Citation: Hu Yangyang, Zeng Xianghua, Gong Chunhua, Xin Li, Zhang Jiaqi, Zhang Junyong, Xie Jingli. Synthesis, Structure and Photocatalytic Property of [Mo₆O₁₉]^2- Polyoxometalate with Phosphonium Cation[J]. Chemistry, ;2017, 80(7): 651-655. shu

Synthesis, Structure and Photocatalytic Property of [Mo₆O₁₉]^2- Polyoxometalate with Phosphonium Cation

College of Biological, Chemical Sciences and Engineering, Jiaxing University, Jiaxing 314001

Corresponding author: Zeng Xianghua, xianghuazeng@mail.zjxu.edu.cn Xie Jingli, jlxie@mail.zjxu.edu.cn
Received Date: 2 November 2016
Accepted Date: 4 February 2017

Figures(9)

A polyoxometalate compound [n-C₅H₁₀Ph₃P]₂[Mo₆O₁₉] was synthesized by the reaction of n-C₅H₁₀Ph₃PI and (NH₄)₆Mo₇O₂₄·7H₂O at ambient condition. This compound was characterized by single crystal X-ray diffraction, UV-Vis spectrum, IR spectrum, TGA and electrochemistry analysis. The polyoxometalate compound contains two n-C₅H₁₀Ph₃P⁺ cations. There were hydrogen bonding interactions between terminal oxygen atoms of [Mo₆O₁₉]^2- anions and phosphonium cations, and consequently one dimensional chain was formed. Three dimensional structures were constructed by the π-π stacking between the phenyl rings of the cationic phosphonium. Additionally, its photocatalytic property for the degradation of methylene blue (MB) was also investigated.
- Polyoxometalate,
- Phosphonium cation,
- Crystal structure,
- Photocatalytic,
- Methylene blue
1. [1]
  I Lindqvist. Arkiv Kemi, 1952, 5:247~250.
2. [2]
  I Lindqvist, B Aronsson. Arkiv Kerai, 1954, 7:49~52.
3. [3]
  A Goiffon, E Philippot, M Maurin. Rev. Chim. Miner., 1980, 17:466~476.
4. [4]
  O Dmitrenko, W L Huang, T W Polenova et al. J. Phy. Chem. B, 2003, 107(31):7747~7752.
5. [5]
  E Derat, D Kumar, R Neumann et al. Inorg. Chem., 2006, 45(21):8655~8663.
6. [6]
  J Li. J. Clust. Sci., 2002, 13(2):137~163.
7. [7]
  X Yang, T Waters, X B Wang et al. J. Phys. Chem. A, 2004, 108(46):10089~10093.
8. [8]
  Y Xia, P Wu, Y Wei et al. Cryst. Growth Des., 2006, 6(2):253~257.
9. [9]
  H Xu, Z Li, B Liu et al. Cryst. Growth Des., 2010, 10(3):1096~1103.
10. [10]
  P L Veya, J K Kochi. J. Organomet. Chem., 1995, 488(1/2):C4~C8.
11. [11]
  M Han, J Hey, W Kawamura et al. Inorg. Chem., 2012, 51(18):9574~9576.
12. [12]
  G H Clever, W Kawamura, S Tashira et al. Angew. Chem. Int. Ed., 2012, 51(11):2606~2609.
13. [13]
  A Moore, H Kwen, A M Beatty et al. Chem. Commun., 2000, (18):1793~1794.
14. [14]
  Q Li, P F Wu, Y G Wei et al. Inorg. Chem. Commun., 2004, 7(4):524~527.
15. [15]
  S X Guo, J Xie, R Gilbert-Wilson et al. Dalton Transac., 2011, 40(2):356~366.
16. [16]
  E C Alyea, D Craig, I Dance et al. CrystEngCom, 2005, 7(81):491~503.
17. [17]
18. [18]
  O V Dolomanov, L J Bourhis, R J Gildea et al. J. Appl. Crystallogr., 2009, 42(2):339~341.
19. [19]
  L Palatinus, G Chapuis. J. Appl. Crystallogr., 2007, 40(4):786~790.
20. [20]
  L Palatinus, A van der Lee. J. Appl. Crystallogr., 2008, 41(6):975~984.
21. [21]
  L Palatinus, S J Prathapa, S van Smaalen. J. Appl. Crystallogr., 2012, 45(3):575~580.
1. [1]
  Haitang WANG , Yanni LING , Xiaqing MA , Yuxin CHEN , Rui ZHANG , Keyi WANG , Ying ZHANG , Wenmin WANG . Construction, crystal structures, and biological activities of two Ln^Ⅲ₃ complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1474-1482. doi: 10.11862/CJIC.20240188
2. [2]
  Changqing MIAO , Fengjiao CHEN , Wenyu LI , Shujie WEI , Yuqing YAO , Keyi WANG , Ni WANG , Xiaoyan XIN , Ming FANG . Crystal structures, DNA action, and antibacterial activities of three tetranuclear lanthanide-based complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2455-2465. doi: 10.11862/CJIC.20240192
3. [3]
  Jing WU , Puzhen HUI , Huilin ZHENG , Pingchuan YUAN , Chunfei WANG , Hui WANG , Xiaoxia GU . Synthesis, crystal structures, and antitumor activities of transition metal complexes incorporating a naphthol-aldehyde Schiff base ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2422-2428. doi: 10.11862/CJIC.20240278
4. [4]
  Hongjie SHEN , Haozhe MIAO , Yuhe YANG , Yinghua LI , Deguang HUANG , Xiaofeng ZHANG . Synthesis, crystal structure, and fluorescence properties of two Cu(Ⅰ) complexes based on pyridyl ligand. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 855-863. doi: 10.11862/CJIC.20250009
