Citation: Dai Hongguang, Liu Xuhui, Wang Lirong, Shi Lan. Synthesis of N-Substituted Pyrroles using Lignosulfonic Acid as Biomass-Based Catalyst[J]. Chemistry, ;2018, 81(10): 929-933. shu

Synthesis of N-Substituted Pyrroles using Lignosulfonic Acid as Biomass-Based Catalyst

College of Science, Inner Mongolia Agricultural University, Hohhot 010018

Corresponding author: Dai Hongguang, imaudm@imau.edu.cn
Received Date: 18 May 2018
Accepted Date: 29 July 2018

Figures(4)

Lignosulfonic acid is a kind of heterogeneous, environmentally friendly, biomass-based solid catalyst. In this paper, it was prepared by ion-exchange method using sodium lignosulfonate in papermaking waste as raw material. Its structure was characterized by FT-IR, elemental analysis and titration. Using lignosulfonic acid as a catalyst, N-substituted pyrroles were synthesized efficiently by Paal-Knorr reaction of hexane-2, 5-dione and primary amine in good to excellent yields. This is a typical nucleophilic reaction. The stronger the nucleophilic ability of the primary amine, the more easily the reaction proceeds.
- Paal-Knorr reaction,
- Lignosulfonic acid,
- Pyrroles,
- Biomass-based catalyst
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沈阳化工大学材料科学与工程学院沈阳 110142