Citation: YANG Shu-qian, LIU Yu-juan, LIU Jin-bo, FANG Ming-ming, XIAO Guo-peng, ZHANG Lei, CHEN Lin, YUAN Xing-zhou, ZHANG Jian. Effect of calcination temperature on the catalytic performance of the hydrotalcite derived Ce/Cu/Zn-Al catalysts for hydrogen production via methanol steam reforming[J]. Journal of Fuel Chemistry and Technology, ;2018, 46(12): 1482-1490. shu

Effect of calcination temperature on the catalytic performance of the hydrotalcite derived Ce/Cu/Zn-Al catalysts for hydrogen production via methanol steam reforming

1.
College of Chemistry, Chemical Engineering and Environmental Engineering, Liaoning Shihua University, Fushun 113001, China
2.
Department of Chemistry and Materials Engineering, Yingkou Institute of Technology, Yingkou 115014, China

Corresponding author: ZHANG Lei, lnpuzhanglei@163.com ZHANG Jian, zhangjian_lnpu@163.com
Received Date: 20 August 2018
Revised Date: 4 November 2018

Fund Project: the Science Research General Foundation of Liaoning Education Department L2015296The project was supported by the National Natural Science Foundation of China (21376237), the Doctoral Scientific Research Foundation of Liaoning Province (201601322) and the Science Research General Foundation of Liaoning Education Department(L2015296)the National Natural Science Foundation of China 21376237the Doctoral Scientific Research Foundation of Liaoning Province 201601322

Figures(10)

ZnAl-LDHs was prepared by in-situ synthesis method on the surface of γ-Al₂O₃, and then a series Ce/Cu/Zn-Al catalysts were prepared by ordinal wet impregnation method. All the catalysts were characterized by XRD, BET, H₂-TPR and XPS to investigate the effects of calcination temperature on the surface structure of Ce/Cu/Zn-Al catalyst and its catalytic performance in methanol steam reforming. The results showed that calcination temperature mainly influenced the specific surface area of copper, surface oxygen vacancy content and the interaction between Cu and Ce. When the calcination temperature is 500℃, the specific surface area of Cu is larger, the content of oxygen vacancy is higher and the interaction between Cu and Ce is stronger. Therefore, the catalytic activity of the catalysts for methanol steam reforming is the best. When the calcination temperature rises to 700℃, the Cu species mainly exist in the form of stable CuAl₂O₄ spinel, which is not conducive to the reaction of methanol steam reforming, resulting in lower catalytic activity.
- calcination temperature,
- hydrotalcite,
- Cu-Al spinel,
- methanol steam reforming,
- hydrogen
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