8564~8567.
39. [39]
  Chakraborty S, Lagaditis P O, Förster M. ACS Catal., 2014, 4(11): 3994~4003.
40. [40]
  Sharninghausen L S, Mercado B Q, Crabtree R H, et al. Chem. Commun., 2015, 51: 16201~16204.
41. [41]
  Peña-López M, Neumann H, Beller M. ChemCatChem, 2015, 7(5): 865~871.
42. [42]
  Lane E M, Uttley K B, Hazari N, et al. Organometallics, 2017, 36(10): 2020~2025.
43. [43]
  Chakraborty S, Leitus G, Milstein D. Angew. Chem. Int. Ed., 2017, 56(8): 2074~2078.
44. [44]
  Mastalir M, Stöger B, Pittenauer E, et al. Adv. Synth. Catal., 2016, 358(23): 3824~3831.
45. [45]
  Mastalir M, Glatz M, Gorgas N, et al. Chem. Eur. J., 2016, 22(35): 12316~12320.
46. [46]
  Yan T, Feringa B L, Barta K. Nat. Commun., 2014, 5: 5602.
47. [47]
  Yan T, Feringa B L, Barta K. ACS Catal., 2016, 6(1): 381~388.
48. [48]
  Zhang G, Vasudevan K V, Scott B L, et al. J. Am. Chem. Soc., 2013, 135(23): 8668~8681.
49. [49]
  Zhang G, Hanson S K. Org. Lett., 2013, 15(3): 650~653.
50. [50]
  Zhang G, Yin Z, Zheng S. Org. Lett., 2016, 18(2): 300~303.
51. [51]
  Mastalir M, Tomsu G, Pittenauer E, et al. Org. Lett. 2016, 18(14): 3462~3465.
52. [52]
  Zhang G, Wu J, Zeng H, et al. Org. Lett. 2017, 19(5): 1080~1083.
53. [53]
  Yin Z, Zeng H, Wu J, et al. ACS Catal., 2016, 6(10): 6546~6550.
54. [54]
  Rösler S, Ertl M, Irrgang T, et al. Angew. Chem. Int. Ed., 2015, 54(50): 15046~15050.
55. [55]
  Freitag F, Irrgang T, Kempe R. Chem. Eur. J., 2017, 23(50): 12110~12113.
56. [56]
  Deibl N, Kempe R. J. Am. Chem. Soc., 2016, 138(34): 10786~10789.
57. [57]
  Elangovan S, Neumann J, Sortais J B, et al. Nat. Commun., 2016, 7: 12641.
58. [58]
  Peña-López M, Piehl P, Elangovan S, et al. Angew. Chem. Int. Ed., 2016, 55(48): 14967~14971.
59. [59]
  Mukherjee A, Nerush A, Leitus G, et al. J. Am. Chem. Soc., 2016, 138(13): 4298~4301.
60. [60]
  Mastalir M, Pittenauer E, Allmaier G, et al. J. Am. Chem. Soc., 2017, 139(26): 8812~8815.
61. [61]
  Schlagbauer M, Kallmeier F, Irrgang T, et al. Angew. Chem. Int. Ed., 2020, 59(4): 1485~1490.
1. [1]
  Wenke ZHENG , Ce LIU , Wei CHEN , Hongshan KE , Fanlong ZENG , Yibo LEI , Anyang LI , Wenyuan WANG . Synthesis and bonding analysis of low-coordinate Fe and Cr complexes with ultra-bulky silylamino groups. Chinese Journal of Inorganic Chemistry, 2025, 41(7): 1285-1293. doi: 10.11862/CJIC.20250095
2. [2]
  Hong Wu , Yuxi Wang , Hongyan Feng , Xiaokui Wang , Bangkun Jin , Xuan Lei , Qianghua Wu , Hongchun Li . Application of Computational Chemistry in the Determination of Magnetic Susceptibility of Metal Complexes. University Chemistry, 2025, 40(3): 116-123. doi: 10.12461/PKU.DXHX202405141
3. [3]
  Ran Yu , Chen Hu , Ruili Guo , Ruonan Liu , Lixing Xia , Cenyu Yang , Jianglan Shui . Catalytic Effect of H₃PW₁₂O₄₀ on Hydrogen Storage of MgH₂. Acta Physico-Chimica Sinica, 2025, 41(1): 100001-0. doi: 10.3866/PKU.WHXB202308032
4. [4]
  Xiaogang Liu , Mengyu Chen , Yanyan Li , Xiantao Ma . Experimental Reform in Applied Chemistry for Cultivating Innovative Competence: A Case Study of Catalytic Hydrogen Production from Liquid Formaldehyde Reforming at Room Temperature. University Chemistry, 2025, 40(7): 300-307. doi: 10.12461/PKU.DXHX202408007
5. [5]
  Shiyan Cheng , Yonghong Ruan , Lei Gong , Yumei Lin . Research Advances in Friedel-Crafts Alkylation Reaction. University Chemistry, 2024, 39(10): 408-415. doi: 10.12461/PKU.DXHX202403024
6. [6]
  Linjie ZHU , Xufeng LIU . Electrocatalytic hydrogen evolution performance of tetra-iron complexes with bridging diphosphine ligands. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 321-328. doi: 10.11862/CJIC.20240207
7. [7]
  Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
8. [8]
  Linjie ZHU , Xufeng LIU . Synthesis, characterization and electrocatalytic hydrogen evolution of two di-iron complexes containing a phosphine ligand with a pendant amine. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 939-947. doi: 10.11862/CJIC.20240416
