Citation: Zhong Keli, Deng Longlong, Guo Jia, Zhang Qiang, Hou Shuhua, Bian Yanjiang, Tang Lijun. Synthesis of 5-N, N-(diethylamino)-2-[(pyridin-2-ylimino)methyl] phenol and Its Recognition Characteristics for Zn²⁺[J]. Chemistry, ;2018, 81(12): 1110-1114, 1120. shu

Synthesis of 5-N, N-(diethylamino)-2-[(pyridin-2-ylimino)methyl] phenol and Its Recognition Characteristics for Zn²⁺

College of Chemistry and Chemical Engineering, Bohai University, Jinzhou 121013

Corresponding author: Tang Lijun, ljtang@bhu.edu.cn
Received Date: 25 July 2018
Accepted Date: 5 September 2018

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In this paper, the titled compound (probe L) was synthesized by using 2-aminopyridine and 4-N, N-diethylamino salicylaldehyde as starting materials, and its structure was characterized by NMR. In DMSO/Tris (6:4, V/V, pH=7.4) solution, the probe L can selectively recognize Zn²⁺ with fluorescence 'turn-on' responding, and fluorescence color of the system was changed from non-fluoresce to strong blue fluorescence under 365 nm UV lamp irradiation. The experimental results demonstrated that the binding ratio of L to Zn²⁺ is 1:1, the binding constant is 2.60×10³ L·mol^-1, the detection limit is 9.39×10^-7mol/L, and the proper pH range is 7~11. The probe L can also detect Zn²⁺ in real water samples.
- 4-N, N-diethylamino salicylaldehyde,
- Fluorescent probe,
- Zn²⁺,
- Recognition
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Synthesis of 5-N, N-(diethylamino)-2-[(pyridin-2-ylimino)methyl] phenol and Its Recognition Characteristics for Zn2+

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通讯作者: 陈斌, bchen63@163.com

Synthesis of 5-N, N-(diethylamino)-2-[(pyridin-2-ylimino)methyl] phenol and Its Recognition Characteristics for Zn²⁺