5. [5]
  Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
6. [6]
  Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145
7. [7]
  Hexing SONG , Zan SUN . Synthesis, crystal structure, Hirshfeld surface analysis, and fluorescent sensing for Fe³⁺ of an Mn(Ⅱ) complex based on 1-naphthalic acid. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 885-892. doi: 10.11862/CJIC.20240402
8. [8]
  Yahui HAN , Jinjin ZHAO , Ning REN , Jianjun ZHANG . Synthesis, crystal structure, thermal decomposition mechanism, and fluorescence properties of benzoic acid and 4-hydroxy-2, 2′: 6′, 2″-terpyridine lanthanide complexes. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 969-982. doi: 10.11862/CJIC.20240395
9. [9]
  Xin MA , Ya SUN , Na SUN , Qian KANG , Jiajia ZHANG , Ruitao ZHU , Xiaoli GAO . A Tb₂ complex based on polydentate Schiff base: Crystal structure, fluorescence properties, and biological activity. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1347-1356. doi: 10.11862/CJIC.20230357
10. [10]
  Yuxin CHEN , Yanni LING , Yuqing YAO , Keyi WANG , Linna LI , Xin ZHANG , Qin WANG , Hongdao LI , Wenmin WANG . Construction, structures, and interaction with DNA of two Sm^Ⅲ₄ complexes. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1141-1150. doi: 10.11862/CJIC.20240258
11. [11]
  Jingjing QING , Fan HE , Zhihui LIU , Shuaipeng HOU , Ya LIU , Yifan JIANG , Mengting TAN , Lifang HE , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two complexes of dimethylglyoxime organotin. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1301-1308. doi: 10.11862/CJIC.20240003
12. [12]
  Lifang HE , Wenjie TANG , Yaoze LUO , Mingsheng LIANG , Jianxin TANG , Yuxuan WU , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two dialkyltin complexes constructed based on 2, 2′-bipyridin-6, 6′-dicarboxylic acid. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1601-1609. doi: 10.11862/CJIC.20250012
13. [13]
  Linjie ZHU , Xufeng LIU . Electrocatalytic hydrogen evolution performance of tetra-iron complexes with bridging diphosphine ligands. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 321-328. doi: 10.11862/CJIC.20240207
14. [14]
  Linjie ZHU , Xufeng LIU . Synthesis, characterization and electrocatalytic hydrogen evolution of two di-iron complexes containing a phosphine ligand with a pendant amine. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 939-947. doi: 10.11862/CJIC.20240416
15. [15]
  Kun WANG , Wenrui LIU , Peng JIANG , Yuhang SONG , Lihua CHEN , Zhao DENG . Hierarchical hollow structured BiOBr-Pt catalysts for photocatalytic CO₂ reduction. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1270-1278. doi: 10.11862/CJIC.20240037
16. [16]
  Ronghui LI . Photocatalysis performance of nitrogen-doped CeO₂ thin films via ion beam-assisted deposition. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1123-1130. doi: 10.11862/CJIC.20240440
17. [17]
  Yan Liu , Yuexiang Zhu , Luhua Lai . Introduction to Blended and Small-Class Teaching in Structural Chemistry: Exploring the Structure and Properties of Crystals. University Chemistry, 2024, 39(3): 1-4. doi: 10.3866/PKU.DXHX202306084
18. [18]
  Linfeng Xiao , Wanlu Ren , Shishi Shen , Mengshan Chen , Runhua Liao , Yingtang Zhou , Xibao Li . Enhancing Photocatalytic Hydrogen Evolution through Electronic Structure and Wettability Adjustment of ZnIn₂S₄/Bi₂O₃ S-Scheme Heterojunction. Acta Physico-Chimica Sinica, 2024, 40(8): 2308036-0. doi: 10.3866/PKU.WHXB202308036
19. [19]
  Yichang Liu , Li An , Dan Qu , Zaicheng Sun . “双碳”背景下的综合设计实验——以PbCrO₄催化甲基蓝的光降解速率常数测定为例. University Chemistry, 2025, 40(6): 222-229. doi: 10.12461/PKU.DXHX202407105
20. [20]
  Weina Wang , Fengyi Liu , Wenliang Wang . “Extracting Commonality, Delving into Typicals, Deriving Individuality”: Constructing a Knowledge Graph of Crystal Structures. University Chemistry, 2024, 39(3): 36-42. doi: 10.3866/PKU.DXHX202308029

Get Citation

PDF

XML

Metrics

PDF Downloads(5)
Abstract views(602)
HTML views(74)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Synthesis, Structure and Photocatalytic Property of [Mo6O19]2- Polyoxometalate with Phosphonium Cation

Metrics

通讯作者: 陈斌, bchen63@163.com

Synthesis, Structure and Photocatalytic Property of [Mo₆O₁₉]^2- Polyoxometalate with Phosphonium Cation