9. [9]
  Wuxin Bai , Qianqian Zhou , Zhenjie Lu , Ye Song , Yongsheng Fu . Co-Ni Bimetallic Zeolitic Imidazolate Frameworks Supported on Carbon Cloth as Free-Standing Electrode for Highly Efficient Oxygen Evolution. Acta Physico-Chimica Sinica, 2024, 40(3): 2305041-0. doi: 10.3866/PKU.WHXB202305041
10. [10]
  Qingjun PAN , Zhongliang GONG , Yuwu ZHONG . Advances in modulation of the excited states of photofunctional iron complexes. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 45-58. doi: 10.11862/CJIC.20240365
11. [11]
  Wang Wang , Yucheng Liu , Shengli Chen . Use of NiFe Layered Double Hydroxide as Electrocatalyst in Oxygen Evolution Reaction: Catalytic Mechanisms, Electrode Design, and Durability. Acta Physico-Chimica Sinica, 2024, 40(2): 2303059-0. doi: 10.3866/PKU.WHXB202303059
12. [12]
  Yao HUANG , Yingshu WU , Zhichun BAO , Yue HUANG , Shangfeng TANG , Ruixue LIU , Yancheng LIU , Hong LIANG . Copper complexes of anthrahydrazone bearing pyridyl side chain: Synthesis, crystal structure, anticancer activity, and DNA binding. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 213-224. doi: 10.11862/CJIC.20240359
13. [13]
  Xinxin YU , Yongxing LIU , Xiaohong YI , Miao CHANG , Fei WANG , Peng WANG , Chongchen WANG . Photocatalytic peroxydisulfate activation for degrading organic pollutants over the zero-valent iron recovered from subway tunnels. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 864-876. doi: 10.11862/CJIC.20240438
14. [14]
  Hexing SONG , Zan SUN . Synthesis, crystal structure, Hirshfeld surface analysis, and fluorescent sensing for Fe³⁺ of an Mn(Ⅱ) complex based on 1-naphthalic acid. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 885-892. doi: 10.11862/CJIC.20240402
15. [15]
  Jinfeng Chu , Yicheng Wang , Ji Qi , Yulin Liu , Yan Li , Lan Jin , Lei He , Yufei Song . Comprehensive Chemical Experiment Design: Convenient Preparation and Characterization of an Oxygen-Bridged Trinuclear Iron(III) Complex. University Chemistry, 2024, 39(7): 299-306. doi: 10.3866/PKU.DXHX202310105
16. [16]
  Yan LIU , Jiaxin GUO , Song YANG , Shixian XU , Yanyan YANG , Zhongliang YU , Xiaogang HAO . Exclusionary recovery of phosphate anions with low concentration from wastewater using a CoNi-layered double hydroxide/graphene electronically controlled separation film. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1775-1783. doi: 10.11862/CJIC.20240043
17. [17]
  Zhicheng JU , Wenxuan FU , Baoyan WANG , Ao LUO , Jiangmin JIANG , Yueli SHI , Yongli CUI . MOF-derived nickel-cobalt bimetallic sulfide microspheres coated by carbon: Preparation and long cycling performance for sodium storage. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 661-674. doi: 10.11862/CJIC.20240363
18. [18]
  Yuanpei ZHANG , Jiahong WANG , Jinming HUANG , Zhi HU . Preparation of magnetic mesoporous carbon loaded nano zero-valent iron for removal of Cr(Ⅲ) organic complexes from high-salt wastewater. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1731-1742. doi: 10.11862/CJIC.20240077
19. [19]
  Liangliang Song , Haoyan Liang , Shunqing Li , Bao Qiu , Zhaoping Liu . Challenges and strategies on high-manganese Li-rich layered oxide cathodes for ultrahigh-energy-density batteries. Acta Physico-Chimica Sinica, 2025, 41(8): 100085-0. doi: 10.1016/j.actphy.2025.100085
20. [20]
  Ke QIAO , Yanlin LI , Shengli HUANG , Guoyu YANG . Advancements in asymmetric catalysis employing chiral iridium (ruthenium) complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2091-2104. doi: 10.11862/CJIC.20240265

Get Citation

PDF

XML

Metrics

PDF Downloads(40)
Abstract views(1689)
HTML views(401)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142